The ultracool dwarf DENIS-P J104814.7-395606. Chromospheres and coronae at the low-mass end of the main-sequence

We have obtained an XMM-Newton observation and a broad-band spectrum from the ultraviolet to the near infrared with X-Shooter for one of the nearest M9 dwarfs, DENIS-P J1048-3956 (4pc). We integrate these data by a compilation of activity parameters for ultracool dwarfs from the literature with the aim to advance our understanding of these objects by comparing them to early-M type dwarf stars and the Sun. Our deep XMM-Newton observation has led to the first X-ray detection of DENIS-P J1048-3956 (log Lx = 25.1) as well as the first measurement of its V band brightness (V = 17.35mag). Flux-flux relations between X-ray and chromospheric activity indicators are here for the first time extended into the regime of the ultracool dwarfs. The approximate agreement of DENIS-P J1048-3956 and other ultracool dwarfs with flux-flux relations for early-M dwarfs suggests that the same heating mechanisms work in the atmospheres of ultracool dwarfs, albeit weaker as judged from their lower fluxes. The observed Balmer decrements of DENIS-P J1048-3956 are compatible with optically thick plasma in LTE at low, nearly photospheric temperature or optically thin LTE plasma at 20000K. Describing the decrements with CaseB recombination requires different emitting regions for Halpha and the higher Balmer lines. The high observed Halpha/Hbeta flux ratio is also poorly fitted by the optically thin models. We derive a similarly high value for the Halpha/Hbeta ratio of vB10 and LHS2065 and conclude that this may be a characteristic of ultracool dwarfs. We add DENIS-P J1048-3956 to the list of ultracool dwarfs detected in both the radio and the X-ray band. The Benz-Guedel relation between radio and X-ray luminosity of late-type stars is well-known to be violated by ultracool dwarfs. We speculate on the presence of two types of ultracool dwarfs with distinct radio and X-ray behavior.Comment: accepted for publication in Astronomy & Astrophysic

Chemical abundances of damped Lyman alpha systems in the XQ-100 survey

The XQ-100 survey has provided high signal-noise spectra of 100 redshift 3-4.5 quasars with the X-Shooter spectrograph. The metal abundances for 13 elements in the 41 damped Lyman alpha systems (DLAs) identified in the XQ-100 sample are presented, and an investigation into abundances of a variety of DLA classes is conducted. The XQ-100 DLA sample contains five DLAs within 5000 km/s of their host quasar (proximate DLAs; PDLAs) as well as three sightlines which contain two DLAs within 10,000 km/s of each other along the same line-of-sight (multiple DLAs; MDLAs). Combined with previous observations in the literature, we demonstrate that PDLAs with logN(HI)<21.0 show lower [S/H] and [Fe/H] (relative to intervening systems with similar redshift and N(HI)), whilst higher [S/H] and [Si/H] are seen in PDLAs with logN(HI)>21.0. These abundance discrepancies are independent of their line-of-sight velocity separation from the host quasar, and the velocity width of the metal lines (v90). Contrary to previous studies, MDLAs show no difference in [alpha/Fe] relative to single DLAs matched in metallicity and redshift. In addition, we present follow-up UVES data of J0034+1639, a sightline containing three DLAs, including a metal-poor DLA with [Fe/H]=-2.82 (the third lowest [Fe/H] in DLAs identified to date) at z=4.25. Lastly we study the dust-corrected [Zn/Fe], emphasizing that near-IR coverage of X-Shooter provides unprecedented access to MgII, CaII and TiII lines (at redshifts 3-4) to provide additional evidence for subsolar [Zn/Fe] ratio in DLAs.Comment: Accepted to MNRAS. 19 pages plus Appendix material (102 pages total

X-Shooter spectroscopy of young stellar objects: II. Impact of chromospheric emission on accretion rate estimates

Context. The lack of knowledge of photospheric parameters and the level of chromospheric activity in young low-mass pre-main sequence stars introduces uncertainties when measuring mass accretion rates in accreting (Class II) Young Stellar Objects. A detailed investigation of the effect of chromospheric emission on the estimates of mass accretion rate in young low-mass stars is still missing. This can be undertaken using samples of young diskless (Class III) K and M-type stars. Aims. Our goal is to measure the chromospheric activity of Class III pre main sequence stars to determine its effect on the estimates of accretion luminosity (Lacc) and mass accretion rate (Macc) in young stellar objects with disks. Methods. Using VLT/X-Shooter spectra we have analyzed a sample of 24 non-accreting young stellar objects of spectral type between K5 and M9.5. We identify the main emission lines normally used as tracers of accretion in Class II objects, and we determine their fluxes in order to estimate the contribution of the chromospheric activity to the line luminosity. Results. We have used the relationships between line luminosity and accretion luminosity derived in the literature for Class II objects to evaluate the impact of chromospheric activity on the accretion rate measurements. We find that the typical chromospheric activity would bias the derived accretion luminosity by Lacc,noise< 10-3Lsun, with a strong dependence with the Teff of the objects. The noise on Macc depends on stellar mass and age, and the typical values of log(Macc,noise) range between -9.2 to -11.6Msun/yr. Conclusions. Values of Lacc< 10-3Lsun obtained in accreting low-mass pre main sequence stars through line luminosity should be treated with caution as the line emission may be dominated by the contribution of chromospheric activity.Comment: accepted for publication in Astronomy & Astrophysic

X-Shooter spectroscopy of young stellar objects: IV -- Accretion in low-mass stars and sub-stellar objects in Lupus

We present X-Shooter/VLT observations of a sample of 36 accreting low-mass stellar and sub-stellar objects (YSOs) in the Lupus star forming region, spanning a range in mass from ~0.03 to ~1.2Msun, but mostly with 0.1Msun < Mstar < 0.5Msun. Our aim is twofold: firstly, analyse the relationship between excess-continuum and line emission accretion diagnostics, and, secondly, to investigate the accretion properties in terms of the physical properties of the central object. The accretion luminosity (Lacc), and from it the accretion rate (Macc), is derived by modelling the excess emission, from the UV to the near-IR, as the continuum emission of a slab of hydrogen. The flux and luminosity (Ll) of a large number of emission lines of H, He, CaII, etc., observed simultaneously in the range from ~330nm to 2500nm, were computed. The luminosity of all the lines is well correlated with Lacc. We provide empirical relationships between Lacc and the luminosity of 39 emission lines, which have a lower dispersion as compared to previous relationships in the literature. Our measurements extend the Pab and Brg relationships to Lacc values about two orders of magnitude lower than those reported in previous studies. We confirm that different methodologies to measure Lacc and Macc yield significantly different results: Ha line profile modelling may underestimate Macc by 0.6 to 0.8dex with respect to Macc derived from continuum-excess measures. Such differences may explain the likely spurious bi-modal relationships between Macc and other YSOs properties reported in the literature. We derive Macc in the range 2e-12 -- 4e-8 Msun/yr and conclude that Macc is proportional to Mstar^1.8(+/-0.2), with a dispersion lower by a factor of about 2 than in previous studies. A number of properties indicate that the physical conditions of the accreting gas are similar over more than 5 orders of magnitude in Macc

Volume intensified dilution of a ring-closing metathesis in ethyl acetate by means of a membrane-assisted process in solvent recycle

BACKGROUND Ring-closing metathesis (RCM) for the synthesis of macrocycles has been used more and more often over recent years, including some interesting applications on industrial scale. However, like all macrocyclization strategies RCM is plagued by the traditional issue of low volume efficiency. To-date this is typically addressed in a molecule specific manner with varying degrees of success. Here we report a process intensification method of metathesis macrocyclization that reduces the solvent load required for the reaction significantly. RESULTS Metathesis macrocylizations were successfully carried out in a solvent volume of upto 82% lower than an equivalent batch reaction, with only minimal impact upon the reaction outcome. A switch of reaction solvent to ethyl acetate renders the process more benign and applicable to large scale. CONCLUSION A membrane-assisted processing method that relies upon organic solvent nanofiltration permitting an internal solvent recycling and concumittent in situ product removal. The method is also designed to be applicable to a wide range of metathesis cyclizations. (c) 2019 Society of Chemical Industr

X-Shooter spectroscopy of young stellar objects III. Photospheric and chromospheric properties of Class III objects

We analyzed X-Shooter/VLT spectra of 24 ClassIII sources from three nearby star-forming regions (sigmaOrionis, LupusIII, and TWHya). We determined the effective temperature, surface gravity, rotational velocity, and radial velocity by comparing the observed spectra with synthetic BT-Settl model spectra. We investigated in detail the emission lines emerging from the stellar chromospheres and combined these data with archival X-ray data to allow for a comparison between chromospheric and coronal emissions. Both X-ray and Halpha luminosity as measured in terms of the bolometric luminosity are independent of the effective temperature for early-M stars but decline toward the end of the spectral M sequence. For the saturated early-M stars the average emission level is almost one dex higher for X-rays than for Halpha: log(L_x/L_bol) = -2.85 +- 0.36 vs. log(L_Halpha/L_bol) = -3.72 +- 0.21. When all chromospheric emission lines (including the Balmer series up to H11, CaII HK, the CaII infrared triplet, and several HeI lines) are summed up the coronal flux still dominates that of the chromosphere, typically by a factor 2-5. Flux-flux relations between activity diagnostics that probe different atmospheric layers (from the lower chromosphere to the corona) separate our sample of active pre-main sequence stars from the bulk of field M dwarfs studied in the literature. Flux ratios between individual optical emission lines show a smooth dependence on the effective temperature. The Balmer decrements can roughly be reproduced by an NLTE radiative transfer model devised for another young star of similar age. Future, more complete chromospheric model grids can be tested against this data set.Comment: accepted for publication in Astronomy & Astrophysic

When two become one: an apparent QSO pair turns out to be a single quasar

We report on our serendipitous discovery that the objects Q 01323-4037 and Q 0132-4037, listed in the V\'eron-Cetty & V\'eron catalog (2006) as two different quasars, are actually a quasar and a star. We briefly discuss the origin of the misidentification, and provide a refined measurement of the quasar redshift.Comment: 3 pages, 2 figures; accepted for publication in A&

Nature and statistical properties of quasar associated absorption systems in the XQ-100 Legacy Survey

We statistically study the physical properties of a sample of narrow absorption line (NAL) systems looking for empirical evidences to distinguish between intrinsic and intervening NALs without taking into account any a priori definition or velocity cut-off. We analyze the spectra of 100 quasars with 3.5 < z$\rm_{em}$ < 4.5, observed with X-shooter/VLT in the context of the XQ-100 Legacy Survey. We detect a $\sim$ 8 $\sigma$ excess in the number density of absorbers within 10,000 km/s of the quasar emission redshift with respect to the random occurrence of NALs. This excess does not show a dependence on the quasar bolometric luminosity and it is not due to the redshift evolution of NALs. It extends far beyond the standard 5000 km/s cut-off traditionally defined for associated absorption lines. We propose to modify this definition, extending the threshold to 10,000 km/s when also weak absorbers (equivalent width < 0.2 \AA) are considered. We infer NV is the ion that better traces the effects of the quasar ionization field, offering the best statistical tool to identify intrinsic systems. Following this criterion we estimate that the fraction of quasars in our sample hosting an intrinsic NAL system is 33 percent. Lastly, we compare the properties of the material along the quasar line of sight, derived from our sample, with results based on close quasar pairs investigating the transverse direction. We find a deficiency of cool gas (traced by CII) along the line of sight associated with the quasar host galaxy, in contrast with what is observed in the transverse direction.Comment: 18 pages, 13 figures, 5 table

GRB host galaxies with VLT/X-Shooter: properties at 0.8 < z < 1.3

Long gamma-ray bursts (LGRBs) are associated with the death of massive stars. Their host galaxies therefore represent a unique class of objects tracing star formation across the observable Universe. Indeed, recently accumulated evidence shows that GRB hosts do not differ substantially from general population of galaxies at high (z > 2) redshifts. However, it has been long recognised that the properties of z < 1.5 hosts, compared to general star-forming population, are unusual. To better understand the reasons for the supposed difference in LGRB hosts properties at z < 1.5, we obtained VLT/X- Shooter spectra of six hosts lying in the redshift range of 0.8 < z < 1.3. Some of these hosts have been observed before, yet we still lack well constrained information on their characteristics such as metallicity, dust extinction and star formation rate. We search for emission lines in the VLT/X-Shooter spectra of the hosts and measure their fluxes. We perform a detailed analysis, estimating host average extinction, star-formation rates, metallicities and electron densities where possible. Measured quantities of our hosts are compared to a larger sample of previously observed GRB hosts at z < 2. Star-formation rates and metallicities are measured for all the hosts analyzed in this paper and metallicities are well determined for 4 hosts. The mass-metallicity relation, the fundamental metallicity relation and SFRs derived from our hosts occupy similar parameter space as other host galaxies investigated so-far at the same redshift. We therefore conclude that GRB hosts in our sample support the found discrepancy between the properties of low-redshift GRB hosts and the general population of star- forming galaxies.Comment: 13 pages, 6 figures, accepted for publication in MNRA