The History of Cyclodextrins

International audienceThis book presents the historical development of Cyclodextrins by scientists who have made outstanding contribution to the field. Cyclodextrins are safe, cage-like molecules that have found major applications in many industrial sectors such as medicine, food, agriculture, environment and chemistry

Author Index

International audienc

Towards a convenient procedure to characterize polycyclic aromatic hydrocarbons in sediments receiving industrial effluents

International audienc

Hemp to limit diffusion of difenoconazole in vegetable garden soils

Triazole molecules are used to manage invasive aspergillosis, a fungal infection mainly due to Aspergillus fumigants. A. fumigants is not a phytopathogen, but, as it is widespread in soils, triazole fungicides have an unintended impact on it, selecting resistant populations' in environment. Thus, to maintain our ability to control fungal infections, whether in human health or agriculture, reduce the impact of the use of triazoles in the environment is important, notably limiting their diffusion in soils. Here we tested a hemp-based material as adsorbent to limit the spread of difenoconazole, a triazole fungicide, in vegetable soils. We studied the effects of contact time, material dose, difenoconazole concentration, and organic content of the soil using batch mode and percolation methods. Batch experiments showed that the material exhibited high adsorption capacities toward difenoconazole. Removal from the soil water increased from 46.6% using 0.35 g hemp per kg of soil to 77.0% using 1.75 g hemp per kg, for a contact time of 15 min and an initial difenoconazole concentration of 1.2 mg/L. For a contact time of 240 min, the removal was 93.5%. Percolation experiments showed that the quantity of difenoconazole removed was greater than the amount obtained by batch method: 41.9% of removal with only one passes of solution at a concentration of 12 mg/L is obtained through percolation technique whereas, with similar conditions, only 20% of removal is obtained by batch method, i.e. after 1 min of contact. The removal was strongly dependent on the number of passes: the values increased from 57.0% to 91.0% with increasing the number of passes from 1 to 15. Addition of hemp to soils allows to remove efficiently the difenoconazole fungicide from soil water. Hemp-based felt is a new and safe adsorbent that can be applied in agriculture to limit crop contamination

Innovative technologies to remove alkylphenols from wastewater: a review

National audienc

Worldwide cases of water pollution by emerging contaminants: a review

National audienceWater contamination by emerging contaminants is increasing in the context of rising urbanization, industrialization, and agriculture production. Emerging contaminants refers to contaminants for which there is currently no regulation requiring monitoring or public reporting of their presence in our water supply or wastewaters. There are many emerging contaminants such as pesticides, pharmaceuticals, drugs, cosmetics, personal care products, surfactants, cleaning products, industrial formulations and chemicals, food additives, food packaging, metalloids, rare earth elements, nanomaterials, microplastics, and pathogens. The main sources of emerging contaminants are domestic discharges, hospital effluents, industrial wastewaters, runoff from agriculture, livestock and aquaculture, and landfill leachates. In particular, effluents from municipal wastewater treatment plants are major contributors to the presence of emerging contaminants in waters. Although many chemicals have been recently regulated as priority hazardous substances, conventional plants for wastewater and drinking water treatment were not designed to remove most emerging contaminants. Here, we review key examples of contamination in China, Portugal, Mexico, Colombia, and Brazil. Examples include persistent organic pollutants such as polychlorinated biphenyls, dibenzofurans, and polybrominated diphenyl ethers, in lake and ocean ecosystems in China; emerging contaminants such as alkylphenols, natural and synthetic estrogens, antibiotics, and antidepressants in Portuguese rivers; and pharmaceuticals, hormones, cosmetics, personal care products, and pesticides in Mexican, Brazilian, and Colombian waters. All continents are affected by these contaminants. Wastewater treatment plants should therefore be upgraded, e.g., by addition of tertiary treatment systems, to limit environmental pollution