A Search for Biomolecules in Sagittarius B2 (LMH) with the ATCA

We have used the Australia Telescope Compact Array to conduct a search for the simplest amino acid, glycine (conformers I and II), and the simple chiral molecule propylene oxide at 3-mm in the Sgr B2 LMH. We searched 15 portions of spectrum between 85 and 91 GHz, each of 64 MHz bandwidth, and detected 58 emission features and 21 absorption features, giving a line density of 75 emission lines and 25 absorption lines per GHz stronger than the 5 sigma level of 110 mJy. Of these, 19 are transitions previously detected in the interstellar medium, and we have made tentative assignments of a further 23 features to molecular transitions. However, as many of these involve molecules not previously detected in the ISM, these assignments cannot be regarded with confidence. Given the median line width of 6.5 km/s in Sgr B2 LMH, we find that the spectra have reached a level where there is line confusion, with about 1/5 of the band being covered with lines. Although we did not confidently detect either glycine or propylene oxide, we can set 3 sigma upper limits for most transitions searched. We also show that if glycine is present in the Sgr B2 LMH at the level of N = 4 x 10^{14} cm^{-2} found by Kuan et al. (2003) in their reported detection of glycine, it should have been easily detected with the ATCA synthesized beam size of 17.0 x 3.4 arcsec^{2}, if it were confined to the scale of the LMH continuum source (< 5 arcsec). This thus puts a strong upper limit on any small-scale glycine emission in Sgr B2, for both of conformers I and II.Comment: 12 pages, 2 figures, 5 tables, accepted by MNRA

Communication satisfaction, job satisfaction, organisational commitment and intention to leave

The retention of highly motivated, skilled and committed employees is a major concern by organisations to achieve a competitive advantage. The turnover intentions of human capital are of interest to managers, employees, and organisations today. This study explores a theoretical model of turnover intentions that included three proximal variables, job satisfaction, affective and continuance commitment, the distal variables of subordinate communication, horizontal communication, personal feedback, media quality, communication climate, supervisor communication, job-related communication, and management communication, with turnover intentions. A questionnaire was completed by 101 participants of a rental firm in New Zealand. Job satisfaction, affective commitment, continuance commitment, subordinate communication, horizontal communication, personal feedback, media quality, communication climate, supervisor communication, job-related communication, and management communication correlated with turnover intentions. The results of the mediated regression analysis indicated that job satisfaction, affective commitment, and continuance commitment are significant mediators between the eight distal (organisational communication) variables, with turnover intentions. This study highlights the necessity for managers to develop good quality relationships with their employees to improve the quality of their communication, to foster job satisfaction, affective commitment, and continuance commitment to reduce turnover intentions. The conclusion of this study discusses the practical implications for managers, and organisations and the direction for future research

Multi-transition study and new detections of class II methanol masers

We have used the ATNF Mopra antenna and the SEST antenna to search in the directions of several class II methanol maser sources for emission from six methanol transitions in the frequency range 85-115 GHz. The transitions were selected from excitation studies as potential maser candidates. Methanol emission at one or more frequencies was detected from five of the maser sources, as well as from Orion KL. Although the lines are weak, we find evidence of maser origin for three new lines in G345.01+1.79, and possibly one new line in G9.62+0.20. The observations, together with published maser observations at other frequencies, are compared with methanol maser modelling for G345.01+1.79 and NGC6334F. We find that the majority of observations in both sources are consistent with a warm dust (175 K) pumping model at hydrogen density ~10^6 cm^-3 and methanol column density ~5 x 10^17 cm^-2. The substantial differences between the maser spectra in the two sources can be attributed to the geometry of the maser region.Comment: 13 pages, 6 figures, Accepted for publication in MNRA

Class I and Class II methanol masers in high-mass star forming regions

Among the tracers of the earliest phases in the massive star formation process, methanol masers have gained increasing importance. The phenomenological distinction between Class I and II methanol masers is based on their spatial association with objects such as jets, cores, and ultracompact HII regions, but is also believed to correspond to different pumping mechanisms: radiation for Class II masers, collisions for Class I masers. In this work, we have surveyed a large sample of massive star forming regions - 296 objects divided into two groups named 'High' and 'Low' according to their [25-12] and [60-12] IRAS colours - in Class I and II methanol masers. Previous studies indicate that the High sources are likely more evolved. Therefore, the sample can be used to assess the existence of a sequence for the occurrence of Class I and II methanol masers during the evolution of a massive star forming region. We observed the 6 GHz (Class II) CH3OH maser with the Effelsberg 100-m telescope, and the 44 GHz and 95 GHz (Class I) CH3OH masers with the Nobeyama 45-m telescope. We have detected: 55 sources in the Class II line (12 new detections); 27 sources in the 44 GHz Class I line (17 new detections); 11 sources in the 95 GHz Class I line (all except one are new detections). Our statistical analysis shows that the ratio between the detection rates of Class II and Class I methanol masers is basically the same in High and Low sources. Therefore, both masers are equally associated with each evolutionary phase. In contrast, all maser species have about 3 times higher detection rates in High than in Low sources. This might indicate that the phenomena that originate all masers become progressively more active with time, during the earliest evolutionary phases of a high-mass star forming region.Comment: 30 pages including Appendices, 11 figures, accepted for publication in Astronomy & Astrophysic

VLBI study of maser kinematics in high-mass SFRs. II. G23.01-0.41

The present paper focuses on the high-mass star-forming region G23.01-0.41. Methods: Using the VLBA and the EVN arrays, we conducted phase-referenced observations of the three most powerful maser species in G23.01-0.41: H2O at 22.2 GHz (4 epochs), CH3OH at 6.7 GHz (3 epochs), and OH at 1.665 GHz (1 epoch). In addition, we performed high-resolution (> 0".1), high-sensitivity (< 0.1 mJy) VLA observations of the radio continuum emission from the HMC at 1.3 and 3.6 cm. Results: We have detected H2O, CH3OH, and OH maser emission clustered within 2000 AU from the center of a flattened HMC, oriented SE-NW, from which emerges a massive 12CO outflow, elongated NE-SW, extended up to the pc-scale. Although the three maser species show a clearly different spatial and velocity distribution and sample distinct environments around the massive YSO, the spatial symmetry and velocity field of each maser specie can be explained in terms of expansion from a common center, which possibly denotes the position of the YSO driving the maser motion. Water masers trace both a fast shock (up to 50 km/s) closer to the YSO, powered by a wide-angle wind, and a slower (20 km/s) bipolar jet, at the base of the large-scale outflow. Since the compact free-free emission is found offset from the putative location of the YSO along a direction consistent with that of the maser jet axis, we interpret the radio continuum in terms of a thermal jet. The velocity field of methanol masers can be explained in terms of a composition of slow (4 km/s in amplitude) motions of radial expansion and rotation about an axis approximately parallel to the maser jet. Finally, the distribution of line of sight velocities of the hydroxyl masers suggests that they can trace gas less dense (n(H2) < 10^6 cm^-3) and more distant from the YSO than that traced by the water and methanol masers, which is expanding toward the observer. (Abridged)Comment: 23 pages, 8 figures, 4 tables, accepted by Astronomy and Astrophysic

Selforganized 3-band structure of the doped fermionic Ising spin glass

The fermionic Ising spin glass is analyzed for arbitrary filling and for all temperatures. A selforganized 3-band structure of the model is obtained in the magnetically ordered phase. Deviation from half filling generates a central nonmagnetic band, which becomes sharply separated at T=0 by (pseudo)gaps from upper and lower magnetic bands. Replica symmetry breaking effects are derived for several observables and correlations. They determine the shape of the 3-band DoS, and, for given chemical potential, influence the fermion filling strongly in the low temperature regime.Comment: 13 page

A search for 4750- and 4765-MHz OH masers in Southern Star Forming Regions

We have used the Australia Telescope Compact Array (ATCA) to make a sensitive (5-$\sigma$ $\simeq$ 100 mJy) search for maser emission from the 4765-MHz $^2\Pi_{1/2}$ F=1$\to$0 transition of OH. Fifty five star formation regions were searched and maser emission with a peak flux density in excess of 100 mJy was detected toward fourteen sites, with ten of these being new discoveries. In addition we observed the 4750-MHz $^2\Pi_{1/2}$ F=1$\to$1 transition towards a sample of star formation regions known to contain 1720-MHz OH masers, detecting marginal maser emission from G348.550-0.979. If confirmed this would be only the second maser discovered from this transition. The occurrence of 4765-MHz OH maser emission accompanying 1720-MHz OH masers in a small number of well studied star formation regions has lead to a general perception in the literature that the two transitions favour similar physical conditions. Our search has found that the presence of the excited-state 6035-MHz OH transition is a much better predictor of 4765-MHz OH maser emission from the same region than is 1720-MHz OH maser emission. Combining our results with those of previous high resolution observations of other OH transitions we have examined the published theoretical models of OH masers and find that none of them predict any conditions in which the 1665-, 6035- and 4765-MHz transitions are simultaneously inverted. Erratum abstract: Dodson & Ellingsen (2002) included several observations with significant pointing errors, invalidating the upper limits found in these directions. These have now been reobserved or recalculated. A new table of upper limits has been generated, and two more masers that would have been seen have been found.Comment: Included an Erratum with Max as another author. This erratum was rejected by MNRAS (Feb 04) as it contained too much data. Resubmitted as a paper (Jun 04). Rejected (Sep 04) it had too little data. Resubmitted as reduced erratum (Apr 05). Still waitin