14,843 research outputs found
Intrusive origin of the Sudbury Igneous Complex: Structural and sedimentological evidence
In recent years, many geoscientists have come to believe that the Sudbury event was exogenic rather than endogenic. Critical to a recent exogenic hypothesis is the impact melt origin of the Sudbury Igneous Complex (SIC). Such origin implies that the SIC was emplaced before deposition of the Whitewater Group, in contrast to origins in which the SIC postdates the lithification of the Onaping Formation. Structural and sedimentological evidence is summarized herein that supports an intrusion of the SIC after lithification of all Whitewater Group strata, and conflicts with the hypothesis advanced by other researchers
Caldolysin, a highly active protease from an extremely Thermophilic Bacterium
Proteases comprise a significant proportion of those proteins which have been subject to detailed characterisation (amino acid sequence and high resolution crystallographic analysis). The extent of research interest in proteolytic enzymes reflects both their historical status, and the practical advantages of proteases as research subjects (available in quantity, extracellular etc.) widely occurring
The industrial potential of enzymes from extremely thermophilic bacteria
The thermal regions of the central North Island of New Zealand are some of the most extensive in the world. In addition, they are readily accessible and contain a diversity of ecological habitats, including a large number at 100°C. These areas are regarded as an important tourist attraction, and as a source of geothermal power, It is now clear that they also contain an important and unique genetic resource
Resonant x-ray scattering spectra from multipole orderings: Np M_{4,5} edges in NpO2
We study resonant x-ray scattering (RXS) at Np M_{4,5} edges in the
triple-\textbf{k} multipole ordering phase in NpO_{2}, on the basis of a
localized electron model. We derive an expression for RXS amplitudes to
characterize the spectra under the assumption that a rotational invariance is
preserved in the intermediate state of scattering process. This assumption is
justified by the fact that energies of the crystal electric field and the
intersite interaction is smaller than the energy of multiplet structures. This
expression is found useful to calculate energy profiles with taking account of
the intra-Coulomb and spin-orbit interactions. Assuming the \Gamma_{8}-quartet
ground state, we construct the triple-\textbf{k} ground state, and analyze the
RXS spectra. The energy profiles are calculated in good agreement with the
experiment, providing a sound basis to previous phenomenological analyses.Comment: 10 pages, 7 figure
Relativistic many-body calculations of the Stark-induced amplitude of the 6P1/2 -7P1/2 transition in thallium
Stark-induced amplitudes for the 6P1/2 - 7P1/2 transition in Tl I are
calculated using the relativistic SD approximation in which single and double
excitations of Dirac-Hartree-Fock levels are summed to all orders in
perturbation theory. Our SD values alpha S = 368 a0 3 and beta S= 298 a 0 3 are
in good agreement with the measurements alpha S=377(8) a 0 3$ and beta S =
313(8) a 0 3 by D. DeMille, D. Budker, and E. D. Commins [Phys. Rev. A 50, 4657
(1994)]. Calculations of the Stark shifts in the 6P1/2 - 7P1/2 and 6P1/2 -
7S1/2 transitions are also carried out. The Stark shifts predicted by our
calculations agree with the most accurate measured values within the
experimental uncertainties for both transitions
Implementation of a Standardized Handoff System for a General Surgery Residency Program
Introduction:
The I-PASS Handoff Bundle is an evidence based standardized set of educational materials designed to decrease handoff failures in patient care.
Two of every three sentinel events , the most serious events reported to the Joint Commission, are due to failures of communication, including miscommunication during patient care handoffs.
Implementation of the I-PASS method results in decreased medical errors and preventable adverse events
There are few studies that evaluate this validated method in the context of a General Surgery resident program
We aim to implement the I-PASS system into the transition of care process for General Surgery residents at our institution, and to analyze of the quality of the handoff process before and after the implementation.https://jdc.jefferson.edu/patientsafetyposters/1047/thumbnail.jp
Alton Ochsner, MD (1896-1981): surgical pioneer and legacy linking smoking and disease.
Edward William Alton Ochsner kept a plain, metal card file in which he recorded close to 50 years worth of medical experiences, research, and insights. The most populated topics were filed as Cancer, Lung and Cancer, Bronchogenic. These reflected his areas of greatest interest, for which he would go on to produce groundbreaking work. Of his many lifetime accomplishments, he is perhaps best known for being the first to report a link between cigarette smoking and lung cancer. This was just one of the many ways in which Ochsner worked to effect social change. The establishment of the Ochsner Health System in New Orleans was born from this similar passion. Ochsner went on to become one of the giants of his generation as a result of this tireless work as a leader, educator, and mentor
Near-UV Observations of CS29497-030: New Constraints on Neutron-Capture Nucleosynthesis Processes
Employing spectra obtained with the new Keck I HIRES near-UV sensitive
detector, we have performed a comprehensive chemical composition analysis of
the binary blue metal-poor star CS29497-030. Abundances for 29 elements and
upper limits for an additional seven have been derived, concentrating on
elements largely produced via neutron-capture nucleosynthesis. Included in our
analysis are the two elements that define the termination point of the slow
neutron-capture process, lead and bismuth. We determine an extremely high value
of [Pb/Fe] = +3.65 +/- 0.07 (sigma = 0.13) from three features, supporting the
single-feature result obtained in previous studies. We also detect Bi for the
first time in a metal-poor star. Our derived Bi/Pb ratio is in accord with
those predicted from the most recent FRANEC calculations of the slow
neutron-capture process in low-mass AGB stars. We find that the neutron-capture
elemental abundances of CS29497-030 are best explained by an AGB model that
also includes very significant amounts of pre-enrichment of rapid
neutron-capture process material in the protostellar cloud out of which the
CS29497-030 binary system formed. Thus, CS29497-030 is both an ``r+s'' and
``extrinsic AGB'' star. Furthermore, we find that the mass of the AGB model can
be further constrained by the abundance of the light odd-element [Na/Fe] which
is sensitive to the neutron excess.Comment: 7 pages = 4 + 2 colour encapsulated postscript figures + 1 table; to
appear in ApJ Letters; additional jpeg figure available at
ftp://www.astro.caltech.edu/users/iii/cs2949703
Multiplet ligand-field theory using Wannier orbitals
We demonstrate how ab initio cluster calculations including the full Coulomb
vertex can be done in the basis of the localized, generalized Wannier orbitals
which describe the low-energy density functional (LDA) band structure of the
infinite crystal, e.g. the transition metal 3d and oxygen 2p orbitals. The
spatial extend of our 3d Wannier orbitals (orthonormalized Nth order muffin-tin
orbitals) is close to that found for atomic Hartree-Fock orbitals. We define
Ligand orbitals as those linear combinations of the O 2p Wannier orbitals which
couple to the 3d orbitals for the chosen cluster. The use of ligand orbitals
allows for a minimal Hilbert space in multiplet ligand-field theory
calculations, thus reducing the computational costs substantially. The result
is a fast and simple ab initio theory, which can provide useful information
about local properties of correlated insulators. We compare results for NiO,
MnO and SrTiO3 with x-ray absorption, inelastic x-ray scattering, and
photoemission experiments. The multiplet ligand field theory parameters found
by our ab initio method agree within ~10% to known experimental values
Non-resonant inelastic x-ray scattering involving excitonic excitations
In a recent publication Larson \textit{et al.} reported remarkably clear
- excitations for NiO and CoO measured with x-ray energies well below the
transition metal edge. In this letter we demonstrate that we can obtain an
accurate quantitative description based on a local many body approach. We find
that the magnitude of can be tuned for maximum sensitivity for
dipole, quadrupole, etc. excitations. We also find that the direction of
with respect to the crystal axes can be used as an equivalent to
polarization similar to electron energy loss spectroscopy, allowing for a
determination of the local symmetry of the initial and final state based on
selection rules. This method is more generally applicable and combined with the
high resolution available, could be a powerful tool for the study of local
distortions and symmetries in transition metal compounds including also buried
interfaces
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