Changes in soil dissolved organic carbon affect reconstructed history and projected future trends in surface water acidification

Preindustrial (1850s) and future (2060) streamwater chemistry of an anthropogenically acidified small catchment was estimated using the MAGIC model for three different scenarios for dissolved organic carbon (DOC) concentrations and sources. The highest modeled pH = 5.7 for 1850s as well as for 2060 (pH = 4.4) was simulated given the assumption that streamwater DOC concentration was constant at the 1993 level. A scenario accounting for an increase of DOC as an inverse function of ionic strength (IS) of soilwater and streamwater resulted in much lower preindustrial (pH = 4.9) and future recovery to (pH = 4.1) if the stream riparian zone was assumed to be the only DOC source. If upland soilwater (where significant DOC increase was observed at −5 and −15 cm) was also included, DOC was partly neutralized within the soil and higher preindustrial pH = 5.3 and future pH = 4.2 were estimated. The observed DOC stream flux was 2–4 times higher than the potential carbon production of the riparian zone, implying that this is unlikely to be the sole DOC source. Modeling based on the assumption that stream DOC changes are solely attributable to changes in the riparian zone appears likely to underestimate preindustrial pH

Assessing recovery from acidification of European surface waters in the year 2010: evaluation of projections made with the MAGIC model in 1995

In 1999 we used the MAGIC (Model of Acidification of Groundwater In Catchments) model to project acidification of acid-sensitive European surface waters in the year 2010, given implementation of the Gothenburg Protocol to the Convention on Long-Range Transboundary Air Pollution (LRTAP). A total of 202 sites in 10 regions in Europe were studied. These forecasts can now be compared with measurements for the year 2010, to give a “ground truth” evaluation of the model. The prerequisite for this test is that the actual sulfur and nitrogen deposition decreased from 1995 to 2010 by the same amount as that used to drive the model forecasts; this was largely the case for sulfur, but less so for nitrogen, and the simulated surface water [NO3–] reflected this difference. For most of the sites, predicted surface water recovery from acidification for the year 2010 is very close to the actual recovery observed from measured data, as recovery is predominantly driven by reductions in sulfur deposition. Overall these results show that MAGIC successfully predicts future water chemistry given known changes in acid deposition

W&L Law Fall Scholarship Celebration 2022

On October 6, 2022, the Washington and Lee Law Library hosted the fourth W&L Law Fall Scholarship Celebration. The event was co-sponsored by the Frances Lewis Law Center and took place in the Law Library\u27s main reading room from 5:00 to 7:00 p.m. On display were dozens of scholarly articles, books, and chapters authored by the W&L Law faculty and student body between October 2019 and October 2022, with hundreds of additional works accessible online through the Scholarly Commons institutional repository. Faculty, librarians, staff, and administrators mingled with law students over hors d\u27oeuvres and wine to peruse the formidable scholarly output of the W&L Law community. Spouses, alumni, faculty from W&L\u27s undergraduate campus, and others with ties to the University were also in attendance. Melanie Wilson, dean of W&L Law; Christopher Seaman, director of the Frances Lewis Law Center; Andrew Christensen, Head of Digital Initiatives and Outreach; and Jenny Mitchell, Archivist and Special Collections Librarian, provided welcoming remarks, alongside W&L Law Library director Michelle Cosby, who also led all attendees in a celebratory toast. The event program, which includes a list of the scholarship on display, is available to download in PDF. Photos taken at the event are also available to view in the W&L Law Scholarly Commons Image Gallery, and a video recording of the welcoming remarks is linked above on this page

Trans-disciplinary Collaboration to Enhance Coastal Resilience: Envisioning a National Community Modeling Initiative

This section presents a synthesis of the major outcomes from the coastal resilience workshops. This paper is based on the presentations and discussions that have been guided by the Chair and numerous stakeholders such as university researchers, Non Governmental Organizations, and federal, state, and local governments. SURA’s workshop series promotes collaboration and fully-integrated processes, and it should be noted that the actual workshop is only a first step; the follow-up work is likely to continue for years. The major results from this workshop relate to the development of trans-disciplinary approaches that help a community to bounce back after hazardous events such as hurricanes, coastal storms, and flooding – rather than simply rebuilding in the aftermath. The workshops have included participants from academia, industry, and government. They provide opportunity to share coastal resilience research and projects focused on helping the community to rebound quickly from climate and extreme weather related events, including sea level rise. The purpose of the paper is to showcase how social and natural scientists can collaborate to reduce the negative human health, environmental, and economic effects of coastal hazards

Trans-disciplinary Collaboration to Enhance Coastal Resilience: Envisioning a National Community Modeling Initiative

This section presents a synthesis of the major outcomes from the coastal resilience workshops. This paper is based on the presentations and discussions that have been guided by the Chair and numerous stakeholders such as university researchers, Non Governmental Organizations, and federal, state, and local governments. SURA’s workshop series promotes collaboration and fully-integrated processes, and it should be noted that the actual workshop is only a first step; the follow-up work is likely to continue for years. The major results from this workshop relate to the development of trans-disciplinary approaches that help a community to bounce back after hazardous events such as hurricanes, coastal storms, and flooding – rather than simply rebuilding in the aftermath. The workshops have included participants from academia, industry, and government. They provide opportunity to share coastal resilience research and projects focused on helping the community to rebound quickly from climate and extreme weather related events, including sea level rise. The purpose of the paper is to showcase how social and natural scientists can collaborate to reduce the negative human health, environmental, and economic effects of coastal hazards

Glastir Monitoring & Evaluation Programme. First year annual report

The Welsh Government has commissioned a comprehensive new ecosystem monitoring and evaluation programme to monitor the effects of Glastir, its new land management scheme, and to monitor progress towards a range of international biodiversity and environmental targets. A random sample of 1 km squares stratified by landcover types will be used both to monitor change at a national level in the wider countryside and to provide a backdrop against which intervention measures are assessed using a second sample of 1 km squares located in areas eligible for enhanced payments for advanced interventions. Modelling in the first year has forecast change based on current understanding, whilst a rolling national monitoring programme based on an ecosystem approach will provide an evidence-base for on-going, adaptive development of the scheme by Welsh Government. To our knowledge, this will constitute the largest and most in-depth ecosystem monitoring and evaluation programme of any member state of the European Union

Earth-Abundant Oxygen Electrocatalysts for Alkaline Anion-Exchange-Membrane Water Electrolysis: Effects of Catalyst Conductivity and Comparison with Performance in Three-Electrode Cells

Anion exchange membrane (AEM) electrolysis is a promising technology to produce hydrogen through the splitting of pure water. In contrast to proton-exchange-membrane (PEM) technology, which requires precious-metal oxide anodes, AEM systems allow for the use of earth-abundant anode catalysts. Here we report a study of first-row transition-metal (oxy)hydroxide/oxide catalyst powders for application in AEM devices and compare physical properties and performance to benchmark IrO x catalysts as well as typical catalysts for alkaline electrolyzers. We show that the catalysts' oxygen-evolution activity measured in alkaline electrolyte using a typical three-electrode cell is a poor indicator of performance in the AEM system. The best oxygen-evolution-reaction (OER) catalysts in alkaline electrolyte, NiFeO x H y oxyhydroxides, are the worst in AEM electrolysis devices where a solid alkaline electrolyte is used along with a pure water feed. NiCoO x -based catalysts show the best performance in AEM electrolysis. The performance can be further improved by adding Fe species to the particle surface. We attribute the differences in performance in part to differences in the electrical conductivity of the catalyst phases, which are also measured and reported

Qualitative impact assessment of land management interventions on ecosystem services ("QEIA"). Report-1: executive summary QEIA evidence review & integrated assessment

The focus of this project was to provide a rapid qualitative assessment of land management interventions on Ecosystem Services (ES) proposed for inclusion in Environmental Land Management (ELM) schemes. This involved a review of the current evidence base by ten expert teams drawn from the independent research community in a consistent series of ten Evidence Reviews. These reviews were undertaken rapidly at Defra’s request and together captured more than 2000 individual sources of evidence. These reviews were then used to inform an Integrated Assessment (IA) to provide a more accessible summary of these evidence reviews with a focus on capturing the actions with the greatest potential magnitude of change for the intended ES and their potential co-benefits and trade-offs across the Ecosystem Services and Ecosystem Services Indicators. The final IA table captured scores for 741 actions across 8 Themes, 33 ES and 53 ES-indicators. This produced a total possible matrix of 39,273 scores. It should be noted that this piece of work is just one element of the wider underpinning work Defra has commissioned to support the development of the ELM schemes. The project was carried out in two phases with the environmental and provisioning services commissioned in Phase 1 and cultural and regulatory services in a follow-on Phase 2. Due to the urgency of the need for these evidence reviews, there was insufficient time for systematic reviews and therefore the reviews relied on the knowledge of the team of the peer reviewed and grey literature with some rapid additional checking of recent reports and papers. This limitation of the review process was clearly explained and understood