Harmonization of space-borne infra-red sensors measuring sea surface temperature

Sea surface temperature (SST) is observed by a constellation of sensors, and SST retrievals are commonly combined into gridded SST analyses and climate data records (CDRs). Differential biases between SSTs from different sensors cause errors in such products, including feature artefacts. We introduce a new method for reducing differential biases across the SST constellation, by reconciling the brightness temperature (BT) calibration and SST retrieval parameters between sensors. We use the Advanced Along-Track Scanning Radiometer (AATSR) and the Sea and Land Surface Temperature Radiometer (SLSTR) as reference sensors, and the Advanced Very High Resolution Radiometer (AVHRR) of the MetOp-A mission to bridge the gap between these references. Observations across a range of AVHRR zenith angles are matched with dual-view three-channel skin SST retrievals from the AATSR and SLSTR. These skin SSTs act as the harmonization reference for AVHRR retrievals by optimal estimation (OE). Parameters for the harmonized AVHRR OE are iteratively determined, including BT bias corrections and observation error covariance matrices as functions of water-vapor path. The OE SSTs obtained from AVHRR are shown to be closely consistent with the reference sensor SSTs. Independent validation against drifting buoy SSTs shows that the AVHRR OE retrieval is stable across the reference-sensor gap. We discuss that this method is suitable to improve consistency across the whole constellation of SST sensors. The approach will help stabilize and reduce errors in future SST CDRs, as well as having application to other domains of remote sensing

Pavlovian conditioning-induced hallucinations result from overweighting of perceptual priors

Some people hear voices that others do not, but only some of those people seek treatment. Using a Pavlovian learning task, we induced conditioned hallucinations in four groups of people who differed orthogonally in their voice-hearing and treatment-seeking statuses. People who hear voices were significantly more susceptible to the effect. Using functional neuroimaging and computational modeling of perception, we identified processes that differentiated voice-hearers from non-voice-hearers and treatment-seekers from non-treatment-seekers and characterized a brain circuit that mediated the conditioned hallucinations. These data demonstrate the profound and sometimes pathological impact of top-down cognitive processes on perception and may represent an objective means to discern people with a need for treatment from those without

Gulf Stream\u27s Induced Sea Level Rise and Variability along the U.S. Mid-Atlantic Coast

Recent studies indicate that the rates of sea level rise (SLR) along the U. S. mid-Atlantic coast have accelerated in recent decades, possibly due to a slowdown of the Atlantic Meridional Overturning Circulation (AMOC) and its upper branch, the Gulf Stream (GS). We analyzed the GS elevation gradient obtained from altimeter data, the Florida Current transport obtained from cable measurements, the North Atlantic Oscillation (NAO) index, and coastal sea level obtained from 10 tide gauge stations in the Chesapeake Bay and the mid-Atlantic coast. An Empirical Mode Decomposition/Hilbert-Huang Transformation (EMD/HHT) method was used to separate long-term trends from oscillating modes. The coastal sea level variations were found to be strongly influenced by variations in the GS on timescales ranging from a few months to decades. It appears that the GS has shifted from a 6-8 year oscillation cycle to a continuous weakening trend since about 2004 and that this trend may be responsible for recent acceleration in local SLR. The correlation between long-term changes in the coastal sea level and changes in the GS strength was extremely high (R = -0.85 with more than 99.99% confidence that the correlation is not zero). The impact of the GS on SLR rates over the past decade seems to be larger in the southern portion of the mid-Atlantic Bight near Cape Hatteras and is reduced northward along the coast. The study suggests that regional coastal sea level rise projections due to climate change must take into account the impact of spatial changes in ocean dynamics

Investigating discrepancies between experimental solid-state NMR and GIPAW calculation : NC–N 13C and OH⋯O 1H chemical shifts in pyridinium fumarates and their cocrystals

An NMR crystallography analysis is presented for four solid-state structures of pyridine fumarates and their cocrystals, using crystal structures deposited in the Cambridge Crystallographic Data Centre, CCDC. Experimental one-dimensional, one-pulse 1H and 13C cross-polarisation (CP) magic-angle spinning (MAS) nuclear magnetic resonance (NMR) and two-dimensional 14N–1H heteronuclear multiple-quantum coherence MAS NMR spectra are compared with gauge-including projector augmented wave (GIPAW) calculations of the 1H and 13C chemical shifts and the 14N shifts that additionally depend on the quadrupolar interaction. Considering the high ppm (>10 ppm) 1H resonances, while there is good agreement (within 0.4 ppm) between experiment and GIPAW calculation for the hydrogen-bonded NH moieties, the hydrogen-bonded fumaric acid OH resonances are 1.2–1.9 ppm higher in GIPAW calculation as compared to experiment. For the cocrystals of a salt and a salt formed by 2-amino-5-methylpyridinium and 2-amino-6-methylpyridinium ions, a large discrepancy of 4.2 and 5.9 ppm between experiment and GIPAW calculation is observed for the quaternary ring carbon 13C resonance that is directly bonded to two nitrogens (in the ring and in the amino group). By comparison, there is excellent agreement (within 0.2 ppm) for the quaternary ring carbon 13C resonance directly bonded to the ring nitrogen for the salt and cocrystal of a salt formed by 2,6-lutidinium and 2,5-lutidine, respectively

35 Cl ‐ 1 H heteronuclear correlation MAS NMR experiments for probing pharmaceutical salts

Heteronuclear multiple-quantum coherence (HMQC) pulse sequences for establishing heteronuclear correlation in solid-state NMR between 35Cl and 1H atoms in chloride salts under fast (60 kHz) magic-angle spinning (MAS) and at high magnetic field (a 1H Larmor frequency of 850 MHz) are investigated. Specifically, recoupling of the 35Cl - 1H dipolar interaction using rotary resonance recoupling with phase inversion every rotor period or the symmetry based SR421 pulse sequence are compared. In our implementation of the PT (population-transfer)-D-HMQC experiment, the satellite transitions of the 35Cl nuclei are saturated with an off-resonance WURST sweep, at a low nutation frequency, over the second spinning sideband, whereby the WURST pulse must be of the same duration as the recoupling time. Numerical simulations of the 35Cl - 1H MAS D-HMQC experiment performed separately for each crystallite orientation in a powder provide insight into the orientation dependence of changes in the second-order quadrupolar broadened 35Cl MAS NMR lineshape under the application of dipolar recoupling. Two-dimensional 35Cl - 1H PT-D-HMQC MAS NMR spectra are presented for the amino acids glycine·HCl and L-tyrosine·HCl and the pharmaceuticals cimetidine·HCl, amitriptyline·HCl and lidocaine·HCl·H2O. Experimentally observed 35Cl lineshapes are compared with those simulated for 35Cl chemical shift and quadrupolar parameters as calculated using the gauge-including projector-augmented wave (GIPAW) method: the calculated quadrupolar product (PQ) values exceed those measured experimentally by a factor of between 1.3 and 1.9

The Copernicus surface velocity platform drifter with barometer and reference sensor for temperature (SVP-BRST): genesis, design, and initial results

To support calibration and validation of satel- lite sea surface temperature (SST) retrievals, over 60 high- resolution SST (HRSST) drifting buoys were deployed at sea between 2012 and 2017. Their data record is reviewed here. It is confirmed that sea state and immersion depth play an important role in understanding the data collected by such buoys and that the SST sensors need adequate insu- lation. In addition, calibration verification of three recovered drifters suggests that the sensor drift is low, albeit negative at around −0.01 K year−1. However, the statistical significance of these results is limited, and the calibration procedure could not be exactly reproduced, introducing additional uncertain- ties into this drift assessment. Based on lessons learnt from these initial buoys, a new sensor package for the Surface Velocity Platform with Barometer (SVP-B) was designed to serve calibration of SST retrievals by European Union’s Copernicus satellites. The novel sensor package includes an HRSST sensor calibrated by a metrology laboratory. The sensor includes a pressure probe to monitor immersion depth in calm water and acquires SST data at 1 Hz over a 5 min in- terval every hour. This enables the derivation of mean SST as well as several percentiles of the SST distribution. The HRSST sensor is calibrated with an uncertainty better than 0.01 K. Analysis of the data collected by two prototypes de- ployed in the Mediterranean Sea shows that the buoys are able to capture small-scale SST variations. These variations are found to be smaller when the sea state is well mixed and when the buoys are located within eddy cores. This affects the drifter SST data representativeness, which is an aspect of importance for optimal use of these data

Generation of angular-momentum-dominated electron beams from a photoinjector

Various projects under study require an angular-momentum-dominated electron beam generated by a photoinjector. Some of the proposals directly use the angular-momentum-dominated beams (e.g. electron cooling of heavy ions), while others require the beam to be transformed into a flat beam (e.g. possible electron injectors for light sources and linear colliders). In this paper, we report our experimental study of an angular-momentum-dominated beam produced in a photoinjector, addressing the dependencies of angular momentum on initial conditions. We also briefly discuss the removal of angular momentum. The results of the experiment, carried out at the Fermilab/NICADD Photoinjector Laboratory, are found to be in good agreement with theoretical and numerical models.Comment: 8 pages, 7 figures, submitted to Phys. Rev. ST Accel. Beam