273 research outputs found

    Effect of pH and nanoclay content on the morphology and physicochemicalproperties of soy protein/montmorillonite nanocomposite obtained byextrusion

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    The present work attempts to clarify the influence of montmorillonite nanoclay content and pH on the me-chanical properties of extruded soy protein nanocomposites. The mechanical behaviour is dominated by theformation of positive synergies between protein and nanoclay above a nanoclay concentration threshold.Moreover, the presence of nanoclay can improve water uptake. The pH also exerts a strong influence on me-chanical and water absorption properties, although montmorillonite tend to reduce this effect.Eventually, this study put forward the feasibility of using a combination of soy protein and montmorillonite toobtain potentially attractive biodegradable nanocomposite materials, processed by means of a simple and easilyscalable twin-screw extruder.Junta de Andalucía (project TEP-6134)Ministerio de Economía y Competitividad (CTQ2015-71164-P

    Erosion caused by propeller jets in a low energy harbour basin

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    This is an Accepted Manuscript of an article published by Taylor & Francis Group in Journal of Hydraulic Research on January, 2017, available online at: http://www.tandfonline.com/10.1080/00221686.2016.1252801Field data of a harbour basin are compared with analytical formulations for predicting maximum scouring depth due to propeller jets. Spatial data analysis of seven-year biannual bathymetries quantifies the evolution of the scouring hole along with the sedimentation process within a harbour basin. The maximum scouring depth is found to be of the order of the propeller diameter with a maximum scouring rate within the first six months of docking manoeuvring. Three of the analysed expressions yielded realistic results while observed discrepancies between the theoretical predictions and field data are related to scaling factors. The outcomes of this analysis can be extrapolated to other harbours to improve their management. The obtained results highlight the importance of field data in developing combined physical and numerical models.Peer ReviewedPostprint (author's final draft

    Hydrology influences carbon flux through metabolic pathways in the hypolimnion of a Mediterranean reservoir

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    Global change is modifying meteorological and hydrological factors that influence the thermal regime of water bodies. These modifications can lead to longer stratification periods with enlarged hypolimnetic anoxic periods, which can promote heterotrophic anaerobic processes and alter reservoir carbon cycling. Here, we quantified aerobic and anaerobic heterotrophic processes (aerobic respiration, denitrification, iron and manganese reduction, sulfate reduction, and methanogenesis) on dissolved inorganic carbon (DIC) production in the hypolimnion of a Mediterranean reservoir (El Gergal, Spain) under two contrasting hydrological conditions: a wet year with heavy direct rainfall and frequent water inputs from upstream reservoirs, and a dry year with scarce rainfall and negligible water inputs. During the wet year, water inputs and rainfall induced low water column thermal stability and earlier turnover. By contrast, thermal stratification was longer and more stable during the dry year. During wet conditions, we observed lower DIC accumulation in the hypolimnion, mainly due to weaker sulfate reduction and methanogenesis. By contrast, longer stratification during the dry year promoted higher hypolimnetic DIC accumulation, resulting from enhanced methanogenesis and sulfate reduction, thus increasing methane emissions and impairing reservoir water quality. Aerobic respiration, denitrification and metal reduction produced a similar amount of DIC in the hypolimnion during the two studied years. All in all, biological and geochemical (calcite dissolution) processes explained most of hypolimnetic DIC accumulation during stratification regardless of the hydrological conditions, but there is still ~ 30% of hypolimnetic DIC production that cannot be explained by the processes contemplated in this study and the assumptions made.This research was funded by project Alter-C (PID2020-114024GB-C31, PID2020-114024GB-C32, PID2020-114024GB-C33) of Spanish Ministry of Science and Innovation (Spanish Research Agency, AEI). JJM-P was supported by a Spanish FPI grant (RE2018-083596). EMASESA staff provide essential technical support during field surveys. R.M. acknowledges funding from Generalitat de Catalunya through the Consolidated Research Group 2017SGR1124 and the CERCA programme. Open Access funding provided thanks to the CRUE-CSIC agreement with Springer Nature. Funding for open access charge: Universidad de Málaga / CBUA

    Validation of the upper limb functional index on breast cancer survivor

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    Breast cancer survivors (BCS) may face functional alterations after surgical intervention. Upper Limb Disorders (ULDs) are highly prevalent even years after a diagnosis. Clinicians may assess the upper limbs after breast cancer. The Upper Limb Functional Index (ULFI) has been validated across different populations and languages. This study aimed to assess the psychometric properties of the Upper Limb Functional Index Spanish version (ULFI-Sp) in the BCS. Methods: A psychometric validation study of the ULFI-Sp was conducted on 216 voluntary breast cancer survivors. The psychometric properties were as follows: analysis of the factor structure by maximum likelihood extraction (MLE), internal consistency, and construct validity by confirmatory factor analysis (CFA). Results: The factor structure was one-dimensional. ULFI-Sp showed a high internal consistency for the total score (α = 0.916) and the regression score obtained from MLE (α = 0.996). CFA revealed a poor fit, and a new 14-item model (short version) was further tested. The developed short version of the ULFI-SP is preferable to assess upper limb function in Spanish BCS. Conclusions: Given the high prevalence of ULD in this population and the broader versions of ULFI across different languages, this study’s results may be transferred to clinical practice and integrated as part of upper limb assessment after breast cancer.Partial funding for open access charge: Universidad de Málag

    Forearm Muscle Activity During the Handgrip Test in Breast Cancer Survivors: A Cross-Sectional Study

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    We recruited 102 breast cancer survivors at a secondary care in Malaga. Included breast cancer survivors showed a good upper limb functionality but a reduced forearm muscle activity. Forearm muscle activity showed a poor significant correlation with the cancer-related fatigue . Handgrip strength also showed a poor correlation with the upper limb functionality. Both outcomes tended to lower values with higher levels of cancer-related fatigue. Introduction/Background: Breast cancer survivors (BCS) frequently show upper limb dysfunctions. The forearm muscle activity measured by surface electromyography (sEMG) in this population has not been studied. This study aimed to describe forearm muscle activity in BCS, as well as to assess its possible relationship with other variables related to upper limb functionality and cancer-related fatigue (CRF). Materials and Methods: A cross-sectional study was carried out including 102 BCS as volunteers at a secondary care in Malaga, Spain. BCS were included if they were aged between 32 and 70 years old, without evidence of cancer recurrence at the time of recruitment. The forearm muscle activity (microvolts, μV) was assessed by sEMG during the handgrip test. The handgrip strength was assessed by dynamometry (kg), the upper limb functionality (%) was measured by the upper limb functional index (ULFI) question- naire and the CRF was also assessed by revised Piper Fatigue Scale (0-10 points). Results: BCS reported reduced forearm muscle activity (287.88 μV) and reduced handgrip strength (21.31 Kg), a good upper limb functionality (68.85%), and a moderate cancer-related fatigue (4.74). Forearm muscle activity showed a poor significant correlation (r = –0.223, P = .038) with the CRF. Handgrip strength showed a poor correlation with the upper limb functionality (r = 0.387, P < .001) and age (r=-0.200, P = .047)...Funding for open access charge: Universidad de Málaga /CBU

    Anàlisi sociodemogràfica a través de les seccions censals de Castelldefels, Gavà i Viladecans

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    Aquest treball de fi de grau es basa en una anàlisi sociodemogràfic de tres municipis diferents, Castelldefels, Gavà i Viladecans, a través de les seccions censals. L'objectiu és trobar semblances i diferències entre aquests tres municipis a partir de dades sociodemogràfiques del Cens de Població i Habitatge i les Cobertes del Sòl i observar com és la població, no pas on viu. Els resultats són expressats a través de diferents mapes generats a partir de les dades.Este trabajo de fin de grado se basa en un análisis sociodemografico de tres municipios diferentes, Castelldefels, Gavà y Viladecans a partir de las secciones censales. El objetivo es encontrar parecidos y diferencias entre estos tres municipios a partir de datos sociodemograficos del Censo de Población y Vivienda i Cubiertas del Suelo y observar como es la población, no donde vive. Los resultados son representados a partir de diferentes mapas generados gracias a los datos.This final degree project is based on a socio-demographic analysis of three different municipalities, Castelldefels, Gavà and Viladecans, through the census tracts . The aim is to find similarities and differences between these three municipalities based on socio-demographic data from the Population and Housing Census and Land Cover and to observe what the population is like, not where it lives. The results are expressed through different maps generated from the data

    Management of hyponatremia associated with acute porphyria-proposal for the use of tolvaptan

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    Hyponatremia is a common feature during the neurovisceral acute attacks which characterize hepatic porphyrias, as well as a sign of its severity. Therapeutic options for first-line acute attacks are intravenous administration of glucose and/or exogenous heme. The former treatment can aggravate hyponatremia by dilution and cause seizures; thus, the correction of hyponatremia must be carried out with extreme caution. This review summarizes recommendations for the management of hyponatremia during acute episodes of porphyria. Hyponatremia should be corrected slowly and seizures treated with medications in order to not exacerbate motor and sensory axonal neuropathy. The syndrome of inappropriate antidiuretic hormone secretion (SIADH) is considered a frequent cause of hyponatremia in acute porphyrias and must be identified as a symptom of an acute porphyria attack. Tolvaptan produces aquaresis and is considered a safe drug in porphyria. However, its use has only been reported in isolated cases during a porphyria attack. The convenience and usefulness of this drug in acute porphyria are discussed
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