Rapid thermal rejuvenation of high-crystallinity magma linked to porphyry copper deposit formation; evidence from the Koloula Porphyry Prospect, Solomon Islands

Magmas containing the components needed to form porphyry copper deposits are relatively common within arcs, yet mineralising events are uncommon within the long-lived magmatic systems that host them. Understanding what causes the transition from barren to productive intrusions is critical to the development of conceptual deposit models. We have constrained the tempo of pre- and syn-mineralisation magmatic events in relationship to the thermal evolution of the plutonic body that underlies one of the world's youngest exposed plutonic–porphyry systems, the Inamumu Zoned Pluton, Koloula Porphyry Prospect, Solomon Islands. High precision ID-TIMS U–Pb dates of texturally and chemically characterised zircons indicate pluton emplacement over 50% crystals) state, past the point of rheological lock-up. We estimate that thermal rejuvenation of the deeper high-crystallinity magma and generation of a mobile melt fraction may have occurred ≤10 kyr before its transport and emplacement within the porphyry environment. The underlying pluton likely cooled and returned to high-crystallinity states prior to subsequent remobilisation-emplacement events. Titanium-in-zircon geothermometry and whole-rock geochemistry suggest pre-mineralisation intrusions were remobilised by mixing of a silicic magma with a high-temperature, less-evolved melt. In contrast, syn-mineralisation melts were most likely remobilised by the percolation of hot volatiles exsolved from contemporaneous less-evolved intrusions cooling beneath the crystalline silicic magma. The evidence for the rapid thermal rejuvenation and long term storage of highly crystalline silicic magmas is consistent with previous studies that indicate two components of exsolved volatiles contribute to ore forming fluids. We conclude that the liberation of crystal-rich porphyry copper deposit forming magmas, and the addition of the chemical components required for ore formation, are intrinsically linked to the volatiles released during the recharge of less-evolved melt into a highly crystalline silicic magma

Pacific 187Os/188Os isotope chemistry and U-Pb geochronology: synchroneity of global Os isotope change across OAE 2

Studies of OAE 2 sections beyond the Atlantic Ocean, Western Interior Seaway (WIS) and European pelagic shelf are limited. Here, we present initial osmium isotope stratigraphy (187Os/188Os–Osi) from two proto-Pacific sites that span the Cenomanian–Turonian boundary interval (CTBI): the Yezo Group (YG) section, Hokkaido, Japan, and the Great Valley Sequence (GVS), California, USA; to evaluate the 187Os/188Os seawater chemistry of the proto-Pacific. Additionally we combine new 206Pb/238U zircon CA-ID-TIMS geochronology from five volcanic tuff horizons of the Yezo Group section to test and facilitate inter-basinal integration with the WIS using radio-isotopically constrained age–depth models for both sections, and quantitatively constrain the absolute timing and duration of events across the CTBI. The YG shows an almost identical Osi profile to that of the WIS, and very similar to that of other sites of the proto-Atlantic and European pelagic oceans (Turgeon and Creaser, 2008 and Du Vivier et al., 2014). The characteristics of the Osi profile are radiogenic and heterogeneous (∼0.55–0.85) prior to the OAE 2, and synchronous with the inferred OAE 2 onset the Osi abruptly become unradiogenic and remain relatively homogeneous (∼0.20–0.30) before showing a gradual return to more radiogenic View the MathML source throughout the middle to late OAE 2. A206Pb/238U zircon age of an interbedded tuff (HK017) in the adjacent horizon to the first unradiogenic Osi value constrains the age of the Osi inflection at 94.44±0.14 Ma. This age, including uncertainty, agrees with the interpolated age of the same point in the Osi profile (94.28±0.25 Ma) in the only other dated OAE 2 section, the WIS; indicating a coeval shift in seawater chemistry associated with volcanism at the OAE 2 onset at the levels of temporal resolution (ca. 0.1 Myr). Further, prior to the onset of OAE 2 an enhanced radiogenic inflection in the Osi profile of the YG is correlative, within uncertainty, with a similar trend in the WIS based on the U–Pb age–depth model. The interpolated ages, 94.78±0.12 Ma and 94.66±0.25 Ma for this Osi inflection in the YG and WIS, respectively, indicate that palaeocirculation was sufficient to simultaneously influence transbasinal seawater chemistry. In contrast, the pre-OAE 2 Osi profile for the GVS is disparate to that of the YG and those of the proto-Atlantic and European pelagic shelf locations. We interpret the pre OAE 2 heterogeneous Osi values (0.30–0.95) to record a palaeobasin that was regionally influenced interchangeably by both unradiogenic (hydrothermal flux) and radiogenic (continental flux) Os. We conclude that the Osi profiles from the proto-Pacific sections record both trends that are consistent globally (OAE 2 onset, syn and post OAE 2), but also show regional differences (pre OAE 2) between OAE 2 sections worldwide. As such the Osi profiles coupled with U–Pb geochronology facilitate the correlation of OAE 2 stratigraphy, and demonstrate both regional and global ocean dynamics

Multiple Palaeoproterozoic carbon burial episodes and excursions

Organic-rich rocks (averaging 2–5% total organic carbon) and positive carbonate-carbon isotope excursions (View the MathML source and locally much higher, i.e. the Lomagundi-Jatuli Event) are hallmark features of Palaeoproterozoic successions and are assumed to archive a global event of unique environmental conditions following the c. 2.3 Ga Great Oxidation Event. Here we combine new and published geochronology that shows that the main Palaeoproterozoic carbon burial episodes (CBEs) preserved in Russia, Gabon and Australia were temporally discrete depositional events between c. 2.10 and 1.85 Ga. In northwest Russia we can also show that timing of the termination of the Lomagundi-Jatuli Event may have differed by up to 50 Ma between localities, and that Ni mineralisation occurred at c. 1920 Ma. Further, CBEs have traits in common with Mesozoic Oceanic Anoxic Events (OAEs); both are exceptionally organic-rich relative to encasing strata, associated with contemporaneous igneous activity and marked by organic carbon isotope profiles that exhibit a stepped decrease followed by a stabilisation period and recovery. Although CBE strata are thicker and of greater duration than OAEs (100 s of metres versus metres, ∼106 years versus ∼105 years), their shared characteristics hint at a commonality of cause(s) and feedbacks. This suggests that CBEs represent processes that can be either basin-specific or global in nature and a combination of circumstances that are not unique to the Palaeoproterozoic. Our findings urge circumspection and re-consideration of models that assume CBEs are a Deep Time singularity

Accelerating Neoproterozoic research through scientific drilling

No abstract available

Using ignimbrites to quantify structural relief growth and understand deformation processes: implications for the development of the Western Andean Slope, northernmost Chile

Large-volume ignimbrites are excellent spatial and temporal markers for local deformation and structural relief growth because they completely inundate and bury the underlying paleotopography and leave planar surfaces with relatively uniform, low-gradient slopes dipping less than 2°. Using one of these planar surfaces as a reference frame, we employed a line-balanced technique to reconstruct the original morphology of an ignimbrite that has undergone postemplacement deformation. This method allowed us to constrain both the amount of posteruptive deformation and the topography of the pre-eruptive paleolandscape. Our test case was the unwelded surface of the 21.9 Ma Cardones ignimbrite, located on the western slope of the Central Andes in northernmost Chile (18°20′S). By reconstructing the original surface slope of this ignimbrite, we demonstrate that the pre–21.9 Ma topography of the Western Andean Slope was characterized by structural relief growth and erosion in the east, and the creation of accommodation space and sedimentation in the west. The paleoslope at that time was dissected by river valleys of up to 450 ± 150 m deep that accumulated great thicknesses (>1000 m) of the Cardones ignimbrite, and likely controlled the location of the present-day Lluta Quebrada as a result of differential welding compaction of the ignimbrite. Our reconstruction suggests that growth of the Western Andean Slope had already started by ca. 23 Ma, consistent with slow and steady models for uplift of the Central Andes. Subsequent deformation in the Miocene generated up to 1725 ± 165 m of structural relief, of which more than 90% can be attributed to fault-related folding of the ∼40-km-wide Huaylillas anticline. Uplift related to regional forearc tilting is less than 10% and could have been zero. The main phase of folding likely occurred in the mid- to late Miocene and had ceased by ca. 6 Ma

Constraints on cosmic hemispherical power anomalies from quasars

Recent analyses of the cosmic microwave background (CMB) maps from the WMAP satellite have uncovered evidence for a hemispherical power anomaly, i.e. a dipole modulation of the CMB power spectrum at large angular scales with an amplitude of +/-14 percent. Erickcek et al have put forward an inflationary model to explain this anomaly. Their scenario is a variation on the curvaton scenario in which the curvaton possesses a large-scale spatial gradient that modulates the amplitude of CMB fluctuations. We show that this scenario would also lead to a spatial gradient in the amplitude of perturbations sigma_8, and hence to a dipole asymmetry in any highly biased tracer of the underlying density field. Using the high-redshift quasars from the Sloan Digital Sky Survey, we find an upper limit on such a gradient of |nabla sigma_8|/sigma_8<0.027/r_{lss} (99% posterior probability), where r_{lss} is the comoving distance to the last-scattering surface. This rules out the simplest version of the curvaton spatial gradient scenario.Comment: matches JCAP accepted version (minor revisions

Model study on the photoassociation of a pair of trapped atoms into an ultralong-range molecule

Using the method of quantum-defect theory, we calculate the ultralong-range molecular vibrational states near the dissociation threshold of a diatomic molecular potential which asymptotically varies as $-1/R^3$. The properties of these states are of considerable interest as they can be formed by photoassociation (PA) of two ground state atoms. The Franck-Condon overlap integrals between the harmonically trapped atom-pair states and the ultralong-range molecular vibrational states are estimated and compared with their values for a pair of untrapped free atoms in the low-energy scattering state. We find that the binding between a pair of ground-state atoms by a harmonic trap has significant effect on the Franck-Condon integrals and thus can be used to influence PA. Trap-induced binding between two ground-state atoms may facilitate coherent PA dynamics between the two atoms and the photoassociated diatomic molecule.Comment: 11 pages, 4 figures, to appear in Phys. Rev. A (September, 2003

Constraining Primordial Non-Gaussianity with High-Redshift Probes

We present an analysis of the constraints on the amplitude of primordial non-Gaussianity of local type described by the dimensionless parameter $f_{\rm NL}$. These constraints are set by the auto-correlation functions (ACFs) of two large scale structure probes, the radio sources from NRAO VLA Sky Survey (NVSS) and the quasar catalogue of Sloan Digital Sky Survey Release Six (SDSS DR6 QSOs), as well as by their cross-correlation functions (CCFs) with the cosmic microwave background (CMB) temperature map (Integrated Sachs-Wolfe effect). Several systematic effects that may affect the observational estimates of the ACFs and of the CCFs are investigated and conservatively accounted for. Our approach exploits the large-scale scale-dependence of the non-Gaussian halo bias. The derived constraints on {$f_{\rm NL}$} coming from the NVSS CCF and from the QSO ACF and CCF are weaker than those previously obtained from the NVSS ACF, but still consistent with them. Finally, we obtain the constraints on $f_{\rm NL}=53\pm25$ ($1\,\sigma$) and $f_{\rm NL}=58\pm24$ ($1\,\sigma$) from NVSS data and SDSS DR6 QSO data, respectively.Comment: 16 pages, 8 figures, 1 table, Accepted for publication on JCA

Cross-Correlation of the Cosmic Microwave Background with the 2MASS Galaxy Survey: Signatures of Dark Energy, Hot Gas, and Point Sources

We cross-correlate the Cosmic Microwave Background (CMB) temperature anisotropies observed by the Wilkinson Microwave Anisotropy Probe (WMAP) with the projected distribution of extended sources in the Two Micron All Sky Survey (2MASS). By modelling the theoretical expectation for this signal, we extract the signatures of dark energy (Integrated Sachs-Wolfe effect;ISW), hot gas (thermal Sunyaev-Zeldovich effect;thermal SZ), and microwave point sources in the cross-correlation. Our strongest signal is the thermal SZ, at the 3.1-3.7 \sigma level, which is consistent with the theoretical prediction based on observations of X-ray clusters. We also see the ISW signal at the 2.5 \sigma level, which is consistent with the expected value for the concordance LCDM cosmology, and is an independent signature of the presence of dark energy in the universe. Finally, we see the signature of microwave point sources at the 2.7 \sigma level.Comment: 35 pages (preprint format), 8 figures. In addition to minor revisions based on referee's comments, after correcting for a bug in the code, the SZ detection is consistent with the X-ray observations. Accepeted for publication in Physical Review