A new data assimilation procedure to develop a debris flow run-out model

Abstract Parameter calibration is one of the most problematic phases of numerical modeling since the choice of parameters affects the model\u2019s reliability as far as the physical problems being studied are concerned. In some cases, laboratory tests or physical models evaluating model parameters cannot be completed and other strategies must be adopted; numerical models reproducing debris flow propagation are one of these. Since scale problems affect the reproduction of real debris flows in the laboratory or specific tests used to determine rheological parameters, calibration is usually carried out by comparing in a subjective way only a few parameters, such as the heights of soil deposits calculated for some sections of the debris flows or the distance traveled by the debris flows using the values detected in situ after an event has occurred. Since no automatic or objective procedure has as yet been produced, this paper presents a numerical procedure based on the application of a statistical algorithm, which makes it possible to define, without ambiguities, the best parameter set. The procedure has been applied to a study case for which digital elevation models of both before and after an important event exist, implicating that a good database for applying the method was available. Its application has uncovered insights to better understand debris flows and related phenomena

Radiation to atom quantum mapping by collective recoil in Bose-Einstein condensate

We propose an experiment to realize radiation to atom continuous variable quantum mapping, i.e. to teleport the quantum state of a single mode radiation field onto the collective state of atoms with a given momentum out of a Bose-Einstein condensate. The atoms-radiation entanglement needed for the teleportation protocol is established through the interaction of a single mode with the condensate in presence of a strong far off-resonant pump laser, whereas the coherent atomic displacement is obtained by the same interaction with the radiation in a classical coherent field. In principle, verification of the protocol requires a joint measurement on the recoiling atoms and the condensate, however, a partial verification involving populations, i.e. diagonal matrix elements may be obtained through counting atoms experiments

How likely are oscillations in a genetic feedback loop with delay?

Some genetic control networks display temporal oscillations as a result of delays in their homeostatic control. A relevant question about these systems is whether the oscillating regime is a rare feature, or it corresponds to a sizeable volume of the space of parameters. The answer is not trivial mainly due to the large number of parameters controlling the rate equations which describe the network. We have developed an efficient sampling scheme of the parameter space, based on a Monte Carlo algorithm, and applied it to a two-node system with delay, characterised by a 8-dimension parameter space. The result is that the volume fraction of the parameter space associated with oscillations is small but not negligible, and it is weakly dependent on the duration of the delay. The most critical parameter to control oscillations is the coupling production rates, which must have opposite sign, giving rise to a negative feedback loop. The oscillating regions are connected except along the equilibrium constants between the two species, not allowing neutral evolution along this parameter

Robust generation of entanglement in Bose-Einstein condensates by collective atomic recoil

We address the dynamics induced by collective atomic recoil in a Bose-Einstein condensate in presence of radiation losses and atomic decoherence. In particular, we focus on the linear regime of the lasing mechanism, and analyze the effects of losses and decoherence on the generation of entanglement. The dynamics is that of three bosons, two atomic modes interacting with a single-mode radiation field, coupled with a bath of oscillators. The resulting three-mode dissipative Master equation is solved analytically in terms of the Wigner function. We examine in details the two complementary limits of {\em high-Q cavity} and {\em bad-cavity}, the latter corresponding to the so-called superradiant regime, both in the quasi-classical and quantum regimes. We found that three-mode entanglement as well as two-mode atom-atom and atom-radiation entanglement is generally robust against losses and decoherence,thus making the present system a good candidate for the experimental observation of entanglement in condensate systems. In particular, steady-state entanglement may be obtained both between atoms with opposite momenta and between atoms and photons

Analysis of agroclimatic resources for Georgian viticulture

One of the results of the \u201cResearch Project for the Study of Georgian Grapes and Wine Culture\u201d promoted by the National Wine Agency of the Republic of eorgia was the production of a bilingual handbook for modern viticulture. The first sections of the handbook were devoted to the agrometeorological analysis of environmental resources and limitations, comprising a general analysis of Georgian climate and agrometeorological features, followed by detailed regional cards. The agrometeorological analysis of Georgia was based on daily data collected by National and International networks for the period 1974-2013. Several agrometeorological indexes were calculated in order to define resources and limitations for viticulture for each viticultural region of Georgia, providing fundamental information for grape-growing and wine-making

A novel heteroditopic terpyridine-pincer ligand as building block for mono- and heterometallic Pd(II) and Ru(II) complexes

A palladium-catalyzed Stille coupling reaction was employed as a versatile method for the synthesis of a novel terpyridine-pincer (3, TPBr) bridging ligand, 4'-{4-BrC6H2(CH2NMe2)(2)-3,5}-2,2':6',2 ''-terpyridine. Mononuclear species [PdX(TP)] (X = Br, Cl), [Ru(TPBr)(tpy)](PF6)(2), and [Ru(TPBr)(2)](PF6)(2), synthesized by selective metalation of the NCNBr-pincer moiety or complexation of the terpyridine of the bifunctional ligand TPBr, were used as building blocks for the preparation of heterodi- and trimetallic complexes [Ru(TPPdCl)(tpy)](PF6)(2) (7) and [Ru(TPPdCl)(2)]-(PF6)(2) (8). The molecular structures in the solid state of [PdBr(TP)] (4a) and [Ru(TPBr)(2)](PF6)(2) (6) have been determined by single-crystal X-ray analysis. Electrochemical behavior and photophysical properties of the mono-and heterometallic complexes are described. All the above di- and trimetallic Ru complexes exhibit absorption bands attributable to (MLCT)-M-1 (Ru -> tpy) transitions. For the heteroleptic complexes, the transitions involving the unsubstituted tpy ligand are at a lower energy than the tpy moiety of the TPBr ligand. The absorption bands observed in the electronic spectra for TPBr and [PdCl(TP)] have been assigned with the aid of TD-DFT calculations. All complexes display weak emission both at room temperature and in a butyronitrile glass at 77 K. The considerable red shift of the emission maxima relative to the signal of the reference compound [Ru(tpy)(2)](2+) indicates stabilization of the luminescent (MLCT)-M-3 state. For the mono- and heterometallic complexes, electrochemical and spectroscopic studies (electronic absorption and emission spectra and luminescence lifetimes recorded at room temperature and 77 K in nitrile solvents), together with the information gained from IR spectroelectrochemical studies of the dimetallic complex [Ru(TPPdSCN)(tpy)](PF6)(2), are indicative of charge redistribution through the bridging ligand TPBr. The results are in line with a weak coupling between the {Ru(tpy)(2)} chromophoric unit and the (non)metalated NCN-pincer moiety