164 research outputs found
Ring-Pattern Dynamics in Smectic-C* and Smectic-C_A* Freely Suspended Liquid Crystal Films
Ring patterns of concentric 2pi-solitons in molecular orientation, form in
freely suspended chiral smectic-C films in response to an in-plane rotating
electric field. We present measurements of the zero-field relaxation of ring
patterns and of the driven dynamics of ring formation under conditions of
synchronous winding, and a simple model which enables their quantitative
description in low polarization DOBAMBC. In smectic C_A* TFMHPOBC we observe an
odd-even layer number effect, with odd number layer films exhibiting order of
magnitude slower relaxation rates than even layer films. We show that this rate
difference is due to much larger spontaneous polarization in odd number layer
films.Comment: 4 RevTeX pgs, 4 eps figures, submitted to Phys. Rev. Let
Ordered droplet structures at the liquid crystal surface and elastic-capillary colloidal interactions
We demonstrate a variety of ordered patterns, including hexagonal structures
and chains, formed by colloidal particles (droplets) at the free surface of a
nematic liquid crystal (LC). The surface placement introduces a new type of
particle interaction as compared to particles entirely in the LC bulk. Namely,
director deformations caused by the particle lead to distortions of the
interface and thus to capillary attraction. The elastic-capillary coupling is
strong enough to remain relevant even at the micron scale when its
buoyancy-capillary counterpart becomes irrelevant.Comment: 10 pages, 3 figures, to be published in Physical Review Letter
X-Ray Diffraction Intensities of a Smectic-A Liquid Crystal
Higher-order diffraction from the smectic-A liquid-crystalline phase of cyanooctylbiphenyl (COB) has been measured. The dominant short-range disorder, described by the relative intensities, is in agreement with our estimate of the smectic order parameter based on McMillan's mean-field theory
Defects in nematic membranes can buckle into pseudospheres
A nematic membrane is a sheet with embedded orientational order, which can
occur in biological cells, liquid crystal films, manufactured materials, and
other soft matter systems. By formulating the free energy of nematic films
using tensor contractions from differential geometry, we elucidate the elastic
terms allowed by symmetry, and indicate differences from hexatic membranes. We
find that topological defects in the orientation field can cause the membrane
to buckle over a size set by the competition between surface tension and
in-plane elasticity. In the absence of bending rigidity the resulting shape is
universal, known as a parabolic pseudosphere or a revolved tractrix. Bending
costs oppose such buckling and modify the shape in a predictable manner. In
particular, the anisotropic rigidities of nematic membranes lead to different
shapes for aster and vortex defects, in principle enabling measurement of
couplings specific to nematic membranes.Comment: 9 pages, 3 figure
Formation of disclination lines near a free nematic interface
We have studied the nucleation and the physical properties of a -1/2 wedge
disclination line near the free surface of a confined nematic liquid crystal.
The position of the disclination line has been related to the material
parameters (elastic constants, anchoring energy and favored anchoring angle of
the molecules at the free surface). The use of a planar model for the structure
of the director field (whose predictions have been contrasted to those of a
fully three-dimensional model) has allowed us to relate the experimentally
observed position of the disclination line to the relevant properties of the
liquid crystals. In particular, we have been able to observe the collapse of
the disclination line due to a temperature-induced anchoring angle transition,
which has allowed us to rule out the presence of a real disclination line near
the nematic/isotropic front in directional growth experiments.
61.30.Jf,61.30.G
Front propagation into unstable and metastable states in Smectic C* liquid crystals: linear and nonlinear marginal stability analysis
We discuss the front propagation in ferroelectric chiral smectics (SmC*)
subjected to electric and magnetic fields applied parallel to smectic layers.
The reversal of the electric field induces the motion of domain walls or fronts
that propagate into either an unstable or a metastable state. In both regimes,
the front velocity is calculated exactly. Depending on the field, the speed of
a front propagating into the unstable state is given either by the so-called
linear marginal stability velocity or by the nonlinear marginal stability
expression. The cross-over between these two regimes can be tuned by a magnetic
field. The influence of initial conditions on the velocity selection problem
can also be studied in such experiments. SmC therefore offers a unique
opportunity to study different aspects of front propagation in an experimental
system
'An Apotheosis of Well-Being': Durkheim on austerity and double-dip recessions
This article is an attempt to contribute a view on the economic crisis from classical sociology, a voice often missing from the sociological response to the crisis. The work of Émile Durkheim provides a unique perspective here centred on morality and inequality produced in a historical context akin to our neoliberal times. It is argued there are four key points to take from Durkheim’s work. Firstly, that the initial credit crunch can be more fully understood with reference to the economic anomie which Durkheim sees as ‘chronic’ in a time of marketization. Secondly, that this creates an antagonistic relationship between a supposedly self-dependent rich and lazy poor. Thirdly, this conception of self-dependency and individual initiative makes any attempt to regulate the economy akin to sacrilege. Finally, the state is unwilling to intervene due to the emergence of ‘pseudo-democracies’. Therefore, Durkheim’s theory accounts for the initial crisis, austerity and double-dip recessions in a sociological framework. The article concludes by returning to the centrality of morality to the crisis for Durkheim and highlighting the omission of this in contemporary debates
Tilt order parameters, polarity and inversion phenomena in smectic liquid crystals
The order parameters for the phenomenological description of the smectic-{\it
A} to smectic-{\it C} phase transition are formulated on the basis of molecular
symmetry and structure. It is shown that, unless the long molecular axis is an
axis of two-fold or higher rotational symmetry, the ordering of the molecules
in the smectic-{\it C} phase gives rise to more than one tilt order parameter
and to one or more polar order parameters. The latter describe the indigenous
polarity of the smectic-{\it C} phase, which is not related to molecular
chirality but underlies the appearance of spontaneous polarisation in chiral
smectics. A phenomenological theory of the phase transition is formulated by
means of a Landau expansion in two tilt order parameters (primary and
secondary) and an indigenous polarity order parameter. The coupling among these
order parameters determines the possibility of sign inversions in the
temperature dependence of the spontaneous polarisation and of the helical pitch
observed experimentally for some chiral smectic-{\it } materials. The
molecular interpretation of the inversion phenomena is examined in the light of
the new formulation.Comment: 12 pages, 5 figures, RevTe
Communitarian perspectives on social enterprise
Concepts of social enterprise have been debated repeatedly, and continue to cause confusion. In this paper, a meta-theoretical framework is developed through discussion of individualist and communitarian philosophy. Philosophers from both traditions build social theories that emphasise either consensus (a unitarist outlook) or diversity (a pluralist outlook). The various discourses in corporate governance reflect these assumptions and create four distinct approaches that impact on the relationship between capital and labour. In rejecting the traditional discourse of private enterprise, social enterprises have adopted other approaches to tackle social exclusion, each derived from different underlying beliefs about the purpose of enterprise and the nature of governance. The theoretical framework offers a way to understand the diversity found within the sector, including the newly constituted Community Interest Company (CIC).</p
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