A new perspective in bio-refining : Levoglucosenone and cleaner lignin from waste biorefinery hydrolysis lignin by selective conversion of residual saccharides

An unexpected opportunity is reported to improve the sustainability of biorefineries whereby 8 wt% levoglucosenone (LGE) can be derived from unconverted saccharides in a lignin-rich biorefinery waste stream in a highly selective fashion (>90%). Additionally, in the process a purer lignin is obtained which can be used for further processing or materials applications. LGE is a valuable and versatile product with a plethora of applications

The role of bioenergy in a climate-changing world

Bioenergy has been under intense scrutiny over the last ten years with significant research efforts in many countries taking place to define and measure sustainable practices. We describe here the main challenges and policy issues and provide policy recommendations for scaling up sustainable bioenergy approaches globally. The 2016 Intended Nationally Determined Contributions (INDCs defined under the UN Framework Convention on Climate Change) (UNFCCC) Conference of the Parties (COP21) will not reach global Greenhouse Gas (GHG) emission targets of 2°C. Sustainable biomass production can make a significant contribution. Substantive evidence exists that many bioenergy cropping systems can bring multiple benefits and off-set environmental problems associated with fossil fuels usage as well as intensive food production and urbanization. We provide evidence that there are many approaches to land use for bioenergy expansion that do not lead to competition for food or other needs. We should focus on how to manage these approaches on a synergistic basis and how to reduce tradeoffs at landscape scales. Priorities include successful synergies between bioenergy and food security (integrated resource management designed to improve both food security and access to bioenergy), investments in technology, rural extension, and innovations that build capacity and infrastructure, promotion of stable prices to incentivize local production and use of double cropping and flex crops (plants grown for both food and non-food markets) that provide food and energy as well as other services. The sustainable production of biomass requires appropriate policies to secure long-term support to improve crop productivity and also to ensure environmental as well as economic and social benefits of bioenergy cropping systems. Continuous support for cropping, infrastructure, agricultural management and related policies is needed to foster positive synergies between food crops and bioenergy production. In comparison to fossil fuels, biofuels have many positive environmental benefits. Potential negative effects caused by land-use change and agriculture intensification can be mitigated by agroecological zoning, best management practices, the use of eco-hydrology and biodiversity-friendly concepts at field, watershed and landscape scales. Global climate and environmental changes related to the use of fossil fuels and inequitable development make it unethical not to pursue more equitable energy development that includes bioenergy. To achieve sustainable development, competitiveness and costs of bioenergy production need to be addressed in a manner that considers not only economic gains but also development of local knowledge and social and environmental benefits

Status and prospects for renewable energy using wood pellets from the southeastern United States

The ongoing debate about costs and benefits of wood-pellet based bioenergy production in the southeastern United States (SE USA) requires an understanding of the science and context influencing market decisions associated with its sustainability. Production of pellets has garnered much attention as US exports have grown from negligible amounts in the early 2000s to 4.6 million metric tonnes in 2015. Currently, 98% of these pellet exports are shipped to Europe to displace coal in power plants. We ask, ‘How is the production of wood pellets in the SE USA affecting forest systems and the ecosystem services they provide?’ To address this question, we review current forest conditions and the status of the wood products industry, how pellet production affects ecosystem services and biodiversity, and what methods are in place to monitor changes and protect vulnerable systems. Scientific studies provide evidence that wood pellets in the SE USA are a fraction of total forestry operations and can be produced while maintaining or improving forest ecosystem services. Ecosystem services are protected by the requirement to utilize loggers trained to apply scientifically based best management practices in planning and implementing harvest for the export market. Bioenergy markets supplement incomes to private rural landholders and provide an incentive for forest management practices that simultaneously benefit water quality and wildlife and reduce risk of fire and insect outbreaks. Bioenergy also increases the value of forest land to landowners, thereby decreasing likelihood of conversion to nonforest uses. Monitoring and evaluation are essential to verify that regulations and good practices are achieving goals and to enable timely responses if problems arise. Conducting rigorous research to understand how conditions change in response to management choices requires baseline data, monitoring, and appropriate reference scenarios. Long-term monitoring data on forest conditions should be publicly accessible and utilized to inform adaptive management

The photochemistry of N-p-toluenesulfonyl peptides: the peptide bond as an electron donor

The scope of photobiological processes that involve absorbers within a protein matrix may be limited by the vulnerability of the peptide group to attack by highly reactive redox centers consequent upon electronic excitation. We have explored the nature of this vulnerability by undertaking comprehensive product analyses of aqueous photolysates of 12 N-p-toluene-sulfonyl peptides with systematically selected structures. The results indicate that degradation includes a major pathway that is initiated by intramolecular electron transfer in which the peptide bond serves as electron donor, and the data support the likelihood of a relay process in dipeptide derivatives

Ionic liquids at electrified interfaces

Until recently, “room-temperature” (<100–150 °C) liquid-state electrochemistry was mostly electrochemistry of diluted electrolytes(1)–(4) where dissolved salt ions were surrounded by a considerable amount of solvent molecules. Highly concentrated liquid electrolytes were mostly considered in the narrow (albeit important) niche of high-temperature electrochemistry of molten inorganic salts(5-9) and in the even narrower niche of “first-generation” room temperature ionic liquids, RTILs (such as chloro-aluminates and alkylammonium nitrates).(10-14) The situation has changed dramatically in the 2000s after the discovery of new moisture- and temperature-stable RTILs.(15, 16) These days, the “later generation” RTILs attracted wide attention within the electrochemical community.(17-31) Indeed, RTILs, as a class of compounds, possess a unique combination of properties (high charge density, electrochemical stability, low/negligible volatility, tunable polarity, etc.) that make them very attractive substances from fundamental and application points of view.(32-38) Most importantly, they can mix with each other in “cocktails” of one’s choice to acquire the desired properties (e.g., wider temperature range of the liquid phase(39, 40)) and can serve as almost “universal” solvents.(37, 41, 42) It is worth noting here one of the advantages of RTILs as compared to their high-temperature molten salt (HTMS)(43) “sister-systems”.(44) In RTILs the dissolved molecules are not imbedded in a harsh high temperature environment which could be destructive for many classes of fragile (organic) molecules

Behavior Discovery and Alignment of Articulated Object Classes from Unstructured Video

We propose an automatic system for organizing the content of a collection of unstructured videos of an articulated object class (e.g. tiger, horse). By exploiting the recurring motion patterns of the class across videos, our system: 1) identifies its characteristic behaviors; and 2) recovers pixel-to-pixel alignments across different instances. Our system can be useful for organizing video collections for indexing and retrieval. Moreover, it can be a platform for learning the appearance or behaviors of object classes from Internet video. Traditional supervised techniques cannot exploit this wealth of data directly, as they require a large amount of time-consuming manual annotations. The behavior discovery stage generates temporal video intervals, each automatically trimmed to one instance of the discovered behavior, clustered by type. It relies on our novel motion representation for articulated motion based on the displacement of ordered pairs of trajectories (PoTs). The alignment stage aligns hundreds of instances of the class to a great accuracy despite considerable appearance variations (e.g. an adult tiger and a cub). It uses a flexible Thin Plate Spline deformation model that can vary through time. We carefully evaluate each step of our system on a new, fully annotated dataset. On behavior discovery, we outperform the state-of-the-art Improved DTF descriptor. On spatial alignment, we outperform the popular SIFT Flow algorithm.Comment: 19 pages, 19 figure, 3 tables. arXiv admin note: substantial text overlap with arXiv:1411.788

Антикризисное управление

Учебно-методический комплекс (УМК) по учебной дисциплине «Ан-тикризисное управление» создан в соответствии с требованиями Положения об учебно-методическом комплексе на уровне высшего образования, утвер-жденного постановлением Министерства образования Республики Беларусь от 26.07.2011 № 167, предназначен для реализации содержания образова-тельной программы для обучающихся первой ступени высшего образования для студентов специальности 1-26 02-02 «Менеджмент». Содержание разделов УМК соответствует образовательному стандарту высшего образования данной специальности. Главная цель УМК – оказание методической помощи магистрантам в освоении и систематизации учебного материала в процессе обучения и под-готовки к аттестации по дисциплине «Антикризисное управление». УМК включает: 1. Теоретический раздел (конспект лекций, аннотированный перечень основных учебных и научно-практических изданий). 2. Практический раздел (тематика практических занятий по дисци-плине в соответствии с учебным планом и учебной программой). 3. Контроль работы обучающихся (материалы для текущей аттестации, позволяющие определить соответствие учебной деятельности обучающихся требованиям образовательного стандарта высшего образования и учебно-программной документации, в т.ч. вопросы для подготовки к зачету). 4. Вспомогательный раздел (содержание учебного материала учебной дисциплины; методические рекомендации по организации самостоятельной работы магистрантов; информационно-аналитические материалы: список ре-комендуемой литературы, перечень электронных ресурсов и их адреса; при-мерный перечень тем для написания рефератов). Работа с УМК должна включать на первом этапе ознакомление с со-держанием учебного материала учебной дисциплины, посредством которого можно получить информацию о тематике лекций и практических занятий, перечнях рассматриваемых вопросов и рекомендуемой для их изучения ли-тературы. Для подготовки к практическим занятиям необходимо использо-вать материалы, представленные в Теоретическом и Практическом разделах. В основу структуры программы легла учебная программа «Антикри-зисное управление» Белорусского государственного университета для выс-ших учебных заведений по специальности Э.01.03.00 «Экономика и управле-ния на предприятии» (регистрационный № ТД-182/баз.)

Inhibition of Orobanche crenata Seed Germination and Radicle Growth by Allelochemicals Identified in Cereals

Orobanche crenata is a parasitic weed that causes severe yield losses in important grain and forage legume crops. Cereals have been reported to inhibit O. crenata parasitism when grown intercropped with susceptible legumes, but the responsible metabolites have not been identified. A number of metabolites have been reported in cereals that have allelopathic properties against weeds, pests, and pathogens. We tested the effect of several allelochemicals identified in cereals on O. crenata seed germination and radicle development. We found that 2-benzoxazolinone, its derivative 6-chloroacetyl-2-benzoxazolinone, and scopoletin significantly inhibited O. crenata seed germination. Benzoxazolinones, l-tryptophan, and coumalic acid caused the stronger inhibition of radicle growth. Also, other metabolites reduced radicle length, this inhibition being dose-dependent. Only scopoletin caused cell necrotic-like darkening in the young radicles. Prospects for their application to parasitic weed management are discussed. © 2013 American Chemical Society.This research is supported by projects FP7-ARIMNet-MEDILEG and AGL2011-22524 (cofinanced by FEDER funds).Peer Reviewe

Weakly Supervised Localization and Learning with Generic Knowledge

ISSN:0920-5691ISSN:1573-140