Plasmon resonances of highly doped two-dimensional MoS2

The exhibition of plasmon resonances in two-dimensional (2D) semiconductor compounds is desirable for many applications. Here, by electrochemically intercalating lithium into 2D molybdenum disulfide (MoS2) nanoflakes, plasmon resonances in the visible and near UV wavelength ranges are achieved. These plasmon resonances are controlled by the high doping level of the nanoflakes after the intercalation, producing two distinct resonance peak areas based on the crystal arrangements. The system is also benchmarked for biosensing using bovine serum albumin. This work provides a foundation for developing future 2D MoS2 based biological and optical units

Exfoliation solvent dependent plasmon resonances in two-dimensional sub-stoichiometric molybdenum oxide nanoflakes

Few-layer two-dimensional (2D) molybdenum oxide nanoflakes are exfoliated using a grinding assisted liquid phase sonication exfoliation method. The sonication process is carried out in five different mixtures of water with both aprotic and protic solvents. We found that surface energy and solubility of mixtures play important roles in changing the thickness, lateral dimension, and synthetic yield of the nanoflakes. We demonstrate an increase in proton intercalation in 2D nanoflakes upon simulated solar light exposure. This results in substoichiometric flakes and a subsequent enhancement in free electron concentrations, producing plasmon resonances. Two plasmon resonance peaks associated with the thickness and the lateral dimension axes are observable in the samples, in which the plasmonic peak positions could be tuned by the choice of the solvent in exfoliating 2D molybdenum oxide. The extinction coefficients of the plasmonic absorption bands of 2D molybdenum oxide nanoflakes in all samples are found to be high (Îμ > 109 L mol-1 cm-1). It is expected that the tunable plasmon resonances of 2D molybdenum oxide nanoflakes presented in this work can be used in future electronic, optical, and sensing devices

Census politics in deeply divided societies

Population censuses in societies that are deeply divided along ethnic, religious or linguistic lines can be sensitive affairs – particularly where political settlements seek to maintain peace through the proportional sharing of power between groups. This brief sets out some key findings from a research project investigating the relationship between census politics and the design of political institutions in Bosnia and Herzegovina, Kenya, Lebanon and Northern Ireland

Searching for ejected supernova companions in the era of precise proper motion and radial velocity measurements

The majority of massive stars are born in binaries, and most unbind upon the first supernova. With precise proper motion surveys such as Gaia, it is possible to trace back the motion of stars in the vicinity of young remnants to search for ejected companions. Establishing the fraction of remnants with an ejected companion, and the photometric and kinematic properties of these stars, offers unique insight into supernova progenitor systems. In this paper, we employ binary population synthesis to produce kinematic and photometric predictions for ejected secondary stars. We demonstrate that the unbound neutron star velocity distribution from supernovae in binaries closely traces the input kicks. Therefore, the observed distribution of neutron star velocities should be representative of their natal kicks. We evaluate the probability for any given filter, magnitude limit, minimum measurable proper motion (as a function of magnitude), temporal baseline, distance and extinction that an unbound companion can be associated with a remnant. We compare our predictions with results from previous companion searches, and demonstrate that the current sample of stars ejected by the supernova of their companion can be increased by a factor of 5-10 with Gaia data release 3. Further progress in this area is achievable by leveraging the absolute astrometric precision of Gaia, and by obtaining multiple epochs of deep, high resolution near-infrared imaging with the Hubble Space Telescope, JWST and next-generation wide-field near-infrared observatories such as Euclid or the Nancy Grace Roman Space Telescope.Comment: Accepted for publication in MNRAS. 19 pages, 17 figure

Estimating transient rates from cosmological simulations and BPASS

The detection rate of electromagnetic (EM) and gravitational wave (GW) transients is growing exponentially. As the accuracy of the transient rates will significantly improve over the coming decades, so will our understanding of their evolution through cosmic history. To this end, we present predicted rates for EM and GW transients over the age of the Universe using Binary Population and Spectral Synthesis (BPASS) results combined with four cosmic star formation histories (SFH). These include a widely used empirical SFH of Madau & Dickinson and those from three cosmological simulations: MilliMillennium, EAGLE and IllustrisTNG. We find that the choice of SFH changes our predictions: transients with short delay times are most affected by the star formation rate and change up to a factor 2, while long-delay time events tend to depend on the metallicity evolution of star formation and can change the predicted rate up to an order of magnitude. Importantly, we find that the cosmological simulations have very different metallicity evolution that cannot be reproduced by the widely used metallicity model of Langer & Norman, which impacts the binary black hole merger, stripped-envelope supernovae, and LGRBs in the local Universe most acutely. We recommend against using simple prescriptions for the metallicity evolution of the Universe when predicting the rates of events that can have long delay times and that are sensitive to metallicity evolution

High-performance field effect transistors using electronic inks of 2D molybdenum oxide nanoflakes

Planar 2D materials are possibly the ideal channel candidates for future field effect transistors (FETs), due to their unique electronic properties. However, the performance of FETs based on 2D materials is yet to exceed those of conventional silicon based devices. Here, a 2D channel thin film made from liquid phase exfoliated molybdenum oxide nanoflake inks with highly controllable substoichiometric levels is presented. The ability to induce oxygen vacancies by solar light irradiation in an aqueous environment allows the tuning of electronic properties in 2D substoichiometric molybdenum oxides (MoO3-x). The highest mobility is found to be approximate to 600 cm(2) V-1 s(-1) with an estimated free electron concentration of approximate to 1.6 x 10(21) cm(-3) and an optimal I-On/I-Off ratio of >10(5) for the FETs made of 2D flakes irradiated for 30 min (x = 0.042). These values are significant and represent a real opportunity to realize the next generation of tunable electronic devices using electronic inks

PRESA DE LOS MOLINOS [Material gráfico]

Copia digital. Madrid : Ministerio de Educación, Cultura y Deporte. Subdirección General de Coordinación Bibliotecaria, 201

Preventing unrecognised oesophageal intubation: a consensus guideline from the Project for Universal Management of Airways and international airway societies.

Across multiple disciplines undertaking airway management globally, preventable episodes of unrecognised oesophageal intubation result in profound hypoxaemia, brain injury and death. These events occur in the hands of both inexperienced and experienced practitioners. Current evidence shows that unrecognised oesophageal intubation occurs sufficiently frequently to be a major concern and to merit a co-ordinated approach to address it. Harm from unrecognised oesophageal intubation is avoidable through reducing the rate of oesophageal intubation, combined with prompt detection and immediate action when it occurs. The detection of 'sustained exhaled carbon dioxide' using waveform capnography is the mainstay for excluding oesophageal placement of an intended tracheal tube. Tube removal should be the default response when sustained exhaled carbon dioxide cannot be detected. If default tube removal is considered dangerous, urgent exclusion of oesophageal intubation using valid alternative techniques is indicated, in parallel with evaluation of other causes of inability to detect carbon dioxide. The tube should be removed if timely restoration of sustained exhaled carbon dioxide cannot be achieved. In addition to technical interventions, strategies are required to address cognitive biases and the deterioration of individual and team performance in stressful situations, to which all practitioners are vulnerable. These guidelines provide recommendations for preventing unrecognised oesophageal intubation that are relevant to all airway practitioners independent of geography, clinical location, discipline or patient type

Physisorption-based charge transfer in two-dimensional SnS2 for selective and reversible NO2 gas sensing

Nitrogen dioxide (NO2) is a gas species that plays an important role in certain industrial, farming, and healthcare sectors. However, there are still significant challenges for NO2 sensing at low detection limits, especially in the presence of other interfering gases. The NO2 selectivity of current gas-sensing technologies is significantly traded-off with their sensitivity and reversibility as well as fabrication and operating costs. In this work, we present an important progress for selective and reversible NO2 sensing by demonstrating an economical sensing platform based on the charge transfer between physisorbed NO2 gas molecules and two-dimensional (2D) tin disulfide (SnS2) flakes at low operating temperatures. The device shows high sensitivity and superior selectivity to NO2 at operating temperatures of less than 160 °C, which are well below those of chemisorptive and ion conductive NO2 sensors with much poorer selectivity. At the same time, excellent reversibility of the sensor is demonstrated, which has rarely been observed in other 2D material counterparts. Such impressive features originate from the planar morphology of 2D SnS2 as well as unique physical affinity and favorable electronic band positions of this material that facilitate the NO2 physisorption and charge transfer at parts per billion levels. The 2D SnS2-based sensor provides a real solution for low-cost and selective NO2 gas sensing