302 research outputs found
Synthesis of Bifunctional Poly(Vinyl Phosphonic Acid-co-glycidyl Metacrylate-co-divinyl Benzene) Cation-Exchange Resin and Its Indium Adsorption Properties from Indium Tin Oxide Solution
ABSTRACT Poly(vinyl phosphonic acid-co-glycidyl methacrylate-co-divinyl benzene) (PVGD) and PVGD containing an iminodiacetic acid group (IPVGD), which has indium ion selectivity, were synthesized by suspension polymerization, and their indium adsorption properties were investigated. The synthesized PVGD and IPVGD resins were characterized using Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and mercury porosimetry. The cation-exchange capacity, the water uptake and the indium adsorption properties were investigated. The cation-exchange capacities of PVGD and IPVGD were 1.2 -4.5 meq/g and 2.5 -6.4 meq/g, respectively. The water uptakes were decreased with increasing contents of divinyl benzene (DVB). The water uptake values were 25% -40% and 20% -35%, respectively. The optimum adsorption of indium from a pure indium solution and an artificial indium tin oxide (ITO) solution by the PVGD and IPVGD ion-exchange resins were 2.3 and 3.5 meq/g, respectively. The indium adsorption capacities of IPVGD were higher than those of PVGD. The indium ion adsorption selectivity in the artificial ITO solution by PVGD and IPVGD was excellent, and other ions were adsorbed only slightly
Age and Retinal Nerve Fiber Layer Thickness Measured by Spectral Domain Optical Coherence Tomography
Crossover from 2D ferromagnetic insulator to wide bandgap quantum anomalous Hall insulator in ultra-thin MnBi2Te4
Intrinsic magnetic topological insulators offer low disorder and large
magnetic bandgaps for robust magnetic topological phases operating at higher
temperatures. By controlling the layer thickness, emergent phenomena such as
the Quantum Anomalous Hall (QAH) effect and axion insulator phases have been
realised. These observations occur at temperatures significantly lower than the
Neel temperature of bulk MnBi2Te4, and measurement of the magnetic energy gap
at the Dirac point in ultra-thin MnBi2Te4 has yet to be achieved. Critical to
achieving the promise of this system is a direct measurement of the
layer-dependent energy gap and verifying whether the gap is magnetic in the QAH
phase. Here we utilise temperature dependent angle-resolved photoemission
spectroscopy to study epitaxial ultra-thin MnBi2Te4. We directly observe a
layer dependent crossover from a 2D ferromagnetic insulator with a bandgap
greater than 780 meV in one septuple layer (1 SL) to a QAH insulator with a
large energy gap (>100 meV) at 8 K in 3 and 5 SL MnBi2Te4. The QAH gap is
confirmed to be magnetic in origin, as it abruptly diminishes with increasing
temperature above 8 K. The direct observation of a large magnetic energy gap in
the QAH phase of few-SL MnBi2Te4 is promising for further increasing the
operating temperature of QAH materials
Dual Fistulas of Ascending Aorta and Coronary Artery to Pulmonary Artery
Coronary artery fistula to pulmonary artery is common. However, to the best of our knowledge, a case of coronary artery fistula to pulmonary artery associated with aortopulmonary fistula remains unreported. We herein report a 64-year-old female with a left anterior descending coronary artery and ascending aorta to pulmonary artery fistulas, and conduct a brief review of the literature
Effect Of Sediment Releasing Operation From Reservoir Outlets On The Water Treatment Plant Downstream
With steep slope and strong rainfall intensity, landslide and debris flow could generate huge amount of sediment yield from the watershed, typically during typhoon floods in Taiwan. As such huge amount of sediment moved into a reservoir, serious sedimentation problem reduced storage of reservoir due to decrease of flow velocity and without sufficient sediment releasing bottom outlet. As a result, using flood discharge to release sediment during Typhoon or rain fall duration is very important. This study adopts the data of field observation from outlet structures of the Shihmen reservoir to establish the operational strategies of sediment releasing rule and keep water sustained supply at downstream river intake. Based on the numerical simulation by using 1-D and 2-D models, the relationship of sediment concentration between the Shihmen reservoir and downstream withdraw intake at the YuanShan weir can be established. The sediment concentration reduction ratio is calculated to be 89% from the Shihmen reservoir to the YuanShan weir. This study also focuses on the sediment concentration mitigation influence of tunnel spillway due to the high sediment concentration releasing from bottom outlet. From simulated results, when the extra discharge of tunnel spillway reaches 830m3/s for specific event, the influence of reducing sediment concentration to downstream river by tunnel spillway can maintain water supply of downstream withdraw intake at YuanShan weir. In practice, when using the extra discharge of tunnel spillway to reduce sediment concentration during Typhoon Haitang and Typhoon Wipha, the sediment concentration at YuanShan weir can reduce water turbidity lower than 6000NTU that water treatment plant can deal with
Transparent Fingerprint Sensor System for Large Flat Panel Display
In this paper, we introduce a transparent fingerprint sensing system using a thin film transistor (TFT) sensor panel, based on a self-capacitive sensing scheme. An armorphousindium gallium zinc oxide (a-IGZO) TFT sensor array and associated custom Read-Out IC (ROIC) are implemented for the system. The sensor panel has a 200 ?? 200 pixel array and each pixel size is as small as 50 ??m ?? 50 ??m. The ROIC uses only eight analog front-end (AFE) amplifier stages along with a successive approximation analog-to-digital converter (SAR ADC). To get the fingerprint image data from the sensor array, the ROIC senses a capacitance, which is formed by a cover glass material between a human finger and an electrode of each pixel of the sensor array. Three methods are reviewed for estimating the self-capacitance. The measurement result demonstrates that the transparent fingerprint sensor system has an ability to differentiate a human finger???s ridges and valleys through the fingerprint sensor array
Identification of a novel antiapoptotic protein that antagonizes ASK1 and CAD activities
Diverse stimuli initiate the activation of apoptotic signaling pathways that often causes nuclear DNA fragmentation. Here, we report a new antiapoptotic protein, a caspase-activated DNase (CAD) inhibitor that interacts with ASK1 (CIIA). CIIA, by binding to apoptosis signal-regulating kinase 1 (ASK1), inhibits oligomerization-induced ASK1 activation. CIIA also associates with CAD and inhibits the nuclease activity of CAD without affecting caspase-3–mediated ICAD cleavage. Overexpressed CIIA reduces H2O2- and tumor necrosis factor-α–induced apoptosis. CIIA antisense oligonucleotides, which abolish expression of endogenous CIIA in murine L929 cells, block the inhibitory effect of CIIA on ASK1 activation, deoxyribonucleic acid fragmentation, and apoptosis. These findings suggest that CIIA is an endogenous antagonist of both ASK1- and CAD-mediated signaling
Disruption of nucleocytoplasmic trafficking as a cellular senescence driver
Senescent cells exhibit a reduced response to intrinsic and extrinsic stimuli. This diminished reaction may be explained by the disrupted transmission of nuclear signals. However, this hypothesis requires more evidence before it can be accepted as a mechanism of cellular senescence. A proteomic analysis of the cytoplasmic and nuclear fractions obtained from young and senescent cells revealed disruption of nucleocytoplasmic trafficking (NCT) as an essential feature of replicative senescence (RS) at the global level. Blocking NCT either chemically or genetically induced the acquisition of an RS-like senescence phenotype, named nuclear barrier-induced senescence (NBIS). A transcriptome analysis revealed that, among various types of cellular senescence, NBIS exhibited a gene expression pattern most similar to that of RS. Core proteomic and transcriptomic patterns common to both RS and NBIS included upregulation of the endocytosis-lysosome network and downregulation of NCT in senescent cells, patterns also observed in an aging yeast model. These results imply coordinated aging-dependent reduction in the transmission of extrinsic signals to the nucleus and in the nucleus-to-cytoplasm supply of proteins/RNAs. We further showed that the aging-associated decrease in Sp1 transcription factor expression was critical for the downregulation of NCT. Our results suggest that NBIS is a modality of cellular senescence that may represent the nature of physiological aging in eukaryotes. © 2021, The Author(s).1
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