325 research outputs found
Threshold photoelectron photoion coincidence spectroscopy of trichloroethene and tetrachloroethene
The threshold photoelectron, the threshold photoelectron photoion coincidence and ion breakdown spectra of trichloroethene and tetrachloroethene have been recorded from 9 – 22 eV. Comparisons with the equivalent data for the three dichloroethene molecules and theoretical calculations highlight the nature of the orbitals involved during photoionisation in this energy range. The ground electronic state of CHCl (CCl) is bound, with excited valence states dissociating to CHCl (CCl) and CHCl (CCl). Appearance energies suggest that CHCl forms from CHCl by loss of two chlorine atoms, whereas CCl forms from CCl by loss of a Cl molecule. The translational kinetic energy release into CHCl (CCl) + Cl is determined as a function of energy. In both cases, the fraction of the available energy released into translational energy of the two products decreases as the photon energy increases
The Quark-Gluon Plasma in a Finite Volume
The statistical mechanics of quarks and gluons are investigated within the
context of the canonical ensemble. Recursive techniques are developed which
enforce the exact conservation of baryon number, total isospin, electric
charge, strangeness, and color. Bose and Fermi-Dirac statistics are also
accounted for to all orders. The energy, entropy and particle number densities
are shown to be significantly reduced for volumes less than 5 cubic fm.Comment: 8 pages, 3 figure
First principles electronic structure of spinel LiCr2O4: A possible half-metal?
We have employed first-principles electronic structure calculations to
examine the hypothetical (but plausible) oxide spinel, LiCr2O4 with the d^{2.5}
electronic configuration. The cell (cubic) and internal (oxygen position)
structural parameters have been obtained for this compound through structural
relaxation in the first-principles framework. Within the one-electron band
picture, we find that LiCr2O4 is magnetic, and a candidate half-metal. The
electronic structure is substantially different from the closely related and
well known rutile half-metal CrO2. In particular, we find a smaller conduction
band width in the spinel compound, perhaps as a result of the distinct topology
of the spinel crystal structure, and the reduced oxidation state. The magnetism
and half-metallicity of LiCr2O4 has been mapped in the parameter space of its
cubic crystal structure. Comparisons with superconducting LiTi2O4 (d^{0.5}),
heavy-fermion LiV2O4 (d^{1.5}) and charge-ordering LiMn2O4 (d^{3.5}) suggest
the effectiveness of a nearly-rigid band picture involving simple shifts of the
position of E_F in these very different materials. Comparisons are also made
with the electronic structure of ZnV2O4 (d^{2}), a correlated insulator that
undergoes a structural and antiferromagnetic phase transition.Comment: 9 pages, 7 Figures, version as published in PR
Double distributions and evolution equations
Applications of perturbative QCD to deeply virtual Compton scattering and
hard exclusive meson electroproduction processes require a generalization of
usual parton distributions for the case when long-distance information is
accumulated in nonforward matrix elements of quark and gluon
light-cone operators. In our previous papers we used two types of
nonperturbative functions parametrizing such matrix elements: double
distributions F(x,y;t) and nonforward distribution functions F_\zeta(X;t). Here
we discuss in more detail the double distributions (DD's) and evolution
equations which they satisfy. We propose simple models for F(x,y;t=0) DD's with
correct spectral and symmetry properties which also satisfy the reduction
relations connecting them to the usual parton densities f(x). In this way, we
obtain self-consistent models for the \zeta-dependence of nonforward
distributions. We show that, for small \zeta, one can easily obtain nonforward
distributions (in the X > \zeta region) from the parton densities: F_\zeta
(X;t=0) \approx f(X-\zeta/2).Comment: 21 pages, Latex, 8 figures. To appear in Phys. Rev.
Novel community data in ecology-properties and prospects
New technologies for monitoring biodiversity such as environmental (e)DNA, passive acoustic monitoring, and optical sensors promise to generate automated spatiotemporal community observations at unprecedented scales and resolutions. Here, we introduce ‘novel community data’ as an umbrella term for these data. We review the emerging field around novel community data, focusing on new ecological questions that could be addressed; the analytical tools available or needed to make best use of these data; and the potential implications of these developments for policy and conservation. We conclude that novel community data offer many opportunities to advance our understanding of fundamental ecological processes, including community assembly, biotic interactions, micro- and macroevolution, and overall ecosystem functioning
Promised Land? Immigration, Religiosity, and Space in Southern California
This article looks at how immigrants and their supporters appropriate and use religious space and other public spaces for religious and socio-political purposes in Southern California. While the everyday living conditions of many immigrants, particularly the unauthorized Latino immigrants, force unto them an embodied disciplinarity that maintains spatialities of restricted citizenship, the public appropriations of space for and through religious practices allow for them -even if only momentarily -to express an embodied transgression. This practice in public space helps realize spaces of freedom and hope, however ephemerally. Potentially, these rehearsing exercises can help revert internalized disempowering subjectivities and create social empowerment. Negative stereotypes about immigrants held by the larger public can also be challenged through these spatial practices, as the public demonstrations make visible the invisible. We focus on “Posadas Without Borders” and “the New Sanctuary Movement,” considering both the role of progressive civic and religious institutions in supporting immigrants and the agency of the immigrants themselves. The theoretical analysis builds on concepts drawn from a conversation between geography and religious and theological studies. We use a triangulated methodological approach that includes observation and participant observation, content-analysis of multimedia, interviews, and intellectual advocacy for the immigrant movement. The cases discussed here show that progressive religious groups and coalitions can be important allies to progressive planners, geographers, and policy makers in advancing social and environmental justice for the disenfranchised. They also show that the theological underpinnings of such groups share a lot in common with planning epistemologies for the just city
Temporal dynamics of the shrub and herbaceous layer of an area of moist grassland in Alto Paraíso de Goiás, Brazil
Este trabalho avaliou a dinâmica estrutural e fl orística de uma comunidade de espécies herbáceo-arbustivas
de uma área de campo limpo úmido em Alto Paraíso de Goiás, o primeiro inventário realizado em 2000 (T0) e o
segundo em 2007 (T1). A diversidade de Shannon entre os períodos foi comparada pelo teste-t de Hutcheson e a
similaridade fl orística, pelo índice de similaridade de Chao-Sørensen. As relações fl orísticas e a cobertura, entre os
períodos e as linhas, foram avaliadas por meio de análises de correspondência retifi cada (DCA). Foram amostradas
98 espécies, 88 no T0 e 67 no T1, sendo 31 exclusivas do T0 e 10 do T1. A diversidade fl orística na comunidade
foi elevada nos dois períodos, porém diferente entre esses (t = 7,12; p < 0,001), devido a variação no número e
cobertura das espécies. A similaridade entre os dois inventários foi alta (Chao-Sørensen ± IC = 0,841 ± 0,074). A
ordenação por DCA indicou relações entre a composição fl orística e a cobertura com o gradiente de umidade e
de matéria orgânica no solo identifi cados em T0. Houve modifi cações nas linhas em zonas sazonais, as quais se
tornaram mais semelhantes às linhas constantemente saturadas por água. Em um intervalo de sete anos o campo
limpo úmido apresentou mudanças na composição fl orística e, principalmente na estrutura devido o aumento da
cobertura de espécies perenes, cespitosas e entouceiradas, que foram favorecidas pela maior umidade no solo em
resposta à elevação da pluviosidade da região. __________________________________________________________________________________________ ABSTRACTTh is study evaluated the fl oristic and structural dynamics of a community of herbaceous-shrub species
in an area of moist grassland in Alto Paraíso de Goiás. Th e fi rst inventory was undertaken in 2000 (T0) and the
second in 2007 (T1). Shannon’s diversity between the periods was compared by Hutchesons´s t-test, and the
fl oristic similarity by the Chao-Sørensen similarity index. Floristic composition and cover, between periods and
lines, were evaluated by detrended correspondence analysis (DCA). We sampled 98 species, 88 at T0 and 67 at T1;
31 were unique to T0 and 10 to T1. Floristic diversity in the community was high in both periods, but diff erent
between them (t = 7.12, p <0.001), due to variation in species number and coverage. Similarity between the two
surveys was high (Chao-Sørensen CI = ± 0.841 ± 0.074). Th e DCA ordination indicated relationships between the
fl oristic composition and cover with a gradient of moisture and organic matter in the soil identifi ed in T0. Th ere
were changes in the lines in the seasonal zones, which became more similar in those constantly saturated with
water. During an interval of seven years the moist grassland showed changes in fl oristic composition and mainly
in structure due to increased cover of the clumped tussock perennial species, which were favored by higher soil
moisture due to high rainfall in the region
The current status of species recognition and identification in Aspergillus
The species recognition and identification of aspergilli and their
teleomorphs is discussed. A historical overview of the taxonomic concepts
starting with the monograph of Raper & Fennell
(1965) is given. A list of
taxa described since 2000 is provided. Physiological characters, particularly
growth rates and the production of extrolites, often show differences that
reflect phylogenetic species boundaries and greater emphasis should be placed
on extrolite profiles and growth characteristics in species descriptions.
Multilocus sequence-based phylogenetic analyses have emerged as the primary
tool for inferring phylogenetic species boundaries and relationships within
subgenera and sections. A four locus DNA sequence study covering all major
lineages in Aspergillus using genealogical concordance theory
resulted in a species recognition system that agrees in part with phenotypic
studies and reveals the presence of many undescribed species not resolved by
phenotype. The use of as much data from as many sources as possible in making
taxonomic decisions is advocated. For species identification, DNA barcoding
uses a short genetic marker in an organism”s DNA to quickly and easily
identify it to a particular species. Partial cytochrome oxidase subunit 1
sequences, which are used for barcoding animal species, were found to have
limited value for species identification among black aspergilli. The various
possibilities are discussed and at present partial β-tubulin or
calmodulin are the most promising loci for Aspergillus
identification. For characterising Aspergillus species one
application would be to produce a multilocus phylogeny, with the goal of
having a firm understanding of the evolutionary relationships among species
across the entire genus. DNA chip technologies are discussed as possibilities
for an accurate multilocus barcoding tool for the genus
Aspergillus
- …