State and unknown input observer design for a class of non-linear systems: application to a fermentation process

International audienceThis paper deals with the simultaneous estimation of states and unknown inputs for a class of non-linear systems using only the measured outputs. A high gain non-linear observer is proposed. Besides the usual rank assumptions on the unknown input observers, the unknown inputs and their derivatives are assumed to be uniformly bounded. An application to an alcoholic fermentation process in chemical reactor semi-continuous, Fed-batch, is presented. Observer's performances are illustrated through the simulation results of the Fed-batch system

Elaboration of alumina-based materials by solution combustion synthesis: A review

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Effects of Olive Mill Wastewater on Soil Nutrients Availability

Abstract Olive mill wastewater (OMW) is one of complex wastewater generated by the olive oil extraction process. It is characterized by high values of COD, BOD and phytotoxic levels of polyphenols, but also by a high amount of organic compounds and plant mineral nutrients. Therefore, OMW field spreading may represent a low cost contribution to soil amendment. Olive mill wastewater (OMW) spraying effects onto soil physico-chemicals characteristics were investigated. Three OMW doses 50, 100 and 200 m 3 ha -1 year -1 were applied for ten successive years on sandy soil. The findings showed that the pH of the soil, electrical conductivity and organic matter, total nitrogen, phosphorus, sodium, and potassium soil contents increased with increased OMW supply. While, no variations were recorded in calcium and magnesium on soil contents

NO reduction with NH3 under oxidizing atmosphere on copper loaded hydroxyapatite

International audienceCopper loaded hydroxyapatite catalysts were prepared by ion exchange in aqueous phase. The copper ion exchange capacity of hydroxyapatite host structure is highly dependent on the initial copper concentration of the solution. For the lowest concentration, a pH variation of the exchange solution is observed. This change in pH may allow the deposition of a small amount of copper hydroxide at the expense of cationic substitution of copper. The increase in copper content exchanged has no effect on the profile of conversion of NO by NH3. From this, it is assumed that the copper cations substituted for calcium are not active in the reaction. The profiles of NO conversion obtained, are in agreement with the presence of a small amount of copper oxide clusters deposited on the surfaces of the apatite

Influence of the Fuel/Oxidant Ratio on the Elaboration of Binary Oxide Catalyst by a Microwave-Assisted Solution Combustion Method

Three series of binary metal oxide catalysts containing Ni, Cu, or Co oxides were prepared, fully characterized and tested in CO oxidation. The catalysts, with a constant transition metal loading of 10 wt%, were prepared from metal nitrates and urea mixtures by a microwave-assisted solution combustion method. The RV/OV ratio, corresponding to the stoichiometry of the reactants, calculated from their elemental oxidizing and reducing valences, was varied. In order to modify the redox character of the synthesis medium from the quantity of urea; an excess of urea was used for attaining reducing conditions, while a deficit of urea shifted the medium to oxidizing conditions. Three RV/OV ratios (0.9, 1.0, and 1.1) were selected to elaborate the different binary metal oxide catalysts, nine oxide catalysts were synthesized. Then, the influence of the stoichiometry (RV/OV ratio) on the bulk and surface properties of the binary metal oxide catalysts was investigated. Similarly, the influence of the RV/OV ratio on the CO oxidation activity was discussed and the optimal value of RV/OV ratio was identified. The results show that the increasing of the RV/OV ratio from 0.9 to 1.1, particularly in Ni- and Co-containing catalysts, induces stronger metal-aluminum interactions, in the form of aluminates phases, and that are correlated to the dramatic reduction of the CO oxidation activity. The best physicochemical properties and highest catalytic activities were achieved with the catalysts prepared in redox systems stoichiometrically balanced (RV/OV = 1). The Cu-containing catalysts presented the best catalytic activities in CO oxidation

Synthesis, Characterization and Catalytic Activity of Ternary Oxide Catalysts Using the Microwave-Assisted Solution Combustion Method

Ni−Co−Al, Ni−Cu−Al and Co−Cu−Al ternary oxide catalysts, with a fixed 5 wt% transition metal loading, were prepared by the microwave-assisted solution combustion method and tested in CO oxidation. The bulk and surface properties of the catalysts were investigated, using XRD, N2 adsorption–desorption, SEM, XPS and TEM techniques. XRD, XPS and TEM results revealed that nickel and cobalt were present as spinels on the surface and in the bulk. Differently, copper was preferentially present in “bulk-like” CuO-segregated phases. No interaction between the couples of transition metal species was detected, and the introduction of Cu-containing precursors into the Ni−Al or Co−Al combustion systems was not effective in preventing the formation of NiAl2O4 and CoAl2O4 spinels in the Ni− or Co-containing catalysts. Copper-containing catalysts were the most active, indicating that copper oxides are the effective active species for improving the CO oxidation activity

Binary Oxides Prepared by Microwave-Assisted Solution Combustion: Synthesis, Characterization and Catalytic Activity

Three different alumina-based Ni, Cu, Co oxide catalysts with metal loading of 10 wt %, and labeled 10Ni–Al, 10Co–Al and 10Cu–Al, were prepared by microwave-assisted solution combustion. Their morphological, structural and surface properties were deeply investigated by complementary physico-chemical techniques. Finally, the three materials were tested in CO oxidation used as test reaction for comparing their catalytic performance. The 10Cu–Al catalyst was constituted of copper oxide phase, while the 10Ni–Al and 10Co–Al catalysts showed the presence of “spinels” phases on the surface. The well-crystallized copper oxide phase in the 10Cu–Al catalyst, obtained by microwave synthesis, allowed for obtaining very high catalytic activity. With a CO conversion of 100% at 225 °C, the copper containing catalyst showed a much higher activity than that usually measured for catalytic materials of similar composition, thus representing a promising alternative for oxidation processes