Chemistry and kinematics of the pre-stellar core L1544: Constraints from H2D+

This paper explores the sensitivity of line profiles of H2D+, HCO+ and N2H+, observed towards the center of L1544, to various kinematic and chemical parameters. The total width of the H2D+ line can be matched by a static model and by models invoking ambipolar diffusion and gravitational collapse. The derived turbulent line width is b=0.15 km/s for the static case and <~ 0.05 km/s for the collapse case. However, line profiles of HC18O+ and N2H+ rule out the static solution. The double-peaked H2D+ line shape requires either infall speeds in the center that are much higher than predicted by ambipolar diffusion models, or a shell-type distribution of H2D+, as is the case for HCO+ and N2H+. At an offset of ~20 arcsec from the dust peak, the H2D+ abundance drops by a factor of ~5.Comment: four pages, two colour figures; to appear in The Dense Interstellar Medium in Galaxies, proceedings of the fourth Cologne-Bonn-Zermatt Symposium, Sept 22-26, 200

H_2D^+ in the High-mass Star-forming Region Cygnus X

H_2D^+ is a primary ion that dominates the gas-phase chemistry of cold dense gas. Therefore, it is hailed as a unique tool in probing the earliest, prestellar phase of star formation. Observationally, its abundance and distribution is, however, just beginning to be understood in low-mass prestellar and cluster-forming cores. In high-mass star-forming regions, H_2D^+ has been detected only in two cores, and its spatial distribution remains unknown. Here, we present the first map of the ortho-H_2D^+J_(k^+,k^-) = 1_(1,0) → 1_(1,1) and N_2H^+ 4-3 transition in the DR21 filament of Cygnus X with the James Clerk Maxwell Telescope, and N_2D^+ 3-2 and dust continuum with the Submillimeter Array. We have discovered five very extended (≤34, 000 AU diameter) weak structures in H2D+ in the vicinity of, but distinctly offset from, embedded protostars. More surprisingly, the H_2D^+ peak is not associated with either a dust continuum or N_2D^+ peak. We have therefore uncovered extended massive cold dense gas that was undetected with previous molecular line and dust continuum surveys of the region. This work also shows that our picture of the structure of cores is too simplistic for cluster-forming cores and needs to be refined: neither dust continuum with existing capabilities nor emission in tracers like N_2D^+ can provide a complete census of the total prestellar gas in such regions. Sensitive H_2D^+ mapping of the entire DR21 filament is likely to discover more of such cold quiescent gas reservoirs in an otherwise active high-mass star-forming region

Structure, Dynamics and Deuterium Fractionation of Massive Pre-Stellar Cores

High levels of deuterium fraction in N$_2$H$^+$ are observed in some pre-stellar cores. Single-zone chemical models find that the timescale required to reach observed values ($D_{\rm frac}^{{\rm N}_2{\rm H}^+} \equiv {\rm N}_2{\rm D}^+/{\rm N}_2{\rm H}^+ \gtrsim 0.1$) is longer than the free-fall time, possibly ten times longer. Here, we explore the deuteration of turbulent, magnetized cores with 3D magnetohydrodynamics simulations. We use an approximate chemical model to follow the growth in abundances of N$_2$H$^+$ and N$_2$D$^+$. We then examine the dynamics of the core using each tracer for comparison to observations. We find that the velocity dispersion of the core as traced by N$_2$D$^+$ appears slightly sub-virial compared to predictions of the Turbulent Core Model of McKee & Tan, except at late times just before the onset of protostar formation. By varying the initial mass surface density, the magnetic energy, the chemical age, and the ortho-to-para ratio of H$_2$, we also determine the physical and temporal properties required for high deuteration. We find that low initial ortho-to-para ratios ($\lesssim 0.01$) and/or multiple free-fall times ($\gtrsim 3$) of prior chemical evolution are necessary to reach the observed values of deuterium fraction in pre-stellar cores.Comment: 20 pages, 18 figures; accepted for publication in Ap

The dynamical properties of dense filaments in the infrared dark cloud G035.39-00.33

Infrared Dark Clouds (IRDCs) are unique laboratories to study the initial conditions of high-mass star and star cluster formation. We present high-sensitivity and high-angular resolution IRAM PdBI observations of N2H+ (1-0) towards IRDC G035.39-00.33. It is found that G035.39-00.33 is a highly complex environment, consisting of several mildly supersonic filaments (sigma_NT/c_s ~1.5), separated in velocity by <1 km s^-1 . Where multiple spectral components are evident, moment analysis overestimates the non-thermal contribution to the line-width by a factor ~2. Large-scale velocity gradients evident in previous single-dish maps may be explained by the presence of substructure now evident in the interferometric maps. Whilst global velocity gradients are small (<0.7 km s^-1 pc^-1), there is evidence for dynamic processes on local scales (~1.5-2.5 km s^-1 pc^-1 ). Systematic trends in velocity gradient are observed towards several continuum peaks. This suggests that the kinematics are influenced by dense (and in some cases, starless) cores. These trends are interpreted as either infalling material, with accretion rates ~(7 \pm 4)x10^-5 M_sun yr^-1 , or expanding shells with momentum ~24 \pm 12 M_sun km s^-1 . These observations highlight the importance of high-sensitivity and high-spectral resolution data in disentangling the complex kinematic and physical structure of massive star forming regions.Comment: 25 pages, 23 figures, accepted for publication in MNRA

The chemical structure of the very young starless core L1521E

L1521E is a dense starless core in Taurus that was found to have relatively low molecular depletion by earlier studies, thus suggesting a recent formation. We aim to characterize the chemical structure of L1521E and compare it to the more evolved L1544 pre-stellar core. We have obtained $\sim$2.5$\times$2.5 arcminute maps toward L1521E using the IRAM-30m telescope in transitions of various species. We derived abundances for the species and compared them to those obtained toward L1544. We estimated CO depletion factors. Similarly to L1544, $c$-C$_3$H$_2$ and CH$_3$OH peak at different positions. Most species peak toward the $c$-C$_3$H$_2$ peak. The CO depletion factor derived toward the $Herschel$ dust peak is 4.3$\pm$1.6, which is about a factor of three lower than that toward L1544. The abundances of sulfur-bearing molecules are higher toward L1521E than toward L1544 by factors of $\sim$2-20. The abundance of methanol is similar toward the two cores. The higher abundances of sulfur-bearing species toward L1521E than toward L1544 suggest that significant sulfur depletion takes place during the dynamical evolution of dense cores, from the starless to pre-stellar stage. The CO depletion factor measured toward L1521E suggests that CO is more depleted than previously found. Similar CH$_3$OH abundances between L1521E and L1544 hint that methanol is forming at specific physical conditions in Taurus, characterized by densities of a few $\times$10$^4$ cm$^{-3}$ and $N$(H$_2$)$\gtrsim$10$^{22}$ cm$^{-2}$, when CO starts to catastrophically freeze-out, while water can still be significantly photodissociated, so that the surfaces of dust grains become rich in solid CO and CH$_3$OH, as already found toward L1544. Methanol can thus provide selective crucial information about the transition region between dense cores and the surrounding parent cloud.Comment: Accepted for publication in A&A, abstract abridge

Response to 'No evidence of SARS-CoV-2 infection by polymerase chain reaction or serology in children with pseudo-chilblain'. Reply from the authors

Dear Editor, Recalcati et al. conclude that chilblain-like lesions (CLLs) are part of the spectrum of COVID-19 based on reports of SARS-CoV-2 in endothelial cells of skin biopsies assessed by immunohistochemistry and electron microscopy (EM).1 Nevertheless, the conclusion does not seem to be adequately supported by the data. Recalcati et al. expand their previously reported case series to include 32 patients with CLLs. In 21 of 32 cases, no nasopharyngeal swab (NPS) was tested for SARS-CoV-2. Two of 11 patients subjected to molecular testing were positive for SARS-CoV-2, but no serological test was performed to verify the seroconversion. Three patients tested positive for IgM and negative for IgG antibodies without any confirmation of infection through NPS

The first frost in the Pipe Nebula

Spectroscopic studies of ices in nearby star-forming regions indicate that ice mantles form on dust grains in two distinct steps, starting with polar ice formation (H2O rich) and switching to apolar ice (CO rich). We test how well the picture applies to more diffuse and quiescent clouds where the formation of the first layers of ice mantles can be witnessed. Medium-resolution near-infrared spectra are obtained toward background field stars behind the Pipe Nebula. The water ice absorption is positively detected at 3.0 micron in seven lines of sight out of 21 sources for which observed spectra are successfully reduced. The peak optical depth of the water ice is significantly lower than those in Taurus with the same visual extinction. The source with the highest water-ice optical depth shows CO ice absorption at 4.7 micron as well. The fractional abundance of CO ice with respect to water ice is 16+7-6 %, and about half as much as the values typically seen in low-mass star-forming regions. A small fractional abundance of CO ice is consistent with some of the existing simulations. Observations of CO2 ice in the early diffuse phase of a cloud play a decisive role in understanding the switching mechanism between polar and apolar ice formation.Comment: 17 pages, 8 figures, accepted by A&

Gas Kinematics and Excitation in the Filamentary IRDC G035.39-00.33

Some theories of dense molecular cloud formation involve dynamical environments driven by converging atomic flows or collisions between preexisting molecular clouds. The determination of the dynamics and physical conditions of the gas in clouds at the early stages of their evolution is essential to establish the dynamical imprints of such collisions, and to infer the processes involved in their formation. We present multi-transition 13CO and C18O maps toward the IRDC G035.39-00.33, believed to be at the earliest stages of evolution. The 13CO and C18O gas is distributed in three filaments (Filaments 1, 2 and 3), where the most massive cores are preferentially found at the intersecting regions between them. The filaments have a similar kinematic structure with smooth velocity gradients of ~0.4-0.8 km s-1 pc-1. Several scenarios are proposed to explain these gradients, including cloud rotation, gas accretion along the filaments, global gravitational collapse, and unresolved sub-filament structures. These results are complemented by HCO+, HNC, H13CO+ and HN13C single-pointing data to search for gas infall signatures. The 13CO and C18O gas motions are supersonic across G035.39-00.33, with the emission showing broader linewidths toward the edges of the IRDC. This could be due to energy dissipation at the densest regions in the cloud. The average H2 densities are ~5000-7000 cm-3, with Filaments 2 and 3 being denser and more massive than Filament 1. The C18O data unveils three regions with high CO depletion factors (f_D~5-12), similar to those found in massive starless cores.Comment: 20 pages, 14 figures, 6 tables, accepted for publication in MNRA