An extreme ultraviolet spectrometer experiment for the Shuttle Get Away Special Program

An extreme ultraviolet (EUV) spectrometer experiment operated successfully during the STS-7 mission in an experiment to measure the global and diurnal variation of the EUV airglow. The spectrometer is an F 3.5 Wadsworth mount with mechanical collimator, a 75 x 75 mm grating, and a bare microchannel plate detector providing a spectral resolution of 7 X FWHM. Read-out of the signal is through discrete channels or resistive anode techniques. The experiment includes a microcomputer, 20 Mbit tape recorder, and a 28V, 40 Ahr silver-zinc battery. It is the first GAS payload to use an opening door. The spectrometer's 0.1 x 4.2 deg field of view is pointed vertically out of the shuttle bay. During the STS-7 flight data were acquired continuously for a period of 5 hours and 37 minutes, providing spectra of the 570 A to 850 A wavelength region of the airglow. Five diurnal cycles of the 584 A emission of neutral helium and the 834 A emission of ionized atomic oxygen were recorded. The experiment also recorded ion events and pressure pulses associated with thruster firings. The experiment is to fly again on Mission 41-F

Chem-News - An On-Line Pesticide Information Program

Computerization of pesticide information is rapidly becoming a necessity as regulatory agencies expand their activities through enforcement, monitoring, and certification of pesticide applicators. Educational institutions responsible for providing pesticide information and pesticide applicator training for certification must also expand their capabilities for immediate updating and faster retrieval. Two programs at Cornell University, the Chemical-Pesticides Program and the Pesticide Impact Assessment Program (PIAP), are presently involved in developing on-line pesticide information for researchers, extension personnel, and regulatory agencies, as well as for those using pesticides

Factorial Moments in a Generalized Lattice Gas Model

We construct a simple multicomponent lattice gas model in one dimension in which each site can either be empty or occupied by at most one particle of any one of $D$ species. Particles interact with a nearest neighbor interaction which depends on the species involved. This model is capable of reproducing the relations between factorial moments observed in high--energy scattering experiments for moderate values of $D$. The factorial moments of the negative binomial distribution can be obtained exactly in the limit as $D$ becomes large, and two suitable prescriptions involving randomly drawn nearest neighbor interactions are given. These results indicate the need for considerable care in any attempt to extract information regarding possible critical phenomena from empirical factorial moments.Comment: 15 pages + 1 figure (appended as postscript file), REVTEX 3.0, NORDITA preprint 93/4

The [4+2]‐Cycloaddition of α‐Nitrosoalkenes with Thiochalcones as a Prototype of Periselective Hetero‐Diels–Alder Reactions—Experimental and Computational Studies

The [4+2]‐cycloadditions of α‐nitrosoalkenes with thiochalcones occur with high selectivity at the thioketone moiety of the dienophile providing styryl‐substituted 4H‐1,5,2‐oxathiazines in moderate to good yields. Of the eight conceivable hetero‐Diels–Alder adducts only this isomer was observed, thus a prototype of a highly periselective and regioselective cycloaddition has been identified. Analysis of crude product mixtures revealed that the α‐nitrosoalkene also adds competitively to the thioketone moiety of the thiochalcone dimer affording bis‐heterocyclic [4+2]‐cycloadducts. The experiments are supported by high‐level DFT calculations that were also extended to related hetero‐Diels–Alder reactions of other nitroso compounds and thioketones. These calculations reveal that the title cycloadditions are kinetically controlled processes confirming the role of thioketones as superdienophiles. The computational study was also applied to the experimentally studied thiochalcone dimerization, and showed that the 1,2‐dithiin and 2H‐thiopyran isomers are in equilibrium with the monomer. Again, the DFT calculations indicate kinetic control of this process

Extended-soft-core Baryon-Baryon Model II. Hyperon-Nucleon Interaction

The YN results are presented from the Extended-soft-core (ESC) interactions. They consist of local- and non-local-potentials due to (i) One-boson-exchange (OBE), with pseudoscalar-, vector-, scalar-, and axial-vector-nonets, (ii) Diffractive exchanges, (iii) Two-pseudoscalar exchange, and (iv) Meson-pair-exchange (MPE). This model, called ESC04, describes NN and YN in a unified way using broken flavor SU(3)-symmetry. Novel ingredients are the inclusion of (i) the axial-vector-mesons, (ii) a zero in the scalar- and axial-vector meson form factors. We describe simultaneous fits to the NN- and YN-data, using four options in the ESC-model. Very good fits were obtained. G-matrix calculations with these four options are also reported. The obtained well depths (U_\Lambda, U_\Sigma, U_\Xi) reveal distinct features of ESC04a-d. The \Lambda\Lambda-interactions are demonstrated to be consistent with the observed data of_{\Lambda\Lambda}^6He. The possible three-body effects are investigated by considering phenomenologically the changes of the vector-meson masses in a nuclear medium.Comment: preprint vesion 66 pages, two-column version 27 pages, 17 figure

The Manchester Color Wheel: development of a novel way of identifying color choice and its validation in healthy, anxious and depressed individuals

Abstract Background For the purposes of our research programme we needed a simple, reliable and validated method for allowing choice of a color in response to a series of questions. On reviewing the literature no such instrument was available and this study aimed to rectify this situation. This was achieved by developing a simple method of presenting a series of colors to people validating it in healthy volunteers and in individuals where color choice might be distorted, namely anxiety and depression. Methods A series of different presentations of four shades of eight colors and grey, as well as black and white were evaluated. 'Mood', 'favourite' and 'drawn to' colors were assessed in 105 healthy, 108 anxious and 110 depressed participants. The positive, neutral or negative attribution of these colors was recorded in a further 204 healthy volunteers. Results The circular presentation of colors was most favoured (Color Wheel). Yellow was the most 'drawn to' color and blue the commonest 'favourite' color in all subjects. Yellow was most often associated with a normal mood and grey with an anxious or depressed mood. Different shades of the same color had completely different positive or negative connotations. Reproducibility was exceptionally high when color choice was recorded in positive, neutral or negative terms. Conclusions The Color Wheel could be used to assess health status, mood or even treatment outcome in a variety of clinical situations. It may also have utility in circumstances where verbal communication may not be optimal, such as with children.</p

Shorewards Upslope of the Layer of Minimum Oxygen Off Bombay: Its Influence on Marine Biology, Especially Fisheries

Shorewards Upslope of the Layer of Minimum Oxygen Off Bombay: Its Influence on Marine Biology, Especially Fisherie