392 research outputs found
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Novel carbonaceous materials for lithium secondary batteries
Carbonaceous materials have been synthesized using pillared clays (PILCs) as templates. The PILC was loaded with organic materials such as pyrene in the liquid and vapor phase, styrene in the vapor phase, trioxane, ethylene and propylene. The samples were then pyrolyzed at 700 C in an inert atmosphere, followed by dissolution of the inorganic template by conventional demineralization methods. X-ray powder diffraction of the carbons showed broad d{sub 002} peaks in the diffraction pattern, indicative of a disordered or turbostratic system. N{sub 2} BET surface areas of the carbonaceous materials range from 10 to 100 m{sup 2}/g. There is some microporosity (r < 1 nm) in the highest surface area carbons. Most of the surface area, however, comes from a mixture of micro and mesopores with radii of 2--5 nm. Electrochemical studies were performed on these carbons. Button cells were fabricated with capacity- limiting carbon pellets electrodes as the cathode a/nd metallic lithium foil as the anode. Large reversible capacities (up to 850 mAh/g) were achieved for most of the samples. The irreversible capacity loss was less than 180 mAh/g after the first cycle, suggesting that these types of carbon materials are very stable to lithium insertion and de-insertion reactions
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Small angle neutron and X-ray scattering studies of carbons prepared using inorganic templates
Small angle neutron (SANS) and X-ray (SAXS) scattering analyses of carbons derived from organic-loaded inorganic template materials, used as anodes in lithium ion cells, have been performed. Two clays were used as templates to load the organic precursors, pillared montmorrillonite (PILC), a layered silicate clay whose sheets have been permanently propped open by sets of thermally stable molecular props, and sepiolite, a natural channeled clay. Five different organic precursors were used to load the PILC: pyrene, styrene, pyrene/trioxane copolymer, ethylene and propylene, whereas only propylene and ethylene were used to load sepiolite. Pyrolysis took place at 700{degrees}C under nitrogen. Values such as hole radius, fractal dimension, cutoff length and density of the final carbons will be compared as a function of the clay and carbon precursors
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Anomalous small angle x-ray scattering study of layered silicate clays containing Ni(II) and Er(III)
These studies concern the synthesis of heterogeneous catalysts and the incorporation of heavy metals in trapping media. The Ni(II) containing clays were synthesized at 200{degree}C whereas those containing Er(III) were ion-exchanged natural clays. For the first system, ASAXS data were measured at 5 different energies near the K{alpha} edge of Ni at three different reaction times: unreacted, 4 hrs, and 15 hrs, when the crystallization is essentially complete. The data for the unreacted sample showed no correlations for a lamellar particle, while that reacted for 4 hrs indicated the evolution of lamella, and the crystallized sample (15 hrs) exhibits much larger lamellar correlations. Systematic variations are seen in the data for the 4 hr and 15 hr samples that are due to the anomalous scattering from the ordered Ni atoms in the layered silicates. The erbium study provides the first scattering measurements of heavy metal ion salvation and migration in clays, which has implications for both catalysis and environmental issues. Systematic energy-dependent variations in the signals near the L{sub III} edge of Er are observed for the hydrated sample, but not for the ``dry,`` as-prepared sample
Effect of clay type on dispersion and barrier properties of hydrophobically modified poly(vinyl alcohol)-bentonite nanocomposites
The oxygen and water vapor permeability at high relative humidity was studied for composite films formed by incorporation of three different bentonites (MMT) into an ethylene-modified, water-soluble poly(vinyl alcohol), EPVOH. The oxygen permeability decreased linearly with an increased addition of hydrophilic MMTs. X-ray diffraction and Fourier transform infrared spectroscopy suggested a homogeneous distribution in the thickness direction with disordered and probably exfoliated structures for hydrophilic MMTs. In contrast, organophilic modified clay showed an intercalated structure with the clay preferentially located at the lower film surface, a combination which was however efficient in reducing the water vapor- and oxygen permeabilities at low addition levels. Composite films of EPVOH and Na+-exchanged MMT resulted in high resistance to dissolution in water, which was ascribed to strong interactions between the components resulting from matching polarities. Annealing the films at 120°C resulted in enhanced resistance to water dissolution and a further reduction in oxygen permeabilit
Hydrophobically modified poly(vinyl alcohol) and bentonite nanocomposites thereof: Barrier, mechanical, and aesthetic properties
Composite films were formed by incorporating three different bentonites into an ethylene modified, water-soluble poly(vinyl alcohol), EPVOH. The interaction of EPVOH with both hydrophilic and hydrophobic bentonites was investigated. EPVOH provided lower water vapor and oxygen transmission rates compared to a conventional PVOH grade when exposed at high relative humidities (70-90% RH). EPVOH films which exhibited oxygen barrier properties comparable to that of a biaxially oriented PET packaging film at 80% RH were produced. High compatibility between EPVOH and hydrophilic bentonites provided an even distribution of clay platelets in the composites. A strong increase in Young's modulus with increased addition of any of the three bentonites was found. At low addition levels the hydrophobic bentonite proved to be effective in terms of maintaining high elongation at break, high transparency and high gloss
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