1,182 research outputs found
Optical study of the vibrational and dielectric properties of BiMnO3
BiMnO3 (BMO), ferromagnetic (FM) below Tc = 100 K, was believed to be also
ferroelectric (FE) due to a non-centro-symmetric C2 structure, until
diffraction data indicated that its space group is the centro-symmetric C2/c.
Here we present infrared phonon spectra of BMO, taken on a mosaic of single
crystals, which are consistent with C2/c at any T > 10 K, as well as
room-temperature Raman data which strongly support this conclusion. We also
find that the infrared intensity of several phonons increases steadily for
decreasing T, causing the relative permittivity of BMO to vary from 18.5 at 300
K to 45 at 10 K. At variance with FE materials of displacive type, no
appreciable softening has been found in the infrared phonons. Both their
frequencies and intensities, moreover, appear insensitive to the FM transition
at Tc
URBAN 3 - PARCO DI SPINA 4. PROMENADE DELL'ARTE E DELLA CULTURA INDUSTRIALE
Presentazione del concorso e del progetto PROMENADE DELL'ARTE E DELLA CULTURA INDUSTRIALE di Politecnico di Torino , Accademia Albertina di Belle Arti e CittĂ di Torino, finanziato nell'ambito del Fondo Europeo di Sviluppo Regionale 2007/2013 - Por Fesr. In www.contemporarytorinopiemonte.it/.../ Portale di CittĂ di Torino, Regione Piemonte e Fondazione per l'Arte Moderna e Contemporanea - CR
Recent advances in analytical approaches for the standardization and quality of polyphenols of propolis
Analytical approaches utilized for the characterization of polyphenols from propolis useful for the
determination of its quality is investigated in this study. A qualitative and quantitative evaluation of
propolis bioactive molecules is of interest in medicine and nutraceuticals. Recent powerful analytical
techniques are of great utility to separate and quantify polyphenols in extracts and finished products
due to their capacity to produce typical fingerprints and a reliable identification of many components.
According to this, an HPLC-UV-MS procedure was validated and applied for the characterization and
quantification of bioactive substances in propolis and for an accurate assessment of their content in
extract samples. By using this analytical approach, we obtained specific compositions related to brown
propolis acquired from different geographic areas (and preparations and treatment). This is more
important by considering the scientific opinion of European Food Safety Authority (EFSA) which
provided a negative response related to health claims of propolis and its polyphenols. These results
prove that HPLC-MS is an attractive tool for the standardization and quality control of propolis and may
be realistically applied to screen raw material and to evaluate finished commercial preparations and
nutraceutical benefits
Power Corrections to Perturbative QCD and OPE in Gluon Green Functions
We show that QCD Green functions in Landau Gauge exhibit sizable
corrections to the expected perturbative behavior at energies as high as 10
GeV. We argue that these are due to a -condensate which does not vanish
in Landau gauge.Comment: 3 pages 1 figure lattice2001 (gaugetheories
THERIA_G: a software program to numerically model prograde garnet growth
We present the software program THERIA_G, which allows for numerical simulation of garnet growth in a given volume of rock along any pressure-temperature-time (P-T-t) path. THERIA_G assumes thermodynamic equilibrium between the garnet rim and the rock matrix during growth and accounts for component fractionation associated with garnet formation as well as for intracrystalline diffusion within garnet. In addition, THERIA_G keeps track of changes in the equilibrium phase relations, which occur during garnet growth along the specified P-T-t trajectory. This is accomplished by the combination of two major modules: a Gibbs free energy minimization routine is used to calculate equilibrium phase relations including the volume and composition of successive garnet growth increments as P and T and the effective bulk rock composition change. With the second module intragranular multi-component diffusion is modelled for spherical garnet geometry. THERIA_G allows to simulate the formation of an entire garnet population, the nucleation and growth history of which is specified via the garnet crystal size frequency distribution. Garnet growth simulations with THERIA_G produce compositional profiles for the garnet porphyroblasts of each size class of a population and full information on equilibrium phase assemblages for any point along the specified P-T-t trajectory. The results of garnet growth simulation can be used to infer the P-T-t path of metamorphism from the chemical zoning of garnet porphyroblasts. With a hypothetical example of garnet growth in a pelitic rock we demonstrate that it is essential for the interpretation of the chemical zoning of garnet to account for the combined effects of the thermodynamic conditions of garnet growth, the nucleation history and intracrystalline diffusio
Renormalization of minimally doubled fermions
We investigate the renormalization properties of minimally doubled fermions,
at one loop in perturbation theory. Our study is based on the two particular
realizations of Borici-Creutz and Karsten-Wilczek. A common feature of both
formulations is the breaking of hyper-cubic symmetry, which requires that the
lattice actions are supplemented by suitable counterterms. We show that three
counterterms are required in each case and determine their coefficients to one
loop in perturbation theory. For both actions we compute the vacuum
polarization of the gluon. It is shown that no power divergences appear and
that all contributions which arise from the breaking of Lorentz symmetry are
cancelled by the counterterms. We also derive the conserved vector and
axial-vector currents for Karsten-Wilczek fermions. Like in the case of the
previously studied Borici-Creutz action, one obtains simple expressions,
involving only nearest-neighbour sites. We suggest methods how to fix the
coefficients of the counterterms non-perturbatively and discuss the
implications of our findings for practical simulations.Comment: 23 pages, 1 figur
Trivariate Burr-III copula with applications to income data
In this work, Bivariate Burr-III copula is extended to the trivariate case. This copula seems to be very general and analytically manageable and it provides an alternative to the commonly employed elliptical copulas (such as the Gaussian or the Stutent's t ones) since they have, roughly, the same number of parameters. Several applications to income and wine data are described in the paper. They show that the Trivariate Burr-III copula is, in general, able to capture the dependence structure implicit in observed trivariate data. Moreover, they show that the third-order interaction parameter results, in some cases, significant at 1\% 1 % significance level while, in other cases, it can be removed from the fitted model. The ability of the Trivariate Burr-III copula in representing the dependence structure implicit in the considered data is compared with the ones of other well known copulas: the Clayton copula, the t copula, and the Skew-t copula. It results that the Trivariate Burr-III copula provides a good fitting and turns out to be the best performer in fitting the considered wine data but, on income data, the best performers are the t and Skew-t copulas. The over-performance of the last two copulas on income data is probably due to their ability in representing right-tail dependence (a kind of dependence that is not taken into account by the Trivariate Burr-III copula)
Moments of parton evolution probabilities on the lattice within the Schroedinger functional scheme
We define, within the Schroedinger functional scheme (SF), the matrix
elements of the twist-2 operators corresponding to the first two moments of
non-singlet parton densities. We perform a lattice one-loop calculation that
fixes the relation between the SF scheme and other common schemes and shows the
main source of lattice artefacts. This calculation sets the basis for a
numerical evaluation of the non-perturbative running of parton densities.Comment: Latex file, 4 figures, 15 page
Non-perturbative renormalization of moments of parton distribution functions
We compute non-perturbatively the evolution of the twist-2 operators
corresponding to the average momentum of non-singlet quark densities. The
calculation is based on a finite-size technique, using the Schr\"odinger
Functional, in quenched QCD. We find that a careful choice of the boundary
conditions, is essential, for such operators, to render possible the
computation. As a by-product we apply the non-perturbatively computed
renormalization constants to available data of bare matrix elements between
nucleon states.Comment: Lattice2003(Matrix); 3 pages, 3 figures. Talk by A.
Coexistence of pressure-induced structural phases in bulk black phosphorus: a combined x-ray diffraction and Raman study up to 18 GPa
We report a study of the structural phase transitions induced by pressure in
bulk black phosphorus by using both synchrotron x-ray diffraction for pressures
up to 12.2 GPa and Raman spectroscopy up to 18.2 GPa. Very recently black
phosphorus attracted large attention because of the unique properties of
fewlayers samples (phosphorene), but some basic questions are still open in the
case of the bulk system. As concerning the presence of a Raman spectrum above
10 GPa, which should not be observed in an elemental simple cubic system, we
propose a new explanation by attributing a key role to the non-hydrostatic
conditions occurring in Raman experiments. Finally, a combined analysis of
Raman and XRD data allowed us to obtain quantitative information on presence
and extent of coexistences between different structural phases from ~5 up to
~15 GPa. This information can have an important role in theoretical studies on
pressure-induced structural and electronic phase transitions in black
phosphorus
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