Simulation to recover niobium and tantalum from the tin slags of the old penouta mine: A case study

Demand for niobium and tantalum is increasing exponentially as these are essential ingre-dients for the manufacture of, among others, capacitors in technological devices and ferroniobium. Mine tailings rich in such elements could constitute an important source of Nb and Ta in the future and alleviate potential supply risks. This paper evaluates the possibility of recovering niobium and tantalum from the slags generated during the tin beneficiation process of mine tailings from the old Penouta mine, located in Spain. To do so, a simulation of the processes required to bene-ficiate and refine both elements is carried out. After carbothermic tin reduction, the slags are sent to a hydrometallurgical process where niobium oxide and tantalum oxide are obtained at the end. Reagents, water, and energy consumption, in addition to emissions, effluents, and product yields, are assessed. Certain factors were identified as critical, and recirculation was encouraged in the model to maximise production and minimise reagents’ use and wastes. With this simulation, considering 3000 production hours per year, the metal output from the tailings of the old mine could cover around 1% and 7.4% of the world annual Nb and Ta demand, respectively. © 2021 by the authors. Licensee MDPI, Basel, Switzerland

A proposal for cost-related and market-oriented train running charges

[EN] This paper examines some key aspects of a charging system for promoting railway transport, including charges reflecting a clear relationship with costs (transparency) and charges reflecting the quality of the infrastructure manager¿s service. Train running charges recover track-related costs and can help to develop a charging system that meets these requirements. To orient train running charges to the market, a method for processing track maintenance and renewal costs is proposed whereby the quality of the service provided by an infrastructure is measured according to its utility to the railway undertaking. To achieve transparency, a single indicator is used for cost planning and the subsequent levying of costs on railway undertakings. The paper includes an example of how proposed train running charges would be calculated according to data from 14 European countries. The example shows that short-distance trains generate the lowest maintenance and renewal costs, followed by long-distance trains and freight trains.This work was supported by the Spanish Ministerio de Fomento [grant number PT-2007-056-05CCPP].Calvo, F.; De Oña, J.; De Oña, R.; López-Maldonado, G.; Garach, L. (2014). A proposal for cost-related and market-oriented train running charges. Transportation Planning and Technology. 37(4):354-372. https://doi.org/10.1080/03081060.2014.897127S354372374Baumgartner, J. P. 2001. “Prices and Costs in the Railway Sector.” Laboratoire d'Intermodalité des Transports et de Planification. École Polytechnique Fédérale de Lausanne. Accessed February 4. http://litep.epfl.ch–2014Calvo, F., and J. de Oña. 2012a. “An Approach to Mark-Ups through Capacity Charges.”Proceedings of the ICE – Transport. Accessed February 4. http://www.icevirtuallibrary.com/content/article/10.1680/tran.11.00050.Calvo, F., & De Oña, J. (2012). Are rail charges connected to costs? Journal of Transport Geography, 22, 28-33. doi:10.1016/j.jtrangeo.2011.11.004Calvo, F., de Oña, J., López, G., Garach, L., & de Oña, R. (2013). Rail track costs management for efficient railway charges. Proceedings of the Institution of Civil Engineers - Transport, 166(6), 325-335. doi:10.1680/tran.11.00001Calvo, F., de Oña, J., & Nash, A. (2007). Proposed Infrastructure Pricing Methodology for Mixed-Use Rail Networks. Transportation Research Record: Journal of the Transportation Research Board, 1995(1), 9-16. doi:10.3141/1995-02CENIT, TIS PT, IWW, and HERRY. 2007. “RailCalc. Calculation of Charges for the Use of Rail Infrastructure.” Prepared for the European Commission Directorate General for Energy and Transport. Accessed February 4. http://ec.europa.eu/transport/rail/legislation/doc/railcalc_discussion_paper_final.pdf.ECMT (European Conference of Ministers of Transport). 2005. “Charges for the Use of Infrastructure in ECMT Railways.” Draft final report. ECMT/CS/CF(2005)1/REV1. Accessed February 4. http://lnweb90.worldbank.org/ECA/Transport.nsf/ECADocByUnid/2CF8BE276F63A37D85256FB20043A05D?Opendocument.EPFL (Ecole Polytechnique Féderale de Lausanne). 2003. “IMPROVERAIL: IMPROVEd Tools for RAILway Capacity and Access Management.” Accessed February 4. http://litep.epfl.ch.Network Rail. 2006. “Usage Costs – Assessment Methodology.” Draft for consultation. Accessed February 4. http://www.networkrail.co.uk/browse%20documents/regulatory%20documents/access%20charges%20reviews/consultations%20on%20future%20charging/variable%20track%20access%20charges/g-%20usage%20costs%20methodology%20sept%2006.pdf.Nyström, B., & Söderholm, P. (2010). Selection of maintenance actions using the analytic hierarchy process (AHP): decision-making in railway infrastructure. Structure and Infrastructure Engineering, 6(4), 467-479. doi:10.1080/15732470801990209ORR (Office of Rail Regulation). 2005. “Revision of Variable Usage and Electrification Asset Usage Charges: Final Report.” Accessed February 4. http://www.rail-reg.gov.uk/upload/pdf/bah_variable-usage-initial-report_jan05.pdf.Quinet, E. (2003). Short term adjustments in rail activity: the limited role of infrastructure charges. Transport Policy, 10(1), 73-79. doi:10.1016/s0967-070x(02)00047-1Thomas, J. 2002. “EU Task Force on Rail Infrastructure Charging: Summary Findings on Best Practice in Marginal Cost Pricing.” IMPRINT-EUROPE. Implementing Reform in Transport. Effective Use of Research on Pricing in Europe. A European Commission-funded Thematic Network (2001–2004). Accessed February 4. www.imprint-eu.org/public/Presentations/imprint3_Thomas.ppt.UIC (International Union of Railways). 2008. “Lasting Infrastructure Cost Benchmarking (LICB).” Summary Report. Accessed February 4. http://www.uic.org/spip.php?article582

Molecular elucidation of CO2 methanation over a highly active, selective and stable LaNiO3/CeO2-derived catalyst by in situ FTIR and NAP-XPS

The CO2 methanation mechanism over the highly active (TOF=75.1 h−1), selective (>92%) and stable 10% LaNiO3/CeO2-derived catalyst is still unresolved. The surface of the catalyst is monitored under hydrogenation (H2), oxidizing (CO2) and CO2 methanation (H2 +CO2) conditions by near ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) using synchrotron radiation. Meanwhile, the main reaction intermediates are identified by in situ FTIR analysis. NAP-XPS experiments confirm that LaNiO3 perovskite reduction leads to the ex-solution of Ni0 nanoparticles and Ni2+single bondCeO2−x and Ni2+single bondLa2O3 interfaces conformation, favouring the CO2 adsorption and the H2 dissociation/transfer. In situ FTIR experiments combined with the C1s spectra (NAP-XPS) suggest that the CO2 activation occurs on CeO2−x (oxygen vacancies and OH–) at low temperatures, in the form of bicarbonates; whereas, mono-/bidentate carbonates are formed on different strength La2O3 sites at increasing temperatures. These species are consecutively reduced to formates, as the main reaction intermediate, and methane by the H spilled from Ni0 nanoparticles near to NiOsingle bondCeO2−x and NiOsingle bondLa2O3 interfaces.Support for this study was provided by Projects PID2019–105960RB-C21 and PID2019–105960RB-C22 by MCIN/AEI/10.13039/501100011033, the Basque Government (Project IT1509–2022), Generalitat Valenciana (CIPROM/2021/74) and ALBA synchrotron. One of the authors (JAOC) acknowledges the postdoctoral research grant (DOCREC20/49) provided by the University of the Basque Country (UPV/EHU)

Soluble Ruthenium Phthalocyanines as Semiconductors for Organic Thin-Film Transistors

Ruthenium phthalocyanine (RuPcs) are multipurpose compounds characterized by their remarkable reactivity and photoelectronic properties, which yield a broad synthetic scope and easy derivatization at the axial position. However, RuPcs have been underexplored for use in organic thin-film transistors (OTFTs), and therefore new studies are necessary to provide basic insight and a first approach in this new application. Herein, two novel RuPc derivatives, containing axial pyridine substituents with aliphatic chains (RuPc(CO)(PyrSiC6) (1) and RuPc(PyrSiC6)2 (2), were synthesized, characterized, and tested as the organic semiconductor in OTFTs. RuPc thin-films were characterized by X-ray diffraction (XRD), and atomic force microscopy (AFM) to assess film morphology and microstructure. 1 displayed comparable p-type device performance to other phthalocyanine-based OTFTs of similar design, with an average field effect mobility of 2.08×10−3 cm2 V−1 s−1 in air and 1.36×10−3 cm2 V−1 s−1 in nitrogen, and threshold voltages from −11 V to −20 V. 2 was found to be non-functional as the semiconductor in the device architecture used, likely as a result of significant differences in thin-film formation. The results of this work illustrate a promising starting point for future development of RuPc electronic devices, particularly in this new family of OTFT

Candida albicans Hyphal Extracellular Vesicles Are Different from Yeast Ones, Carrying an Active Proteasome Complex and Showing a Different Role in Host Immune Response.

Candida albicans is the principal causative agent of lethal fungal infections, predominantly in immunocompromised hosts. Extracellular vesicles (EVs) have been described as crucial in the interaction of microorganisms with their host. Since the yeast-to-hypha transition is an important virulence trait with great impact in invasive candidiasis (IC), we have addressed the characterization of EVs secreted by hyphal cells (HEVs) from C. albicans, comparing them to yeast EVs (YEVs). YEVs comprised a larger population of bigger EVs with mainly cell wall proteins, while HEVs were smaller, in general, and had a much higher protein diversity. YEVs were able to rescue the sensitivity of a cell wall mutant against calcofluor white, presumably due to the larger amount of cell wall proteins they contained. On the other hand, HEVs also contained many cytoplasmic proteins related to protein metabolism and intracellular protein transport and the endosomal sorting complexes required for transport (ESCRT) pathway related to exosome biogenesis, pointing to an intracellular origin of HEVs. Interestingly, an active 20S proteasome complex was secreted exclusively in HEVs. Moreover, HEVs contained a greater number of virulence-related proteins. As for their immunogenic role, both types of EV presented immune reactivity with human sera from patients suffering invasive candidiasis; however, under our conditions, only HEVs showed a cytotoxic effect on human macrophages and could elicit the release of tumor necrosis factor alpha (TNF-α) by these macrophages. IMPORTANCE This first analysis of HEVs of C. albicans has shown clear differences between them and the YEVs of C. albicans, showing their relevance and possible use in the discovery of new diagnostic markers and treatment targets against C. albicans infections. The data obtained point to different mechanisms of biogenesis of YEVs and HEVs, as well as different involvements in cell biology and host interaction. YEVs played a more relevant role in cell wall maintenance, while HEVs were more closely related to virulence, as they had greater effects on human immune cells. Importantly, an active 20S proteosome complex was described as a fungal-EV cargo. A deeper study of its role and those of many other proteins exclusively detected in HEVs and involved in different relevant biological processes of this fungus could open up interesting new areas of research in the battle against C. albicans

Comunidades, hábitat y tipos de suelos sobre los que se desarrolla la digital de Sierra Nevada

La Digital de Sierra Nevada crece sobre suelos generalmente poco evolucionados, presentando en la zona de máxima expansión de esta planta, un epipedon umbrico con un grado de saturación al cincuenta por ciento, de· creciendo su presencia cuando el epipedon disminuye en espesor y aumenta o decrece sensiblemente' su grado de saturación. Se incluye también la descripción botánica de la Digital de Sierra Nevada y los inventarios de cada una de las zonas experimentales.The digitalis from S. Nevada growes on few evolutioned soils so that the most evolutioned soli, were the plants are better represented, have a umbric horizon with a degree of saturation near 50 % which degrease which decrease when the depth of the mollic 'epipedon decrease and then also decrease the amounts of plants. It have inoluded also the botanic description and the floristic inventary

Utilización inadecuada de un servicio de urgencias hospitalario. Una evaluación con criterios explícitos

ResumenFundamentoExiste un crecimiento del número de visitas en los servicios de urgencias hospitalarios (SUH) con una elevada proporción de utilización inapropiada. Los métodos empleados para identificar el uso inadecuado basados en criterios implícitos limitan las comparaciones entre hospitales. El objetivo de este estudio es conocer la proporción de visitas inadecuadas en un SUH y sus factores asociados, utilizando un método objetivo.Material y métodoSe utilizó un instrumento basado en criterios explícitos e independientes del diagnóstico para identificar las visitas inapropiadas en una muestra aleatoria de 1.845 pacientes mayores de 14 años que acudieron a los servicios médicos de un SUH, y se analizaron los factores asociados a la demanda inadecuada.ResultadosLa proporción de urgencias inadecuadas fue del 26,8% (495/1.845). En el análisis bivariante la menor edad, la ausencia de patología asociada, las visitas espontáneas y determinados grupos diagnósticos (enfermedades de la piel, músculo-esqueléticas, mentales y sintamos mal definidos) se asociaron a una mayor proporción de uso inadecuado del SUH. Al ajustar las variables mediante regresión logística, la edad, la patología asociada, las consultas espontáneas y los grupos diagnósticos, mantuvieron la asociación con el uso inadecuado, pero otras variables como el ser mujer y la llegada al SUH fuera del turno de noche también se asociaron a una mayor utilización inadecuada.ConclusionesAl menos la cuarta parte de las visitas realizadas en los servicios médicos de los SUH no requieren atención urgente. La inadecuación de las visitas se asocia a características del paciente y el proceso asistido.SummaryBackgroundSeveral studies have shown a growth in the number of visits to accident and emergency (A&E) hospital departments with a high proportion of inappropriate utilization. Methods to identify improper use based on implicit criteria limit the comparisons between hospitals. The aim of this study is to know the proportion of inappropriate attendance's in an A&E department and their associated factors, using a method with objective criteria.MethodsAn instrument based on diagnosis-independent explicit criteria was used to identify inappropriate visits in a random sample of 1845 14-year-old greater patients attended to A&E medical services, and the factors associated with improper demand were analysed.ResultsThe proportion of inappropriate attendance's was of the 26,8% (495/1.845). The unadjusted analysis show that the smaller age, absence of comorbidity, spontaneous visit and some diagnostic groups (diseases of the skin, muscle-skeletal, mental, and bad defined symptoms) were associated to a greater proportion of improper use. Upon adjusting the variables through logistics regression, the age, associated pathology, the spontaneous attendance's and diagnostic groups, maintained the association with improper use, but other variables as woman gender, and night hours were also associated to inappropriate utilization.ConclusionsAt least the fourth part of the attendance's in the A&E medical services do not require urgent attention. Inappropriate utilization is associated to characteristic of the patient and the attended process

Zeolite mineralogy of the Cayo formation in Guayaquil, Ecuador

This work shows the presence of zeolites in the Cretaceous Cayo formation in Coastal Ecuador. In the area of Guayaquil the Cayo formation consist of marine pyroclastic flow deposits, associated fallout tuffs and epiclastic rocks. The main zeolites are Ca-heulandite (mean Si/Al: 3.30) and Ca-clinoptilolite (mean Si/Al: 4.35). Less common are laumontite, mordenite and analcime. Zeolites compose 10–60% of the rocks. The deposit is of great importance for Ecuador, considering its enormous zeolitised outcrop area (more than 10,000 km2