New mechanism for impurity-induced step bunching

Codeposition of impurities during the growth of a vicinal surface leads to an impurity concentration gradient on the terraces, which induces corresponding gradients in the mobility and the chemical potential of the adatoms. Here it is shown that the two types of gradients have opposing effects on the stability of the surface: Step bunching can be caused by impurities which either lower the adatom mobility, or increase the adatom chemical potential. In particular, impurities acting as random barriers (without affecting the adatom binding) cause step bunching, while for impurities acting as random traps the combination of the two effects reduces to a modification of the attachment boundary conditions at the steps. In this case attachment to descending steps, and thus step bunching, is favored if the impurities bind adatoms more weakly than the substrate.Comment: 7 pages, 3 figures. Substantial revisions and correction

Histogram comparison as a powerful tool for the search of new physics at LHC. Application to CMSSM

We propose a rigorous and effective way to compare experimental and theoretical histograms, incorporating the different sources of statistical and systematic uncertainties. This is a useful tool to extract as much information as possible from the comparison between experimental data with theoretical simulations, optimizing the chances of identifying New Physics at the LHC. We illustrate this by showing how a search in the CMSSM parameter space, using Bayesian techniques, can effectively find the correct values of the CMSSM parameters by comparing histograms of events with multijets + missing transverse momentum displayed in the effective-mass variable. The procedure is in fact very efficient to identify the true supersymmetric model, in the case supersymmetry is really there and accessible to the LHC

Collapse of the Gd3+Gd^{3+} ESR fine structure throughout the coherent temperature of the Gd-doped Kondo Semiconductor CeFe4P12CeFe_{4}P_{12}

Experiments on the $Gd^{3+}$ Electron Spin Resonance (ESR) in the filled skutterudite $Ce_{1-x}Gd_{x}Fe_{4}P_{12}$ ($x \approx 0.001$), at temperatures where the host resistivity manifests a smooth insulator-metal crossover, provides evidence of the underlying Kondo physics associated with this system. At low temperatures (below $T \approx K$), $Ce_{1-x}Gd_{x}Fe_{4}P_{12}$ behaves as a Kondo-insulator with a relatively large hybridization gap, and the $Gd^{3+}$ ESR spectra displays a fine structure with lorentzian line shape, typical of insulating media. The electronic gap is attributed to the large hybridization present in the coherent regime of a Kondo lattice, when Ce 4f-electrons cooperate with band properties at half-filling. Mean-field calculations suggest that the electron-phonon interaction is fundamental at explaining the strong 4f-electron hybridization in this filled skutterudite. The resulting electronic structure is strongly temperature dependent, and at about $T^{*} \approx 160 K$ the system undergoes an insulator-to-metal transition induced by the withdrawal of 4f-electrons from the Fermi volume, the system becoming metallic and non-magnetic. The $Gd^{3+}$ ESR fine structure coalesces into a single dysonian resonance, as in metals. Still, our simulations suggest that exchange-narrowing via the usual Korringa mechanism, alone, is not capable of describing the thermal behavior of the ESR spectra in the entire temperature region ($4.2$ - $300$ K). We propose that temperature activated fluctuating-valence of the Ce ions is the missing ingredient that, added to the usual exchange-narrowing mechanism, fully describes this unique temperature dependence of the $Gd^{3+}$ ESR fine structure observed in $Ce_{1-x}Gd_{x}Fe_{4}P_{12}$.Comment: 19 pages, 6 figure

The role of consumption in material reduction opportunities: the impact of product lifetime in supplying the UK steel demand

Most of the products purchased in the UK are manufactured in other countries. As a result, worldwide greenhouse gases (GHG) emissions released to manufacture all products purchased in the UK are significantly higher than the UK territorial emissions. More than one half of global industrial emissions result from the use of steel, cement, paper, plastics, and aluminium. In this paper, the UK consumption of products that embody these five materials is estimated. For steel, which is the most widely used among these five materials, consumption and accumulation patterns are examined across four product categories. The impact of steel product lifetime extension is examined for the UK as one option for material demand reduction at the consumption stage of the supply chain. Different levels of steel product lifetimes are simulated for the UK in 2050 and their impacts are examined in terms of UK steel production, implicit steel imports, and global carbon dioxide emissions. Steel product lifetime extension promotes a reduction in the need for steel imports, by reducing the demand for new steel, which leads to lower carbon dioxide emissions required to supply the UK steel demand. The results demonstrate the criticality of a focus on the consumption stage, since any interventions made towards demand reduction of end-use goods leads to material reduction across the supply chain

Cage-size control of guest vibration and thermal conductivity in Sr8Ga16Si30-xGex

We present a systematic study of thermal conductivity, specific heat, electrical resistivity, thermopower and x-ray diffraction measurements performed on single-crystalline samples of the pseudoquaternary type-I clathrate system Sr8Ga16Si30-xGex, in the full range of 0 < x < 30. All the samples show metallic behavior with n-type majority carriers. However, the thermal conductivity and specific heat strongly depend on x. Upon increasing x from 0 to 30, the lattice parameter increases by 3%, from 10.446 to 10.726 A, and the localized vibrational energies of the Sr guest ions in the tetrakaidekahedron (dodecahedron) cages decrease from 59 (120) K to 35 (90) K. Furthermore, the lattice thermal conductivity at low temperatures is largely suppressed. In fact, a crystalline peak found at 15 K for x = 0 gradually decreases and disappears for x > 20, evolving into the anomalous glass-like behavior observed for x = 30. It is found that the increase of the free space for the Sr guest motion directly correlates with a continuous transition from on-center harmonic vibration to off-center anharmonic vibration, with consequent increase in the coupling strength between the guest's low-energy modes and the cage's acoustic phonon modes.Comment: 7 pages, 7 figures, submitted to PR