From vortex molecules to the Abrikosov lattice in thin mesoscopic superconducting disks

Stable vortex states are studied in large superconducting thin disks (for numerical purposes we considered with radius R = 50 \xi). Configurations containing more than 700 vortices were obtained using two different approaches: the nonlinear Ginzburg-Landau (GL) theory and the London approximation. To obtain better agreement with results from the GL theory we generalized the London theory by including the spatial variation of the order parameter following Clem's ansatz. We find that configurations calculated in the London limit are also stable within the Ginzburg-Landau theory for up to ~ 230 vortices. For large values of the vorticity (typically, L > 100), the vortices are arranged in an Abrikosov lattice in the center of the disk, which is surrounded by at least two circular shells of vortices. A Voronoi construction is used to identify the defects present in the ground state vortex configurations. Such defects cluster near the edge of the disk, but for large L also grain boundaries are found which extend up to the center of the disk.Comment: 15 pages, 10 figures, RevTex4, submitted to Phys. Rev.

Duration of Low Wage Employment: A Study Based on a Survival Model

This paper includes a survival analysis which attempts to explain the duration, as in the number of years a worker remains in a low wage situation. Explanatory variables take into account the characteristics of the employee, such as education, age, tenure with the company, gender and nationality, and the characteristics of the job and the company such as industry affiliation, number of employees, age of the company and location.low wage, survival, Portugal

Informal learning at school. Science fairs in basic schools

The communication herein reports on the second edition of the annual Science Fair at Externato Maria Auxiliadora, in Viana do Castelo, Portugal. It was intended to give continuity to the research project on science fairs of the previous year improving, based on past conclusions, some aspects: the age group of the participants was enlarged to ages 10 to 15, and there was a major effort to engage parents and the whole school community in the process and in the development/construction of the projects to the science fair. Besides that, to the teachers involved in the project, was assigned an increased set of weekly hours to give support to the works realization. The participation of the students was not obligatory and it had no weight in the student’s formal evaluation. The results suggested that the whole school benefited from the enlargement of the age group of the participants in the event, and that the projects made by the younger students were particularly interesting. We concluded again that the Science Fair contributed effectively to an increase of the student’s interest on scientific subjects

Assessment of CO2 emissions during acidification, storage and after incorporation to soil of pig slurry

RAMIRAN International ConferenceLarge amounts of pig slurry are produced each year in Portugal leading to environmental problems such as water and air pollution. Previous studies have reported that livestock production is the main source of anthropogenic ammonia (NH3) emissions in Europe (Kai et al., 2008) and an important source of greenhouse gases (Weiske and Petersen, 2006). Effluent treatment has been promoted to improve slurry management and to reduce its environmental impact (Sommer and Hutchings, 2001, Fangueiro et al., 2008a). Solid-liquid separation of slurry is a useful tool at the farm level producing valuable fractions, a liquid that can be used for direct fertilisation and a solid fraction that can be composted (Fangueiro et al., 2008b). Alternatively, acidification of slurry has been proposed to reduce ammonia (NH3) emissions during storage and field application (Kai et al., 2008). Previous works (Misselbrook et al., 2005; Fangueiro et al., 2008a) reported that higher NH3 emissions occurred during storage of liquid fraction of slurry or manure with low dry matter content, probably due to a reduced crust formation that decreases NH3 emissions. Hence, acidification of the liquid fraction of slurry is strongly recommended. Slurry acidification is common practice in The Netherlands and Denmark (Schils et al., 1999; Eriksen et al., 2008) but this technology still needs to be improved to avoid hazards. It is expected that this technology will be used in more countries since the European Directive (2001/81/CE) demands a decrease of atmospheric pollutants such as NH3: targets for lower NH3 emissions have been already set in Spain (Castrillon et al., 2009). Nevertheless, the acidification process leads to significant carbon dioxide (CO2) emissions (Vandré and Clemens, 1997). Such CO2 release is problematic when a closed system of slurry acidification is used (when acidified slurry is flushed back to pig houses) since it may lead to foam formation (Vandré and Clemens, 1997; Borst, 2001). Nevertheless, Fangueiro et al. (2010) reported that acidification of slurry or derived fractions led to a decrease in CO2 emissions following soil addition relative to non acidified materials. The aim of the present work was to measure the CO2 emissions during the acidification process of the liquid fraction of pig slurry and its subsequent impact during storage and after soil incorporation

Determinação do nivel de resistência de campo de acessos de alface e avaliação da resistência de acessos de alface (Lactuca sativa) ao groundnut ringspot virus (GRSV) em condições de casa de vegetação.

Com o objetivo de avaliar a resistência de campo de genótipos de alface do Banco de Germoplasma da Embrapa montou-se um ensaio com 30 genótipos em três repetições de 12 plantas por parcela.Resumo 9

Nanogravimetric study of lead underpotential deposition on selenium thin films as a semiconductor alloy formation procedure

An electrochemical quartz crystal microbalance Au electrode modified with a Se thin film was used to investigate the electrochemical behavior of lead ad-atoms using underpotential deposition (UPD) conditions. A specific quasi-reversible process was observed during the reduction of Pb2+ on Se thin films in perchloric acid media. The charge density of Pb ad-atoms on Se thin film (46.86 mu C cm(-2)) suggests a recovery of 0.1 monolayers, which is in good agreement with EQCM data. The Se thin film can be successfully alloyed with Pb atoms that are deposited by chronoamperometry using time intervals large enough to allow for diffusion toward the inner Se phase. Linear sweep voltammetry combined with EQCM in perchloric acid was used to characterize the amount of Pb absorbed in the Se thin film. These findings offer a new strategy for alloy formation in semiconductor films using UPD as an effective tool to quantify the exact amount of the incorporated metal2624982503CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQFUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESPsem informação04/09906-

Estuarine production of resident and nursery fish species: Conditioning by drought events?

The production of resident (Pomatoschistus minutus and Pomatoschistus microps) and marine juvenile fish species using the Mondego estuary (central Portugal) as nursery grounds (Dicentrarchus labrax, Platichthys flesus, Solea solea), was assessed in order to: (1) understand the potential of the estuary for fish production; (2) know the production of nursery fish species likely to be exported to the coastal stocks; and (3) how anthropogenic and natural stress could influence the estimated production. Sampling occurred from June 2003 to May 2006 and together the 5 species in study comprised around 70% of the whole fish community numbers and biomass. Increasing drought conditions were observed, starting with a normal hydrological year in 2003 until attaining a severe drought in 2005, which resulted in low river discharges (1/3 of the mean river discharges in 2003). Additionally, high water temperatures were observed in 2003 and 2005 (24 and 26 °C, night temperatures). The secondary production was estimated using the increment summation method, after recognition of the cohorts. Production was in general lower in the Mondego estuary when compared to other systems, which was associated to the estuary's small area (only 3.4 km2, less than 1/4 of area compared to other studied systems). Dicentrarchus labrax was among the most productive species. Production decreased in the drought year for all species, especially evident for D. labrax, P. minutus and P. flesus. No direct effects could be attributable to the salinity and temperature variations and to the low freshwater discharges (resulting from the drought and high temperatures), yet these were pointed as probable major reasons for the decreased production. A significant reduction (15-45% reduction in the estuarine production) was also concluded for the potential production to be exported for coastal areas by the nursery species in the drought conditions.http://www.sciencedirect.com/science/article/B6WDV-4R9GGXS-2/1/663d5981f8928a75fea6999bf328f16

Backside-surface imprinting as a new strategy to generate specific plastic antibody materials

A backside protein-surface imprinting process is presented herein as a novel way to generate specific synthetic antibody materials. The template is covalently bonded to a carboxylated-PVC supporting film previously cast on gold, let to interact with charged monomers and surrounded next by another thick polymer. This polymer is then covalently attached to a transducing element and the backside of this structure (supporting film plus template) is removed as a regular “tape”. The new sensing layer is exposed after the full template removal, showing a high density of re-binding positions, as evidenced by SEM. To ensure that the templates have been efficiently removed, this re-binding layer was cleaned further with a proteolytic enzyme and solution washout. The final material was named MAPS, as in the back-side reading of SPAM, because it acts as a back-side imprinting of this recent approach. It was able to generate, for the first time, a specific response to a complex biomolecule from a synthetic material. Non-imprinted materials (NIMs) were also produced as blank and were used as a control of the imprinting process. All chemical modifications were followed by electrochemical techniques. This was done on a supporting film and transducing element of both MAPS and NIM. Only the MAPS-based device responded to oxLDL and the sensing layer was insensitive to other serum proteins, such as myoglobin and haemoglobin. Linear behaviour between log(C, μg mL−1) versus charged tranfer resistance (RCT, Ω) was observed by electrochemical impedance spectroscopy (EIS). Calibrations made in Fetal Calf Serum (FCS) were linear from 2.5 to 12.5 μg mL−1 (RCT = 946.12 × log C + 1590.7) with an R-squared of 0.9966. Overall, these were promising results towards the design of materials acting close to the natural antibodies and applied to practical use of clinical interest

As razões de flexibilização dos efeitos da decisão de Inconstitucionalalidade.

Trata do estudo da questão da decisão de inconstitucionalidade e sua eficácia no tempo proferida pelo Supremo Tribunal Federal no exercício do controle de constitucionalidade abstrato. Inicia, no Capítulo 1, uma abordagem acerca do Constitucionalismo e da Constituição, destacando, dentre suas características, a imortalidade normativa e a indisponibilidade política. Após, no Capítulo 2, introduz considerações acerca da jurisdição constitucional e alguns modelos de controle de constitucionalidade no Direito estrangeiro. Expõe toda a evolução da jurisdição constitucional e, mormente do controle de constitucionalidade no Brasil, desde a Constituição do Império até a do final do período militar. Faz uma explanação do atual modelo na Constituição da República de 1988. No Capítulo 3, aborda algumas peculiaridades do processo constitucional, suas partes, ferramentas e premissas, os efeitos da decisão de inconstitucionalidade e, principalmente, a sua eficácia temporal e o desenvolvimento no Direito estrangeiro de técnicas de decisão da inconstitucionalidade e suas justificativas. Pontua, no Capítulo 4, a função do Supremo Tribunal Federal como guardião maior da Constituição, faz uma retrospecto da jurisprudência e da doutrina acerca dos efeitos temporais da decisão de inconstitucionalidade no controle abstrato, sob a vigência da Lei nº. 9.868/99 e fixa as razões de flexibilização e variabilidade da eficácia temporal da decisão de inconstitucionalidade no sistema jurídico nacional. Diversos métodos foram utilizados para o desenvolvimento deste trabalho. São eles: o histórico, o jurídico-comparado, o dogmático e o argumentativo. Conclui que a nulidade da lei inconstitucional é princípio constitucional, mas pode ser afastada quando em confronto com outro valor constitucional superior. Palavras-chave: Constituição. Jurisdição Constitucional. Processo constitucional. Controle de constitucionalidade; Inconstitucionalidade. Efeito prospectivo