536 research outputs found
Generalization of Linearized Gouy-Chapman-Stern Model of Electric Double Layer for Nanostructured and Porous Electrodes: Deterministic and Stochastic Morphology
We generalize linearized Gouy-Chapman-Stern theory of electric double layer
for nanostructured and morphologically disordered electrodes. Equation for
capacitance is obtained using linear Gouy-Chapman (GC) or
Debye-ckel equation for potential near complex
electrode/electrolyte interface. The effect of surface morphology of an
electrode on electric double layer (EDL) is obtained using "multiple scattering
formalism" in surface curvature. The result for capacitance is expressed in
terms of the ratio of Gouy screening length and the local principal radii of
curvature of surface. We also include a contribution of compact layer, which is
significant in overall prediction of capacitance. Our general results are
analyzed in details for two special morphologies of electrodes, i.e.
"nanoporous membrane" and "forest of nanopillars". Variations of local shapes
and global size variations due to residual randomness in morphology are
accounted as curvature fluctuations over a reference shape element.
Particularly, the theory shows that the presence of geometrical fluctuations in
porous systems causes enhanced dependence of capacitance on mean pore sizes and
suppresses the magnitude of capacitance. Theory emphasizes a strong influence
of overall morphology and its disorder on capacitance. Finally, our predictions
are in reasonable agreement with recent experimental measurements on
supercapacitive mesoporous systems
Vesicles in solutions of hard rods
The surface free energy of ideal hard rods near curved hard surfaces is
determined to second order in curvature for surfaces of general shape. In
accordance with previous results for spherical and cylindrical surfaces it is
found that this quantity is non-analytical when one of the principal curvatures
changes signs. This prohibits writing it in the common Helfrich form. It is
shown that the non-analytical terms are the same for any aspect ratio of the
rods. These results are used to find the equilibrium shape of vesicles immersed
in solutions of rod-like (colloidal) particles. The presence of the particles
induces a change in the equilibrium shape and to a shift of the prolate-oblate
transition in the vesicle phase diagram, which are calculated within the
framework of the spontaneous curvature model. As a consequence of the special
form of the energy contribution due to the rods these changes cannot be
accounted for by a simple rescaling of the elastic constants of the vesicle as
for solutions of spherical colloids or polymers.Comment: 11 pages, 7 figures, submitted to Phys. Rev.
Bioprospecção de bactérias com potencial antagônico a fusarium spp. associado à morte de brachiaria brizantha
Há uma crescente busca nos últimos tempos por sistemas agropecuários que sejam produtivos, econômicos e sustentáveis. A síndrome da morte do capim Marandu (Brachiaria brizantha cv. Marandu) é um problema que vem crescendo nos últimos anos, um dos principais sinais de baixa sustentabilidade da pecuária brasileira. A morte das plantas forrageiras ocorre na época chuvosa, geralmente em solos mal drenados, devido a falta de adaptação da planta à baixa oxigenação das raízes, deixando-a suscetível ao ataque de fitopatógenos oportunistas. Diante da problemática, objetivou-se isolar e selecionar bactérias com potencial antagônico a Fusarium spp., um dos agentes fitopatogênicos que participam desse processo. Foram avaliados 10 sistemas, no período de chuva e seca: 1-F: floresta; 2-L: lavoura; 3-P: pecuária; 4-iPL: integração pecuária-lavoura; 5-iLP: integração lavoura-pecuária; 6-iLF: integração lavoura-floresta; 7-iPF: integração pecuária-floresta; 8-iLPF: lavoura e floresta por 2 anos e após pecuária e floresta por 2 anos; 9iLPF: pecuária e floresta por 2 anos e lavoura e floresta por 2 anos; 10-iLPF: integração lavoura-pecuária-floresta; além da mata nativa e área de pousio, distribuídos em blocos casualizados com 4 repetições. Os isolados bacterianos foram obtidos de amostras de solo diluídas, aplicadas em meio de cultura TSA 10% (Triptona soja ágar) e incubadas a 28ºC. Após a purificação os isolados foram armazenados em solução de glicerol 20% a -80°C. Foram testadas 20 bactérias em cada sistema. O método para avaliação de antagonismo foi o de cultura pareada em placa de Petri, por confronto direto, e em meio sólido BDA (Batata dextrose ágar). Na avaliação, foi considerado como positivo as bactérias que formaram halo de inibição ou quando o crescimento do corpo fúngico não encostou na bactéria. Dois isolados foram testados, Fusarium spp. isolado de planta de soja acometida (1) e Fusarium spp. isolado de solo onde ocorreu a morte da forrageira (2). Primeiramente, todos os isolados bacterianos foram testados contra o patógeno 1 e então, somente as bactérias antagônicas foram testadas contra o patógeno 2. Para o patógeno 1, na época da chuva, 7,5% dos isolados testados apresentaram antagonismo enquanto na seca esse valor foi maior (15%). Para o patógeno 2, nem todos os isolados positivos para o patógeno 1 foram eficientes no controle, demonstrando a ocorrência de interações entre isolados bacterianos e Fusarium spp. Quando considerados os sistemas, na chuva, para o patógeno 1, a mata apresentou maior número de isolados positivos (20%). Na seca, mata, 1-F e 8-iLPF para o patógeno 1, foram os que apresentaram maior número de positivos (25%). Dentre as épocas avaliadas, a seca teve mais bactérias antagonistas, e o tratamento 8-iLPF apresentou melhores resultados. O que demonstra possibilidade de encontrar um controlador biológico à Fusarium spp. neste sistema. Os sistemas mais biodiversos parecem favorecer o equilíbrio entre os microrganismos (antagonismo), o que pode reduzir ação do Fusarium spp. no capim Marandu. Isso deve ser evidenciado em análises posteriores com testes in vivo, a fim de comprovar e desenvolver novas biotecnologias. Palavras-chave: controle biológico, forragem, microbiologia
Geometric Mechanics of Curved Crease Origami
Folding a sheet of paper along a curve can lead to structures seen in
decorative art and utilitarian packing boxes. Here we present a theory for the
simplest such structure: an annular circular strip that is folded along a
central circular curve to form a three-dimensional buckled structure driven by
geometrical frustration. We quantify this shape in terms of the radius of the
circle, the dihedral angle of the fold and the mechanical properties of the
sheet of paper and the fold itself. When the sheet is isometrically deformed
everywhere except along the fold itself, stiff folds result in creases with
constant curvature and oscillatory torsion. However, relatively softer folds
inherit the broken symmetry of the buckled shape with oscillatory curvature and
torsion. Our asymptotic analysis of the isometrically deformed state is
corroborated by numerical simulations which allow us to generalize our analysis
to study multiply folded structures
How to determine local elastic properties of lipid bilayer membranes from atomic-force-microscope measurements: A theoretical analysis
Measurements with an atomic force microscope (AFM) offer a direct way to
probe elastic properties of lipid bilayer membranes locally: provided the
underlying stress-strain relation is known, material parameters such as surface
tension or bending rigidity may be deduced. In a recent experiment a
pore-spanning membrane was poked with an AFM tip, yielding a linear behavior of
the force-indentation curves. A theoretical model for this case is presented
here which describes these curves in the framework of Helfrich theory. The
linear behavior of the measurements is reproduced if one neglects the influence
of adhesion between tip and membrane. Including it via an adhesion balance
changes the situation significantly: force-distance curves cease to be linear,
hysteresis and nonzero detachment forces can show up. The characteristics of
this rich scenario are discussed in detail in this article.Comment: 14 pages, 9 figures, REVTeX4 style. New version corresponds to the
one accepted by PRE. The result section is restructured: a comparison to
experimental findings is included; the discussion on the influence of
adhesion between AFM tip and membrane is extende
Planar sheets meet negative curvature liquid interfaces
If an inextensible thin sheet is adhered to a substrate with a negative
Gaussian curvature it will experience stress due to geometric frustration. We
analyze the consequences of such geometric frustration using analytic arguments
and numerical simulations. Both concentric wrinkles and eye-like folds are
shown to be compatible with negative curvatures. Which pattern will be realized
depends on the curvature of the substrate. We discuss both types of folding
patterns and determine the phase diagram governing their appearance.Comment: 5 pages, 4 figure
Expressão do gene PTHLH em frangos de corte normais e afetados pela necrose da cabeça do fêmur.
Seleção de genes constitutivos para estudos de expressão gênica em ossos de frangos de corte aos 35 dias de idade.
The Serret-Andoyer Riemannian metric and Euler-Poinsot rigid body motion
The Euler-Poinsot rigid body motion is a standard mechanical system and is the model for left-invariant Riemannian metrics on SO(3). In this article, using the Serret-Andoyer variables we parameterize the solutions and compute the Jacobi fields in relation with the conjugate locus evaluation. Moreover the metric can be restricted to a 2D surface and the conjugate points of this metric are evaluated using recent work [4] on surfaces of revolution
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