If only it were true: the problem with the four conditionals

The traditional division of conditionals into four main types (zero, first, second, and third) has long been called into question. Unfortunately, the awareness that this description does not reflect conditional patterns in actual usage has not generally been reflected in EFL coursebooks. This article re-examines the arguments for a description of conditional patterns which reflects actual usage and uses corpus data to demonstrate the kind of patterns in frequent use. It then suggests two teaching approaches that may help teachers to tackle a variety of conditional patterns in the classroom

Entrepreneurship through Bricolage. A Study of Displaced Entrepreneurs at Times of War and Conflict

War and conflict brings about adverse changes for those who are displaced. How do entrepreneurial individuals respond to such adversity to either set-up, or continue with their existing entrepreneurial endeavours that would improve their own livelihood or that of others who have been affected? Whilst previous studies have found local knowledge, networks and resources to be crucial in the development of ventures in the war and conflict context, alienation from mainstream society within the host location often means that to succeed, those who are displaced require alternative strategies and approaches. Through examining the entrepreneurship ventures of six internally displaced entrepreneurs in Pakistan, our study identifies that entrepreneurial individuals find different ways to adapt to the new order, with both internal and external bricolage becoming the key strategies deployed to either re-establish their previous business(es) or to develop new endeavour(s) in the host location. To compensate for lack of local knowledge, networks and resources, we found that entrepreneurs followed closely their previous paths in their bricolage attempts, relying on reconfigurations of their pre-existing competencies, as well as utilising pre-established and clandestine networks

Iron(III)-catalyzed chlorination of activated arenes

A general and regioselective method for the chlorination of activated arenes has been developed. The transformation uses iron(III) triflimide as a powerful Lewis acid for the activation of N-chlorosuccinimide and the subsequent chlorination of a wide range of anisole, aniline, acetanilide and phenol derivatives. The reaction was utilized for the late-stage mono- and di-chlorination of a range of target compounds such as the natural product nitrofungin, the antibacterial agent chloroxylenol and the herbicide chloroxynil. The facile nature of this transformation was demonstrated with the development of one-pot tandem iron-catalyzed dihalogenation processes allowing highly regioselective formation of different carbon-halogen bonds. The synthetic utility of the resulting dihalogenated aryl compounds as building blocks was established with the synthesis of natural products and pharmaceutically relevant targets

Multiscale Representations for Manifold-Valued Data

We describe multiscale representations for data observed on equispaced grids and taking values in manifolds such as the sphere $S^2$, the special orthogonal group $SO(3)$, the positive definite matrices $SPD(n)$, and the Grassmann manifolds $G(n,k)$. The representations are based on the deployment of Deslauriers--Dubuc and average-interpolating pyramids "in the tangent plane" of such manifolds, using the $Exp$ and $Log$ maps of those manifolds. The representations provide "wavelet coefficients" which can be thresholded, quantized, and scaled in much the same way as traditional wavelet coefficients. Tasks such as compression, noise removal, contrast enhancement, and stochastic simulation are facilitated by this representation. The approach applies to general manifolds but is particularly suited to the manifolds we consider, i.e., Riemannian symmetric spaces, such as $S^{n-1}$, $SO(n)$, $G(n,k)$, where the $Exp$ and $Log$ maps are effectively computable. Applications to manifold-valued data sources of a geometric nature (motion, orientation, diffusion) seem particularly immediate. A software toolbox, SymmLab, can reproduce the results discussed in this paper

Determination of gamma-ray widths in 15^{15}N using nuclear resonance fluorescence

The stable nucleus $^{15}$N is the mirror of $^{15}$O, the bottleneck in the hydrogen burning CNO cycle. Most of the $^{15}$N level widths below the proton emission threshold are known from just one nuclear resonance fluorescence (NRF) measurement, with limited precision in some cases. A recent experiment with the AGATA demonstrator array determined level lifetimes using the Doppler Shift Attenuation Method (DSAM) in $^{15}$O. As a reference and for testing the method, level lifetimes in $^{15}$N have also been determined in the same experiment. The latest compilation of $^{15}$N level properties dates back to 1991. The limited precision in some cases in the compilation calls for a new measurement in order to enable a comparison to the AGATA demonstrator data. The widths of several $^{15}$N levels have been studied with the NRF method. The solid nitrogen compounds enriched in $^{15}$N have been irradiated with bremsstrahlung. The $\gamma$-rays following the deexcitation of the excited nuclear levels were detected with four HPGe detectors. Integrated photon-scattering cross sections of ten levels below the proton emission threshold have been measured. Partial gamma-ray widths of ground-state transitions were deduced and compared to the literature. The photon scattering cross sections of two levels above the proton emission threshold, but still below other particle emission energies have also been measured, and proton resonance strengths and proton widths were deduced. Gamma and proton widths consistent with the literature values were obtained, but with greatly improved precision.Comment: Final published version, minor grammar changes, 10 pages, 4 figures, 8 tables; An addendum is published where the last section is revised: T. Sz\"ucs and P. Mohr, Phys. Rev. C 92, 044328 (2015) [arXiv:1510.04956

A comprehensive review on properties, modification and applications

Publisher Copyright: © 2023 The AuthorsThis comprehensive review explores the potential and versatility of biogenic materials as sustainable and environmentally benign alternatives to conventional adsorbents for the removal of drugs and dyes. Biogenic adsorbents derived from plants, animals, microorganisms, algae and biopolymers have bioactive compounds that interact with functional groups of pollutants, resulting in their binding with the sorbent. These materials can be modified mechanically, thermally and chemically to enhance their adsorption properties. Biogenic hybrid composites, which integrate the characteristics of more than one material, have also been fabricated. Additionally, microorganisms and algae are analyzed for their ability to uptake pollutants. Various influential factors that contribute to the adsorption process are also discussed. The challenge, limitations and future prospects for research are reviewed and bridging gap between large scale application and laboratory scale. This comprehensive review, involves a combination of various biogenic adsorbents, going beyond the existing literature where typically only specific adsorbents are reported. The review also covers the isotherms, kinetics, and desorption studies of biogenic adsorbents, providing an improved framework for their effective use in removing pharmaceuticals and dyes from wastewater.publishersversionpublishe

A Hybrid Modified Ant Colony Optimization - Particle Swarm Optimization Algorithm for Optimal Node Positioning and Routing in Wireless Sensor Networks

Wireless Sensor Networks (WSNs) have been widely deployed in hostile locations for environmental monitoring. Sensor placement and energy management are the two main factors that should be focused due to certain limitations in WSNs. The nodes in a sensor network might not stay charged when energy draining takes place; therefore, increasing the operational lifespan of the network is the primary purpose of energy management. Recently, major research interest in WSN has been focused with the essential aspect of localization. Several types of research have also taken place on the challenges of node localization of wireless sensor networks with the inclusion of range-free and range-based localization algorithms. In this work, the optimal positions of Sensor Nodes (SNs) are determined by proposing a novel Hybrid M-ACO – PSO (HMAP) algorithm. In the HMAP method, the improved PSO utilizes learning strategies for estimating the relay nodes\u27 optimal positions. The M-ACO assures the data conveyance. A route discovers when it relates to the ideal route irrespective of the possibility of a system that includes the nodes with various transmission ranges, and the network lifetime improves. The proposed strategy is executed based on the energy, throughput, delivery ratio, overhead, and delay of the information packets

A conserved filamentous assembly underlies the structure of the meiotic chromosome axis.

The meiotic chromosome axis plays key roles in meiotic chromosome organization and recombination, yet the underlying protein components of this structure are highly diverged. Here, we show that 'axis core proteins' from budding yeast (Red1), mammals (SYCP2/SYCP3), and plants (ASY3/ASY4) are evolutionarily related and play equivalent roles in chromosome axis assembly. We first identify 'closure motifs' in each complex that recruit meiotic HORMADs, the master regulators of meiotic recombination. We next find that axis core proteins form homotetrameric (Red1) or heterotetrameric (SYCP2:SYCP3 and ASY3:ASY4) coiled-coil assemblies that further oligomerize into micron-length filaments. Thus, the meiotic chromosome axis core in fungi, mammals, and plants shares a common molecular architecture, and likely also plays conserved roles in meiotic chromosome axis assembly and recombination control