Simultaneous Determination of the Cosmic Ray Ionization Rate and Fractional Ionization in DR21(OH)

We present a new method for the simultaneous calculation of the cosmic ray ionization rate, zeta(H2), and the ionization fraction, chi(e), in dense molecular clouds. A simple network of chemical reactions dominant in the creation and destruction of HCNH+ and HCO+ is used in conjunction with observed pairs of rotational transitions of several molecular species in order to determine the electron abundance and the H3+ abundance. The cosmic ray ionization rate is then calculated by taking advantage of the fact that, in dark clouds, it governs the rate of creation of H3+. We apply this technique to the case of the star-forming region DR21(OH), where we successfully detected the (J=3-2) and (J=4-3) rotational transitions of HCNH+. We also determine the C and O isotopic ratios in this source to be 12C/13C=63+-4 and 16O/18O=318+-64, which are in good agreement with previous measurements in other clouds. The significance of our method lies in the ability to determine N(H3+) and chi(e) directly from observations, and estimate zeta(H2) accordingly. Our results, zeta(H2)=3.1x10^(-18) 1/s and chi(e)=3.2x10^(-8), are consistent with recent determinations in other objects.Comment: 22 pages, including 3 figure

The origin of organic emission in NGC 2071

Context: The physical origin behind organic emission in embedded low-mass star formation has been fiercely debated in the last two decades. A multitude of scenarios have been proposed, from a hot corino to PDRs on cavity walls to shock excitation. Aims: The aim of this paper is to determine the location and the corresponding physical conditions of the gas responsible for organics emission lines. The outflows around the small protocluster NGC 2071 are an ideal testbed to differentiate between various scenarios. Methods: Using Herschel-HIFI and the SMA, observations of CH3OH, H2CO and CH3CN emission lines over a wide range of excitation energies were obtained. Comparisons to a grid of radiative transfer models provide constraints on the physical conditions. Comparison to H2O line shape is able to trace gas-phase synthesis versus a sputtered origin. Results: Emission of organics originates in three spots: the continuum sources IRS 1 ('B') and IRS 3 ('A') as well as a outflow position ('F'). Densities are above 10$^7$ cm$^{-3}$ and temperatures between 100 to 200 K. CH3OH emission observed with HIFI originates in all three regions and cannot be associated with a single region. Very little organic emission originates outside of these regions. Conclusions: Although the three regions are small (<1,500 AU), gas-phase organics likely originate from sputtering of ices due to outflow activity. The derived high densities (>10$^7$ cm$^{-3}$) are likely a requirement for organic molecules to survive from being destroyed by shock products. The lack of spatially extended emission confirms that organic molecules cannot (re)form through gas-phase synthesis, as opposed to H2O, which shows strong line wing emission. The lack of CH3CN emission at 'F' is evidence for a different history of ice processing due to the absence of a protostar at that location and recent ice mantle evaporation.Comment: 10 Pages, 8 figures, Accepted for Astronomy and Astrophysic

Polarisation Observations of H2_{2}O JK−1K1=532−441J_{K_{-1}K_{1}} = 5_{32} - 4_{41} 620.701 GHz Maser Emission with Herschel/HIFI in Orion KL

Context. The high intensities and narrow bandwidths exhibited by some astronomical masers make them ideal tools for studying star-forming giant molecular clouds. The water maser transition $J_{K_{-1}K_{1}}=5_{32}-4_{41}$ at 620.701 GHz can only be observed from above Earth's strongly absorbing atmosphere; its emission has recently been detected from space. Aims. We sought to further characterize the star-forming environment of Orion KL by investigating the linear polarisation of a source emitting a narrow 620.701 GHz maser feature with the heterodyne spectrometer HIFI on board the Herschel Space Observatory. Methods. High-resolution spectral datasets were collected over a thirteen month period beginning in 2011 March, to establish not only the linear polarisation but also the temporal variability of the source. Results. Within a $3\sigma$ uncertainty, no polarisation was detected to an upper limit of approximately 2%. These results are compared with coeval linear polarisation measurements of the 22.235 GHz $J_{K_{-1}K_{1}}=6_{16}-5_{23}$ maser line from the Effelsberg 100-m radio telescope, typically a much stronger maser transition. Although strongly polarised emission is observed for one component of the 22.235 GHz maser at 7.2 km s$^{-1}$, a weaker component at the same velocity as the 620.701 GHz maser at 11.7 km s$^{-1}$ is much less polarised.Comment: Accepted for publication in A&

The hot core towards the intermediate mass protostar NGC7129 FIRS 2: Chemical similarities with Orion KL

NGC 7129 FIRS 2 (hereafter FIRS 2) is an intermediate-mass (2 to 8 Msun) protostar located at a distance of 1250 pc. High spatial resolution observations are required to resolve the hot core at its center. We present a molecular survey from 218200 MHz to 221800 MHz carried out with the IRAM Plateau de Bure Interferometer. These observations were complemented with a long integration single-dish spectrum taken with the IRAM 30m telescope. We used a Local Thermodynamic Equilibrium (LTE) single temperature code to model the whole dataset. The interferometric spectrum is crowded with a total of ~300 lines from which a few dozens remain unidentified yet. The spectrum has been modeled with a total of 20 species and their isomers, isotopologues and deuterated compounds. Complex molecules like methyl formate (CH3OCHO), ethanol (CH3CH2OH), glycolaldehyde (CH2OHCHO), acetone (CH3COCH3), dimethyl ether (CH3OCH3), ethyl cyanide (CH3CH2CN) and the aGg' conformer of ethylene glycol (aGg'-(CH2OH)_2) are among the detected species. The detection of vibrationally excited lines of CH3CN, CH3OCHO, CH3OH, OCS, HC3N and CH3CHO proves the existence of gas and dust at high temperatures. In fact, the gas kinetic temperature estimated from the vibrational lines of CH3CN, ~405 K, is similar to that measured in massive hot cores. Our data allow an extensive comparison of the chemistry in FIRS~2 and the Orion hot core. We find a quite similar chemistry in FIRS 2 and Orion. Most of the studied fractional molecular abundances agree within a factor of 5. Larger differences are only found for the deuterated compounds D2CO and CH2DOH and a few molecules (CH3CH2CN, SO2, HNCO and CH3CHO). Since the physical conditions are similar in both hot cores, only different initial conditions (warmer pre-collapse phase in the case of Orion) and/or different crossing time of the gas in the hot core can explain this behavior.Comment: 30 pages, 9 figure

Spin properties of dense near-surface ensembles of nitrogen-vacancy centres in diamond

We present a study of the spin properties of dense layers of near-surface nitrogen-vacancy (NV) centres in diamond created by nitrogen ion implantation. The optically detected magnetic resonance contrast and linewidth, spin coherence time, and spin relaxation time, are measured as a function of implantation energy, dose, annealing temperature and surface treatment. To track the presence of damage and surface-related spin defects, we perform in situ electron spin resonance spectroscopy through both double electron-electron resonance and cross-relaxation spectroscopy on the NV centres. We find that, for the energy ($4-30$~keV) and dose ($5\times10^{11}-10^{13}$~ions/cm$^2$) ranges considered, the NV spin properties are mainly governed by the dose via residual implantation-induced paramagnetic defects, but that the resulting magnetic sensitivity is essentially independent of both dose and energy. We then show that the magnetic sensitivity is significantly improved by high-temperature annealing at $\geq1100^\circ$C. Moreover, the spin properties are not significantly affected by oxygen annealing, apart from the spin relaxation time, which is dramatically decreased. Finally, the average NV depth is determined by nuclear magnetic resonance measurements, giving $\approx10$-17~nm at 4-6 keV implantation energy. This study sheds light on the optimal conditions to create dense layers of near-surface NV centres for high-sensitivity sensing and imaging applications.Comment: 12 pages, 7 figure

OH far-infrared emission from low- and intermediate-mass protostars surveyed with Herschel-PACS

OH is a key species in the water chemistry of star-forming regions, because its presence is tightly related to the formation and destruction of water. This paper presents OH observations from 23 low- and intermediate-mass young stellar objects obtained with the PACS integral field spectrometer on-board Herschel in the context of the Water In Star-forming Regions with Herschel (WISH) key program. Most low-mass sources have compact OH emission (< 5000 AU scale), whereas the OH lines in most intermediate-mass sources are extended over the whole PACS detector field-of-view (> 20000 AU). The strength of the OH emission is correlated with various source properties such as the bolometric luminosity and the envelope mass, but also with the OI and H2O emission. Rotational diagrams for sources with many OH lines show that the level populations of OH can be approximated by a Boltzmann distribution with an excitation temperature at around 70 K. Radiative transfer models of spherically symmetric envelopes cannot reproduce the OH emission fluxes nor their broad line widths, strongly suggesting an outflow origin. Slab excitation models indicate that the observed excitation temperature can either be reached if the OH molecules are exposed to a strong far-infrared continuum radiation field or if the gas temperature and density are sufficiently high. Using realistic source parameters and radiation fields, it is shown for the case of Ser SMM1 that radiative pumping plays an important role in transitions arising from upper level energies higher than 300 K. The compact emission in the low-mass sources and the required presence of a strong radiation field and/or a high density to excite the OH molecules points towards an origin in shocks in the inner envelope close to the protostar.Comment: Accepted for publication in Astronomy and Astrophysics. Abstract abridge

Deuterated water in the solar-type protostars NGC 1333 IRAS 4A and IRAS 4B

Aims. The aim of this paper is to study deuterated water in the solar-type protostars NGC1333 IRAS4A and IRAS4B, to compare their HDO abundance distribution with other star-forming regions, and to constrain their HDO/H2O ratios. Methods. Using the Herschel/HIFI instrument as well as ground-based telescopes, we observed several HDO lines covering a large excitation range (Eup/k=22-168 K) towards these protostars and an outflow position. Non-LTE radiative transfer codes were then used to determine the HDO abundance profiles in these sources. Results. The HDO fundamental line profiles show a very broad component, tracing the molecular outflows, in addition to a narrower emission component and a narrow absorbing component. In the protostellar envelope of NGC1333 IRAS4A, the HDO inner (T>100 K) and outer (T<100 K) abundances with respect to H2 are estimated at 7.5x10^{-9} and 1.2x10^{-11}, respectively, whereas, in NGC1333 IRAS4B, they are 1.0x10^{-8} and 1.2x10^{-10}, respectively. Similarly to the low-mass protostar IRAS16293-2422, an absorbing outer layer with an enhanced abundance of deuterated water is required to reproduce the absorbing components seen in the fundamental lines at 465 and 894 GHz in both sources. This water-rich layer is probably extended enough to encompass the two sources as well as parts of the outflows. In the outflows emanating from NGC1333 IRAS4A, the HDO column density is estimated at about (2-4)x10^{13} cm^{-2}, leading to an abundance of about (0.7-1.9)x10^{-9}. An HDO/H2O ratio between 7x10^{-4} and 9x10^{-2} is derived in the outflows. In the warm inner regions of these two sources, we estimate the HDO/H2O ratios at about 1x10^{-4}-4x10^{-3}. This ratio seems higher (a few %) in the cold envelope of IRAS4A, whose possible origin is discussed in relation to formation processes of HDO and H2O.Comment: 16 pages, 13 figure

Spitzer imaging of the jet driving the NGC 2264 G outflow

We present new infrared imaging of the NGC 2264 G protostellar outflow region, obtained with the InfraRed Array Camera (IRAC) on-board the Spitzer Space Telescope. A jet in the red outflow lobe (eastern lobe) is clearly detected in all four IRAC bands and, for the first time, is shown to continuously extend over the entire length of the red outflow lobe traced by CO observations. The redshifted jet also extends to a deeply embedded Class 0 source, VLA 2, confirming previous suggestions that it is the driving source of the outflow (Gomez et al. 1994). The images show that the easternmost part of the redshifted jet exhibits what appear to be multiple changes of direction. To understand the redshifted jet morphology we explore several mechanisms that could generate such apparent changes of direction. From this analysis, we conclude that the redshifted jet structure and morphology visible in the IRAC images can be largely, although not entirely, explained by a slowly precessing jet (period ~8000 yr) that lies mostly on the plane of the sky. It appears that the observed changes in the redshifted jet direction may be sufficient to account for a significant fraction of the broadening of the outflow lobe observed in the CO emission.Comment: Accepted for publication in MNRAS. The paper has 7 pages and 4 figures. Preprint with high resolution images is available at http://www.cfa.harvard.edu/~pteixeir/publications.htm