A negative feedback between anthropogenic ozone pollution and enhanced ocean emissions of iodine

Naturally emitted from the oceans, iodine compounds efficiently destroy atmospheric ozone and reduce its positive radiative forcing effects in the troposphere. Emissions of inorganic iodine have been experimentally shown to depend on the deposition to the oceans of tropospheric ozone, whose concentrations have significantly increased since 1850 as a result of human activities. A chemistry-climate model is used herein to quantify the current ocean emissions of inorganic iodine and assess the impact that the anthropogenic increase in tropospheric ozone has had on the natural cycle of iodine in the marine environment since pre-industrial times. Our results indicate that the human-driven enhancement of tropospheric ozone has doubled the oceanic inorganic iodine emissions following the reaction of ozone with iodide at the sea surface. The consequent build-up of atmospheric iodine, with maximum enhancements of up to 70% with respect to pre-industrial times in continental pollution outflow regions, has in turn accelerated the ozone chemical loss over the oceans with strong spatial patterns. We suggest that this ocean-atmosphere interaction represents a negative geochemical feedback loop by which current ocean emissions of iodine act as a natural buffer for ozone pollution and its radiative forcing in the global marine environment.Fil: Prados Roman, C.. Consejo Superior de Investigaciones Científicas. Instituto de Química Física; EspañaFil: Cuevas, Carlos Alberto. Consejo Superior de Investigaciones Científicas. Instituto de Química Física; EspañaFil: Fernandez, Rafael Pedro. Consejo Superior de Investigaciones Científicas. Instituto de Química Física; España. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza; ArgentinaFil: Kinnison, Douglas E.. National Center For Atmospheric Research. Amospheric Chemistry División; Estados UnidosFil: Lamarque, Jean Francoise. National Center For Atmospheric Research. Amospheric Chemistry División; Estados UnidosFil: Saiz-lopez, Alfonso. Consejo Superior de Investigaciones Científicas. Instituto de Química Física; Españ

Redefining Performance Evaluation Tools for Real-Time QRS Complex Classification Systems

International audienceIn a heartbeat classification procedure, the detection of QRS complex waveforms is necessary. In many studies, this heartbeat extraction function is not considered: the inputs of the classifier are assumed to be correctly identified. This paper aims to redefine classical performance evaluation tools in entire QRS complex classification systems and to evaluate the effects induced by QRS detection errors on the performance of a heartbeat classification processing (normal vs abnormal). Performance statistics are given and discussed considering the MIT/BIH database records that are replayed on a real-time classification system imposed of the classical detector proposed by Hamilton & Tompkins, followed by a neural network classifier. This study shows that a classification accuracy of 96.72% falls to 94.90% when a drop of 1.78% error rate is introduced in the detector quality. This corresponds an increase of about 50% bad classifications

How would farmers in the French Alps adapt their systems to different drought and socio-economic context scenarios?

International audienceThe French Alps are considered as an area that is particularly vulnerable to climate change. Several droughts have already occurred since 2003. In order to assess the ability of farming systems to adapt to future drought events, we developed prospective scenarios combining different climatic and socio-economic contexts. Four scenarios were defined based on (i) prospective studies conducted at national and international levels, and (ii) a participatory approach with various stakeholders to transcribe these scenarios at a local level. Farmers and shepherds in the Vercors and Oisans massifs were surveyed in order to understand how they had reacted to previous droughts, and how they would plan to react to our scenarios. Results show first that the farmers would strive to continue their activity in each scenario, taking advantage of the flexibility of their farming systems, as in previous years. However, in the most pessimistic climatic scenario, they would also decrease the size of their herds. Depending on the socio-economic hypothesis, they would adopt farm structural changes (farm processing activities, direct selling, etc.), or look for part-time non-agricultural jobs. Three types of strategies were identified, depending on the farmers' objectives and adjustments. Finally, public policies to accompany these changes are considered

4D Visualization of the Left Ventricle, Using a Rotating Ultrasound Probe During 4 Cardiac Cycles

A new type of external ultrasound probe is proposed to visualize dynamically the left-ventricular three-dimensional deformations. This probe acquires successive apical long axis cross sections by rotating continuously around its axis (one or two rotations per cardiac cycle). From the set of one hundred images obtained during only four consecutive heart beats the volume is reconstructed. In the present development phase, segmentation is performed manually, but supervised in order to guarantee a coherent set of contours. Experimental validations on regular cardiac cycles have been made on a patient fitted with pacemaker. The results obtained are promising

Iodine chemistry in the troposphere and its effect on ozone

Despite the potential influence of iodine chemistry on the oxidizing capacity of the troposphere, reactive iodine distributions and their impact on tropospheric ozone remain almost unexplored aspects of the global atmosphere. Here we present a comprehensive global modelling experiment aimed at estimating lower and upper limits of the inorganic iodine burden and its impact on tropospheric ozone. Two sets of simulations without and with the photolysis of IxOy oxides (i.e. I2O2, I2O3 and I2O4) were conducted to define the range of inorganic iodine loading, partitioning and impact in the troposphere. Our results show that the most abundant daytime iodine species throughout the middle to upper troposphere is atomic iodine, with an annual average tropical abundance of (0.15-0.55) pptv. We propose the existence of a "tropical ring of atomic iodine" that peaks in the tropical upper troposphere (∼11-14 km) at the equator and extends to the sub-tropics (30°N-30°S). Annual average daytime I = IO ratios larger than 3 are modelled within the tropics, reaching ratios up to ∼20 during vigorous uplift events within strong convective regions. We calculate that the integrated contribution of catalytic iodine reactions to the total rate of tropospheric ozone loss (IOx Loss) is 2-5 times larger than the combined bromine and chlorine cycles. When IxOy photolysis is included, IOx Loss represents an upper limit of approximately 27, 14 and 27% of the tropical annual ozone loss for the marine boundary layer (MBL), free troposphere (FT) and upper troposphere (UT), respectively, while the lower limit throughout the tropical troposphere is ∼9 %. Our results indicate that iodine is the second strongest ozone-depleting family throughout the global marine UT and in the tropical MBL. We suggest that (i) iodine sources and its chemistry need to be included in global tropospheric chemistry models, (ii) experimental programs designed to quantify the iodine budget in the troposphere should include a strategy for the measurement of atomic I, and (iii) laboratory programs are needed to characterize the photochemistry of higher iodine oxides to determine their atmospheric fate since they can potentially dominate halogen-catalysed ozone destruction in the troposphere

How emissions, climate, and land use change will impact mid-century air quality over the United States: A focus on effects at national parks

We use a global coupled chemistry-climate-land model (CESM) to assess the integrated effect of climate, emissions and land use changes on annual surface O3 and PM2.5 in the United States with a focus on national parks (NPs) and wilderness areas, using the RCP4.5 and RCP8.5 projections. We show that, when stringent domestic emission controls are applied, air quality is predicted to improve across the US, except surface O3 over the western and central US under RCP8.5 conditions, where rising background ozone counteracts domestic emission reductions. Under the RCP4.5 scenario, surface O3 is substantially reduced (about 5 ppb), with daily maximum 8 h averages below the primary US Environmental Protection Agency (EPA) National Ambient Air Quality Standards (NAAQS) of 75 ppb (and even 65 ppb) in all the NPs. PM2.5 is significantly reduced in both scenarios (4 μg m-3; ~50%), with levels below the annual US EPA NAAQS of 12 μg m-3 across all the NPs; visibility is also improved (10-15 dv; >75 km in visibility range), although some western US parks with Class I status (40-74 % of total sites in the US) are still above the 2050 planned target level to reach the goal of natural visibility conditions by 2064. We estimate that climate-driven increases in fire activity may dominate summertime PM2.5 over the western US, potentially offsetting the large PM2.5 reductions from domestic emission controls, and keeping visibility at present-day levels in many parks. Our study indicates that anthropogenic emission patterns will be important for air quality in 2050. However, climate and land use changes alone may lead to a substantial increase in surface O3 (2-3 ppb) with important consequences for O3 air quality and ecosystem degradation at the US NPs. Our study illustrates the need to consider the effects of changes in climate, vegetation, and fires in future air quality management and planning and emission policy making

THE EFFECT OF COMBUSTION CHAMBER SHAPE AND OTHER ENGINE DESIGN FACTORS ON EXHAUST EMISSIONS

A Heron combustion chamber engine of 2 litre capacity has been utilized to investigate the effect of combustion chamber shape, increased mixture movement, valve timing, mixture formation, and reaction in the exhaust system on engine performance and level of exhaust emissions using the seven-mode U.S. Federal cycle. Such factors as carburettor weakening and limitation of intake manifold vacuum during overrun have been included in this investigation, and it has been shown that it is possible to reduce exhaust emissions and also satisfy the current U.S. requirements with an engine giving acceptable performance, improved economy, and unaffected reliability. Much of the information reported may be negative in terms of improvement to exhaust emissions by detailed engine design. Nevertheless, some positive conclusions have been reached as a result of this work, and it is hoped that this will draw forth more informed discussion than the authors have been able to assemble from the work attempted wirh one basic engine