Short-wavelength undulatory extinction in quartz recording coseismic deformation in the middle crust – an experimental study

Deformation experiments are carried out on natural vein quartz in a modified Griggs-type solid medium apparatus to explore the preservation potential of microfabrics created by crystal-plastic deformation at high stress, overprinted during subsequent creep at lower stress. A corresponding stress history is expected for the upper plastosphere, where fault slip during an earthquake causes quasi-instantaneous loading to high stress, followed by stress relaxation. The question is whether evidence of crystal-plastic deformation at high stress, hence an indicator of past seismic activity, can still be identified in the microstructure after overprint by creep at lower stresses. First, quartz samples are deformed at a temperature of 400 °C and constant strain rate of 10⁻⁴ s⁻¹ ("kick"), and then held at 900 to 1000 °C at residual stress ("creep"). In quartz exclusively subject to high-stress deformation, lamellar domains of slightly differing crystallographic orientation (misorientation angle < 2°) and a few tens of micrometres wide occur. In the transmission electron microscope (TEM), these areas show a high density of tangled dislocations and cellular structures. After "kick and creep" experiments, pronounced short-wavelength undulatory extinction (SWUE) is observed in the polarization microscope. The wavelength of SWUE is up to 10 μm, with oscillatory misorientation of up to a few degrees. TEM inspection reveals domains with high density of dislocations and differing diffraction contrast bound by poorly ordered dislocation walls. Only zones with exceptional damage generated during high-stress deformation are replaced by small new grains with a diameter of about 10 to 20 μm, forming strings of recrystallized grains. For large original grains showing SWUE, the Schmid factor for basal ⟨ <i>a</i> ⟩ glide is found to be high. SWUE is taken to reflect high-stress crystal-plastic deformation, the modified microstructure being sufficiently stable to be recognized after subsequent creep as an indicator of past seismic activity

Polycrystalline apatite synthesized by hydrothermal replacement of calcium carbonates

Aragonite and calcite single crystals can be readily transformed into polycrystalline hydroxyapatite pseudomorphs by hydrothermal treatment in a (NH4)2HPO4 solution. Scanning electron microscopy of the reaction products showed that the transformation of aragonite to apatite is characterised by the formation of a sharp interface between the two phases and by the development of intracrystalline porosity in the hydroxyapatite phase. In addition, electron backscattered diffraction (EBSD) imaging showed that the c-axis of apatite is predominantly oriented perpendicular to the reaction front with no crystallographic relationship to the aragonite lattice. However, the Ca isotopic composition of the parent aragonite, measured by thermal ionization mass spectrometry was inherited by the apatite product.Hydrothermal experiments conducted with use of phosphate solutions prepared with water enriched in 18O (97%) further revealed that the 18O from the solution is incorporated in the product apatite, as measured by micro-Raman spectroscopy. Monitoring the distribution of 18O with Raman spectroscopy was possible because the incorporation of 18O in the PO4 group of apatite generates four new Raman bands at 945.8, 932, 919.7 and 908.8cm-1, in addition to the ?1(PO4) symmetric stretching band of apatite located at 962cm-1, which can be assigned to four 18O-bearing PO4 species. The relative intensities of these bands reflect the 18O content in the PO4 group of the apatite product. By using equilibrated and non-equilibrated solutions, with respect to the 18O distribution between aqueous phosphate and water, we could show that the concentration of 18O in the apatite product is linked to the degree of 18O equilibration in the solution. The textural and chemical observations are indicative of a coupled mechanism of aragonite dissolution and apatite precipitation taking place at a moving reaction interface

Rare earth elements and Sm-Nd isotope redistribution in apatite and accessory minerals in retrogressed lower crust material (Bergen Arcs, Norway)

In the Bergen Arcs (Norway), Grenvillian granulite retrogressed under eclogite- and amphibolite-facies conditions during Caledonian subduction/collision offer a unique opportunity to investigate rare earth elements (REE) and Sm-Nd isotope redistribution in accessory minerals during fluid-assisted metamorphism. Our sampling targeted apatite-bearing REE-rich protoliths (mangerite and jotunite) that preserve distinct mineral assemblages, depending on the external fluid availability and metamorphic conditions. REE concentrations in apatite are the highest in the granulite. Two populations are present: magmatic apatite (Ap1) relics that occur as inclusions in ilmenite-hematite, and intergranular apatite (Ap2) formed under granulite-facies conditions. The presence of abundant needle-like monazite and sulphide inclusions in Ap2 indicate that granulite reactions were fluid assisted. A thin (typically < 10 μm) rim of REE-rich epidote (Ep1) commonly surrounds Ap2. In these accessory minerals, U and Th contents are too low, or grains are too small, for in situ U-Th-Pb dating. Sm-Nd isotope data of Ap2, monazite and Ep1 give an isochron age of 601 ± 69 Ma, which is interpreted to represent a partially reset Grenvillian age, affected by Caledonian fluid-assisted mineral growth. In amphibolitized samples, granulite Ap2 is replaced by apatite (Ap3) with lower REE contents and no monazite inclusions. The REE released by this replacement are redistributed in a corona of epidote group minerals (Ep2) surrounding Ap3. The in situ Sm-Nd isotope data for Ep2 and titanite, found in replacement of ilmenite-hematite, return an isochron age of 395 ± 65 Ma, recording the timing of amphibolite-facies mineral growth when fluids were introduced into the rock. In eclogitized samples, eclogitic apatite (Ap4) occurs as polycrystalline aggregates, suggesting for a complex replacement process during deformation. REE contents of Ap4 are low, as REE originally contained in the precursor apatite were redistributed mainly into zoisite. Apatite shielded as inclusions in ilmenite and garnet preserve the REE-rich signature of the initial magmatic (Ap1) and granulite (Ap2) apatite, indicating these grains did not undergo further re-equilibration during Caledonian metamorphism. The resistance of apatite to compositional re-equilibration in this case confirms the petrological potential of apatite inclusions shielded in chemically inert minerals to track early magmatic, or metamorphic, crystallisation stages.Emilie Janots, Håkon Austrheim, Carl Spandler, Johannes Hammerli, Claudia A. Trepmann, Jasper Berndt, Valérie Magnin, Anthony I.S. Kem

Evaluating the influence of meteorite impact events on global potassium feldspar availability to the atmosphere since 600 Ma

Potassium feldspar present in global mineral aerosol (30%. By combining crater size and tectonic reconstructions, we are able to provide a quantitative and self-consistent assessment of changes to global potassium feldspar availability. Considerable differences in potassium feldspar availability following meteorite impact events are revealed. Different impact events generated dust containing different amounts of potassium feldspar. Differing levels of influence upon climate are hypothesized, and should now be tested by looking at stratigraphic records of these events to reveal the sensitivity of climate to different dust mineralogy