231 research outputs found
Charge localization at the interface between La1-xSrxMnO3 and the infinite layers cuprate CaCuO2
(CaCuO2)m/(La0.7Sr0.3MnO3)n superlattices, consisting of the infinite layers
cuprate CaCuO2 and the optimally doped manganite La1-xSrxMnO3, were grown by
pulsed laser deposition. The transport properties are dominated by the
manganite block. X-Ray Absorption spectroscopy measurements show a clear
evidence of an orbital reconstruction at the interface, ascribed to the
hybridization between the Cu 3d3z2-r2 and the Mn 3d3z2-r2 orbitals via
interface apical oxygen ions. Such a mechanism localizes holes at the
interfaces, thus preventing charge transfer to the CaCuO2 block. Some charge
(holes) transfer occurs toward the La0.7Sr0.3MnO3 block in strongly oxidized
superlattices, contributing to the suppression of the magnetotransport
properties.Comment: 20 pages, 6 figure
Evidence of orbital reconstruction at interfaces in La0.67Sr0.33MnO3 films
Electronic properties of transition metal oxides at interfaces are influenced
by strain, electric polarization and oxygen diffusion. Linear dichroism (LD)
x-ray absorption, diffraction, transport and magnetization on thin
La0.7Sr0.3MnO3 films, allow identification of a peculiar universal interface
effect. We report the LD signature of preferential 3d-eg(3z2-r2) occupation at
the interface, suppressing the double exchange mechanism. This surface orbital
reconstruction is opposite of that favored by residual strain and independent
of dipolar fields, chemical nature of the substrate and capping.Comment: 13 pages, 5 figure
La0.8Sr0.2Ga0.8Mg0.2O3-δ thin films for IT-SOFCs: Microstructure and transport properties correlation.
Highly textured La0.8Sr0.2Ga0.8Mg0.2O3 (LSGM) films with columnar structure were grown by pulsed laser
deposition on (001) NdGaO3 and SrTiO3 buffered (001) MgO substrates. Combined analysis of the films
structure and morphology and EIS measurements showed that the transport properties are mainly
limited by perpendicular grain boundaries effects. Increasing the film thickness, columnar nanosized
grains tend to coalesce leading to a decrease of grain boundary concentration, hence to enhanced
conductivity
Current profiles and AC losses of a superconducting strip with elliptic cross-section in perpendicular magnetic field
The case of a hard type II superconductor in the form of strip with elliptic
cross-section when placed in transverse magnetic field is studied. We approach
the problem in two steps, both based on the critical-state model. First we
calculate numerically the penetrated current profiles that ensure complete
shielding in the interior, without assuming an a priori form for the profiles.
In the second step we introduce an analytical approximation that asumes that
the current profiles are ellipses. Expressions linking the sample magnetization
to the applied field are derived covering the whole range of applied fields.
The theoretical predictions are tested by the comparison with experimental data
for the imaginary part of AC susceptibility.Comment: 12 pages; 3 figure
Effect of water adsorption on conductivity in epitaxial Sm0.1Ce0.9O2-δ thin film for micro solid oxide fuel cells applications
Water adsorption, splitting, and proton liberation were investigated on Sm0.1Ce0.9O2-δ thin films by scanning probe microscopy. An irreversible volume expansion was observed by applying a positive bias with increased temperature. The volume expansion is also linearly dependent on the relative humidity. A reversible water adsorption process and its effect on the conductivity were also investigated by electrochemical strain microscopy and first order reversal curve under a number of experiment conditions. The presence of a Ce3+ along with OH groups, detected by hard x-ray photoemission spectroscopy established a clear correlation between the water incorporation and the valence state of C
Strain induced phase separation in La0.7Sr0.3MnO3 thin films.
La0.7Sr0.3MnO3 thin films having different thicknesses were grown by pulsed laser deposition with in situ
reflection high energy electron diffraction diagnostics on LaAlO3 substrates. The mismatch between film and
substrate gives rise to an in-plane compressive biaxial strain, which partially relaxes in films thicker than
30 unit cells. Accordingly, the ratio between the out-of-plane and the in-plane lattice parameter c/a varies
between 1.06 fully strained and 1.03 partially relaxed. In-plane compressive strain favors the stabilization of
the 3z2−r2 orbitals chain-type antiferromagnetic phase, thus giving rise to a sizeable x-ray absorption linear
dichroism signal. The shape of the linear dichroism depends weakly on the c/a ratio, while its intensity
strongly increases with c/a. At the same time, the metal-insulator transition temperature shifts from about
360 K towards lower temperatures with decreasing thickness, eventually reaching an insulating state for the
30 unit cells film. Low-temperature nuclear magnetic resonance spectra show a decrease of the MnDE doubleexchange
metallic contribution with decreasing the thickness, which becomes negligible in the 30 unit cells
thick film. The experimental results demonstrate a strain driven competition between two stable phases: the
orbital ordered chain-type insulating antiferromagnetic and the orbital disordered metallic ferromagnetic. For
intermediate values of the epitaxial strain the local minimum state of the system lies in a gap region between
the two stable phases. Such a region has glassy characteristics with coexisting clusters of the two phases. The
strain is used as a driving force to span the glassy region
Adenosine A2A receptor modulation of hippocampal CA3-CA1 synapse plasticity during associative learning in behaving mice
© 2009 Nature Publishing Group All rights reservedPrevious in vitro studies have characterized the electrophysiological and molecular signaling pathways of adenosine tonic modulation on long-lasting synaptic plasticity events, particularly for hippocampal long-term potentiation(LTP). However, it remains to be elucidated
whether the long-term changes produced by endogenous adenosine in the efficiency of synapses are related to those required for
learning and memory formation. Our goal was to understand how endogenous activation of adenosine excitatory A2A receptors modulates the associative learning evolution in conscious behaving mice. We have studied here the effects of the application of a highly selective A2A receptor antagonist, SCH58261, upon a well-known associative learning paradigm - classical eyeblink conditioning. We used a trace paradigm, with a tone as the conditioned stimulus (CS) and an electric shock presented to the supraorbital nerve as the unconditioned stimulus(US). A single electrical pulse was presented to the Schaffer collateral–commissural pathway to evoke field EPSPs (fEPSPs) in the pyramidal CA1 area during the CS–US interval. In vehicle-injected animals, there was a progressive increase in the percentage of conditioning responses (CRs) and in the slope of fEPSPs through conditioning sessions, an effect that was completely prevented (and lost) in SCH58261 (0.5 mg/kg, i.p.)-injected animals. Moreover, experimentally evoked LTP was impaired in SCH58261- injected mice. In conclusion, the endogenous activation of adenosine A2A receptors plays a pivotal effect on the associative learning process and its relevant hippocampal circuits, including activity-dependent changes at the CA3-CA1 synapse.This study was supported by grants from the Spanish Ministry of Education and Research (BFU2005-01024 and BFU2005-02512), Spanish Junta de Andalucía (BIO-122 and CVI-02487), and the Fundación Conocimiento y Cultura of
the Pablo de Olavide University (Seville, Spain).B. Fontinha was in receipt of a studentship from a project grant (POCI/SAU-NEU/56332/2004) supported by Fundação para a Ciência e Tecnologia (FCT, Portugal), and of an STSM from Cost B30 concerted action of the EU
Is the functional interaction between adenosine A2A receptors and metabotropic glutamate 5 receptors a general mechanism in the brain? Differences and similarities between the striatum and the hippocampus
The aim of the present paper was to examine, in a comparative way, the occurrence and the mechanisms of the interactions between adenosine A2A receptors (A2ARs) and metabotropic glutamate 5 receptors (mGlu5Rs) in the hippocampus and the striatum. In rat hippocampal and corticostriatal slices, combined ineffective doses of the mGlu5R agonist 2-chloro-5-hydroxyphenylglycine (CHPG) and the A2AR agonist CGS 21680 synergistically reduced the slope of excitatory postsynaptic field potentials (fEPSPs) recorded in CA1 and the amplitude of field potentials (FPs) recorded in the dorsomedial striatum. The cyclic adenosine monophosphate (cAMP)/protein kinase A (PKA) pathway appeared to be involved in the effects of CGS 21680 in corticostriatal but not in hippocampal slices. In both areas, a postsynaptic locus of interaction appeared more likely. N-methyl-D-aspartate (NMDA) reduced the fEPSP slope and FP amplitude in hippocampal and corticostriatal slices, respectively. Such an effect was significantly potentiated by CHPG in both areas. Interestingly, the A2AR antagonist ZM 241385 significantly reduced the NMDA-potentiating effect of CHPG. In primary cultures of rat hippocampal and striatal neurons (ED 17, DIV 14), CHPG significantly potentiated NMDA-induced lactate dehydrogenase (LDH) release. Again, such an effect was prevented by ZM 241385. Our results show that A2A and mGlu5 receptors functionally interact both in the hippocampus and in the striatum, even though different mechanisms seem to be involved in the two areas. The ability of A2ARs to control mGlu5R-dependent effects may thus be a general feature of A2ARs in different brain regions (irrespective of their density) and may represent an additional target for the development of therapeutic strategies against neurological disorders
High Tc superconductivity in superlattices of insulating oxides
We report the occurrence of superconductivity, with maximum Tc = 40 K, in
superlattices (SLs) based on two insulating oxides, namely CaCuO2 and SrTiO3.
In these (CaCuO2)n/(SrTiO3)m SLs, the CuO2 planes belong only to CaCuO2 block,
which is an antiferromagnetic insulator. Superconductivity, confined within few
unit cells at the CaCuO2/SrTiO3 interface, shows up only when the SLs are grown
in a highly oxidizing atmosphere, because of extra oxygen ions entering at the
interfaces. Evidence is reported that the hole doping of the CuO2 planes is
obtained by charge transfer from the interface layers, which act as charge
reservoir.Comment: 18 pages, 8 figure
Control of magnetic anisotropy by orbital hybridization in (La0.67Sr0.33MnO3)n/(SrTiO3)n superlattice
The asymmetry of chemical nature at the hetero-structural interface offers an
unique opportunity to design desirable electronic structure by controlling
charge transfer and orbital hybridization across the interface. However, the
control of hetero-interface remains a daunting task. Here, we report the
modulation of interfacial coupling of (La0.67Sr0.33MnO3)n/(SrTiO3)n
superlattices by manipulating the periodic thickness with n unit cells of
SrTiO3 and n unit cells La0.67Sr0.33MnO3. The easy axis of magnetic anisotropy
rotates from in-plane (n = 10) to out-of-plane (n = 2) orientation at 150 K.
Transmission electron microscopy reveals enlarged tetragonal ratio > 1 with
breaking of volume conservation around the (La0.67Sr0.33MnO3)n/(SrTiO3)n
interface, and electronic charge transfer from Mn to Ti 3d orbitals across the
interface. Orbital hybridization accompanying the charge transfer results in
preferred occupancy of 3d3z2-r2 orbital at the interface, which induces a
stronger electronic hopping integral along the out-of-plane direction and
corresponding out-of-plane magnetic easy axis for n = 2. We demonstrate that
interfacial orbital hybridization in superlattices of strongly correlated
oxides may be a promising approach to tailor electronic and magnetic properties
in device applications
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