230 research outputs found

    The public data method: an alternative procedure for estimating toxic releases in the production of petrochemicals for the materials production stage of a life-cycle inventory

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    An alternative technique for estimating toxic releases in the production of petrochemicals for the materials production stage of a life-cycle inventory was developed. This procedure is called the Public Data Method and is based on data sources available from the public domain - the Toxic Release Inventory, the Chemical Guide to United States, selected literature sources, Chemical Marketing Reporter chemical profiles, and the Environmental Protection Agency\u27s Sector Facility Indexing Project notebook on petroleum refining. Petrochemical databases for polystyrene, high-density polyethylene, polyvinyl chloride, polycarbonate, and ethylene glycol were created by the Public Data Method and presented as examples of this methodology. Results were mixed, with the positive result of speciation of toxic releases, but negative result of inconsistent datum values when compared to values from other data sources. Advantages of the Public Data Method are generation of speciated data of toxic chemical emissions, less aggregation than is found in the data sources of conventional life-cycle inventories, data that is current and date-specific, and less labor-intensive than current methods. Although the Public Data Method as presented in this study was applied to petrochemicals, it could be used for other materials based on sector facility reports of other industries such as, aluminum, copper, lead, or zinc refining, the iron and steel industry, metal mining extraction, glass and other industries

    Comparison of numerical simulation and experimental data for steam-in-place sterilization

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    A complex problem involving convective flow of a binary mixture containing a condensable vapor and noncondensable gas in a partially enclosed chamber was modelled and results compared to transient experimental values. The finite element model successfully predicted transport processes in dead-ended tubes with inside diameters of 0.4 to 1.0 cm. When buoyancy driven convective flow was dominant, temperature and mixture compositions agreed with experimental data. Data from 0.4 cm tubes indicate diffusion to be the primary air removal method in small diameter tubes and the diffusivity value in the model to be too large

    Prediction of pressure drop in fluid tuned mounts using analytical and computational techniques

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    A simplified model for predicting pressure drop in fluid tuned isolator mounts was developed. The model is based on an exact solution to the Navier-Stokes equations and was made more general through the use of empirical coefficients. The values of these coefficients were determined by numerical simulation of the flow using the commercial computational fluid dynamics (CFD) package FIDAP

    Provable first-order transitions for liquid crystal and lattice gauge models with continuous symmetries

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    We consider various sufficiently nonlinear sigma models for nematic liquid crystal ordering of RP^{N-1} type and of lattice gauge type with continous symmetries. We rigorously show that they exhibit a first-order transition in the temperature. The result holds in dimension 2 or more for the RP^{N-1} models and in dimension 3 or more for the lattice gauge models. In the two-dimensional case our results clarify and solve a recent controversy about the possibility of such transitions. For lattice gauge models our methods provide the first proof of a first-order transition in a model with a continuous gauge symmetry

    Evaluation of an entraining droplet activation parameterization using in situ cloud data

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    This study investigates the ability of a droplet activation parameterization (which considers the effects of entrainment and mixing) to reproduce observed cloud droplet number concentration (CDNC) in ambient clouds. Predictions of the parameterization are compared against cloud averages of CDNC from ambient cumulus and stratocumulus clouds sampled during CRYSTAL‐FACE (Key West, Florida, July 2002) and CSTRIPE (Monterey, California, July 2003), respectively. The entrainment parameters required by the parameterization are derived from the observed liquid water content profiles. For the cumulus clouds considered in the study, CDNC is overpredicted by 45% with the adiabatic parameterization. When entrainment is accounted for, the predicted CDNC agrees within 3.5%. Cloud‐averaged CDNC for stratocumulus clouds is well captured when entrainment is not considered. In all cases considered, the entraining parameterization compared favorably against a statistical correlation developed from observations to treat entrainment effects on droplet number. These results suggest that including entrainment effects in the calculation of CDNC, as presented here, could address important overprediction biases associated with using adiabatic CDNC to represent cloud‐scale average values

    Entropy and Spin Susceptibility of s-wave Type-II Superconductors near Hc2H_{c2}

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    A theoretical study is performed on the entropy SsS_{\rm s} and the spin susceptibility χs\chi_{\rm s} near the upper critical field Hc2H_{c2} of s-wave type-II superconductors with arbitrary impurity concentrations. The changes of these quantities through Hc2H_{c2} may be expressed as [Ss(T,B)Ss(T,0)]/[Sn(T)Ss(T,0)]=1αS(1B/Hc2)(B/Hc2)αS[S_{\rm s}(T,B)-S_{\rm s}(T,0)]/[S_{\rm n}(T)-S_{\rm s}(T,0)]=1-\alpha_{S}(1-B/H_{c2})\approx (B/H_{c2})^{\alpha_{S}}, for example, where BB is the average flux density and SnS_{\rm n} denotes entropy in the normal state. It is found that the slopes αS\alpha_{S} and αχ\alpha_{\chi} at T=0 are identical, connected directly with the zero-energy density of states, and vary from 1.72 in the dirty limit to 0.50.60.5\sim 0.6 in the clean limit. This mean-free-path dependence of αS\alpha_{S} and αχ\alpha_{\chi} at T=0 is quantitatively the same as that of the slope αρ(T=0)\alpha_{\rho}(T=0) for the flux-flow resistivity studied previously. The result suggests that Ss(B)S_{\rm s}(B) and χs(B)\chi_{\rm s}(B) near T=0 are convex downward (upward) in the dirty (clean) limit, deviating substantially from the linear behavior B/Hc2\propto B/H_{c2}. The specific-heat jump at Hc2H_{c2} also shows fairly large mean-free-path dependence.Comment: 8 pages, 5 figure

    Possible first order transition in the two-dimensional Ginzburg-Landau model induced by thermally fluctuating vortex cores

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    We study the two-dimensional Ginzburg-Landau model of a neutral superfluid in the vicinity of the vortex unbinding transition. The model is mapped onto an effective interacting vortex gas by a systematic perturbative elimination of all fluctuating degrees of freedom (amplitude {\em and} phase of the order parameter field) except the vortex positions. In the Coulomb gas descriptions derived previously in the literature, thermal amplitude fluctuations were neglected altogether. We argue that, if one includes the latter, the vortices still form a two- dimensional Coulomb gas, but the vortex fugacity can be substantially raised. Under the assumption that Minnhagen's generic phase diagram of the two- dimensional Coulomb gas is correct, our results then point to a first order transition rather than a Kosterlitz-Thouless transition, provided the Ginzburg-Landau correlation length is large enough in units of a microscopic cutoff length for fluctuations. The experimental relevance of these results is briefly discussed. [Submitted to J. Stat. Phys.]Comment: 36 pages, LaTeX, 6 figures upon request, UATP2-DB1-9
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