Influence of disordered porous media in the anomalous properties of a simple water model

The thermodynamic, dynamic and structural behavior of a water-like system confined in a matrix is analyzed for increasing confining geometries. The liquid is modeled by a two dimensional associating lattice gas model that exhibits density and diffusion anomalies, in similarity to the anomalies present in liquid water. The matrix is a triangular lattice in which fixed obstacles impose restrictions to the occupation of the particles. We show that obstacules shortens all lines, including the phase coexistence, the critical and the anomalous lines. The inclusion of a very dense matrix not only suppress the anomalies but also the liquid-liquid critical point

General approach for studying first-order phase transitions at low temperatures

By combining different ideas, a general and efficient protocol to deal with discontinuous phase transitions at low temperatures is proposed. For small $T$'s, it is possible to derive a generic analytic expression for appropriate order parameters, whose coefficients are obtained from simple simulations. Once in such regimes simulations by standard algorithms are not reliable, an enhanced tempering method, the parallel tempering -- accurate for small and intermediate system sizes with rather low computational cost -- is used. Finally, from finite size analysis, one can obtain the thermodynamic limit. The procedure is illustrated for four distinct models, demonstrating its power, e.g., to locate coexistence lines and the phases density at the coexistence.Comment: 5 page

Diffusion anomaly and dynamic transitions in the Bell-Lavis water model

In this paper we investigate the dynamic properties of the minimal Bell-Lavis (BL) water model and their relation to the thermodynamic anomalies. The Bell-Lavis model is defined on a triangular lattice in which water molecules are represented by particles with three symmetric bonding arms interacting through van der Waals and hydrogen bonds. We have studied the model diffusivity in different regions of the phase diagram through Monte Carlo simulations. Our results show that the model displays a region of anomalous diffusion which lies inside the region of anomalous density, englobed by the line of temperatures of maximum density (TMD). Further, we have found that the diffusivity undergoes a dynamic transition which may be classified as fragile-to-strong transition at the critical line only at low pressures. At higher densities, no dynamic transition is seen on crossing the critical line. Thus evidence from this study is that relation of dynamic transitions to criticality may be discarded

Very extended cold gas, star formation and outflows in the halo of a bright QSO at z>6

Past observations of QSO host galaxies at z >6 have found cold gas and star formation on compact scales of a few kiloparsecs. We present new high sensitivity IRAM PdBI follow-up observations of the [CII] 158micron emission line and FIR continuum in the host galaxy of SDSS J1148+5152, a luminous QSO at redshift 6.4189. We find that a large fraction of the gas traced by [CII] is at high velocities, up to ~1400 km/s relative to the systemic velocity, confirming the presence of a major quasar-driven outflow indicated by previous observations. The outflow has a complex morphology and reaches a maximum projected radius of ~30 kpc. The extreme spatial extent of the outflow allows us, for the first time in an external galaxy, to estimate mass-loss rate, kinetic power and momentum rate of the outflow as a function of the projected distance from the nucleus and the dynamical time-scale. These trends reveal multiple outflow events during the past 100 Myr, although the bulk of the mass, energy and momentum appear to have been released more recently, within the past ~20 Myr. Surprisingly, we discover that also the quiescent gas at systemic velocity is extremely extended. More specifically, we find that, while 30% of the [CII] within v\in(-200, 200) km/s traces a compact component that is not resolved by our observations, 70% of the [CII] emission in this velocity range is extended, with a projected FWHM size of 17.4+-1.4 kpc. We detect FIR continuum emission associated with both the compact and the extended [CII] components, although the extended FIR emission has a FWHM of 11+-3 kpc, thus smaller than the extended [CII] source. Overall, our results indicate that the cold gas traced by [CII] is distributed up to r~30 kpc. A large fraction of extended [CII] is likely associated with star formation on large scales, but the [CII] source extends well beyond the FIR continuum.Comment: Accepted for publication in A&A, 21 pages, 18 figures, 3 tables (v2: accepted version, discussion expanded in Sect. 3, 4 and in the Appendices, minor changes elsewhere