Laser diagnostics for NTP fuel corrosion studies

Viewgraphs and explanations on laser diagnostics for nuclear thermal propulsion (NTP) fuel corrosion studies are presented. Topics covered include: NTP fuels; U-Zr-C system corrosion products; planar laser-induced fluorescence (PLIF); utilization of PLIF for corrosion product characterization of nuclear thermal rocket fuel elements under test; ZrC emission spectrum; and PLIF imaging of ZrC plume

Tomorrow's Doctors: Review of The Australian Medical Workforce Advisory Committee (AMWAC)

The aim of this Review, prepared under the auspices of the Australian Health Ministers' Advisory Council, is to 1. Assess AMWAC's performance to date against its original terms of reference and assess to what extent have expectations been achieved? 2. Assess and make relevant recommendations on future national medical workforce planning needs, taking account of the relationship between the medical workforce and other health professionals and support staff, and AHMAC's decision to establish the Australian Health Workforce Advisory Committee (AHWAC); and the relationship between workforce and broader health systems issues. 3. Assess and make relevant recommendations on the suitability of AMWAC - including its structure and methodology - for meeting future medical workforce planning needs, taking account of access to and utilisation of evidence-based data; need for independence and access to broadly sourced advice; international experiences; and current issues, including the changing medical workforce; the implications of the application of the Trade Practices Act 1974 and competition policy; and corporatisation of medical practice. 4. Consider and recommend on appropriate financial commitment by AHMAC to medical workforce planning

High-Temperature Corrosion Testing of Uranium Silicide Surrogates

The corrosion resistance of cerium silicide, a surrogate of uranium silicide, is investigated to gain insight into the reaction of uranium silicide with water. As-received and proton-irradiated Ce3Si2, CeSi2, and CeSi1.x monolithic pellets are subjected to corrosion tests in water at 300°C and 9 MPa for up to 48 h. Results show that an oxide layer composed of Ce4.67 (SiO4)3O forms on the surface of all samples, and it grows thicker with extended exposure times. Irradiated samples corrode to a greater extent than their unirradiated counterparts, which is mainly a result of the existing post-irradiation cerium oxide and the presence of ion-induced defects. Most of the Ce3Si2 samples crack (as-received) or fracture (ion-irradiated) during testing, which is due to the brittleness of the samples and oxide erosion/spallation that occur during testing

Impurity Ion Complexation Enhances Carbon Dioxide Reduction Catalysis

Herein, we show that group 11 CO[subscript 2] reduction catalysts are rapidly poisoned by progressive deposition of trace metal ion impurities present in high purity electrolytes. Metal impurity deposition was characterized by XPS and in situ stripping voltammetry and is coincident with loss of catalytic activity and selectivity for CO[subscript 2] reduction, favoring hydrogen evolution on poisoned surfaces. Metal deposition can be suppressed by complexing trace metal ion impurities with ethylenediaminetetraacetic acid or solid-supported iminodiacetate resins. Metal ion complexation allows for reproducible, sustained catalytic activity and selectivity for CO[subscript 2] reduction on Au, Ag, and Cu electrodes. Together, this study establishes the principal mode by which group 11 CO[subscript 2] reduction catalysts are poisoned and lays out a general approach for extending the lifetime of electrocatalysts subject to impurity metal deposition.MIT Energy Initiative (Saudi Aramco, research agreement)United States. Air Force Office of Scientific Research (Award FA9550-15-1-0135)Massachusetts Institute of Technology. Department of Chemistry (Junior Faculty Funds)National Science Foundation (U.S.) (Predoctoral Fellowship)National Science Foundation (U.S.) (MIT MRSEC Program, award number DMR-0819762

An Extended Radio Counterpart of TeV J2032+4130?

We carried out a 5-pointing mosaic observation of TeV J2032+4130 at 1.4 and 4.8 GHz with the VLA in April of 2003. The analysis of the 4.8GHz data indicate weak wispy shell-like radio structure(s) which are at least partially non-thermal. The radio data is compatible with one or more young supernova remnants or perhaps the signature of large scale cluster shocks in this region induced by the violent action of the many massive stars in Cyg OB2.Comment: Proc. 1st GLAST Symp. Feb 5-8, 2007, Stanford C

XMM-Newton observations of the first unidentified TeV gamma-ray source TeV J2032+4130

(abridged) The first unidentified very high energy gamma ray source (TeV J2032+4130) in the Cygnus region has been the subject of intensive search for a counterpart source at other wavelengths. A deep ($\approx 50$ ksec) exposure of TeV J2032+4130 with \textit{XMM-Newton} has been obtained. The contribution of point sources to the observed X-ray emission from TeV J2032+4130 is subtracted from the data. The point-source subtracted X-ray data are analyzed using blank sky exposures and regions adjacent to the position of TeV J2032+4130 in the field of view covered by the XMM-Newton telescopes to search for diffuse X-ray emission. An extended X-ray emission region with a full width half maximum (FWHM) size of $\approx 12$ arc min is found. The centroid of the emission is co-located with the position of TeV J2032+4130.The energy spectrum of the emission coinciding with the position and extension of TeV J2032+4130 can be modeled by a power-law model with a photon index $\Gamma=1.5\pm0.2_\mathrm{stat}\pm0.3_\mathrm{sys}$ and an energy flux integrated between 2 and 10 keV of $f_{2-10 \mathrm{keV}} \approx 7\cdot 10^{-13}$ ergs/(cm$^2$ s) which is lower than the very high energy gamma-ray flux observed from TeV J2032+4130. We conclude that the faint extended X-ray emission discovered in this observation is the X-ray counterpart of TeV J2032+4130. Formally, it can not be excluded that the extended emission is due to an unrelated population of faint, hot ($k_BT\approx 10$ keV) unresolved point-sources which by chance coincides with the position and extension of TeV J2032+4130. We discuss our findings in the frame of both hadronic and leptonic gamma-ray production scenarios.Comment: 5 Pages, 3 Figures, accepted for publication in A&

Microdomain Formation, Oxidation, and Cation Ordering in LaCa\u3csub\u3e2\u3c/sub\u3eFe\u3csub\u3e3\u3c/sub\u3eO\u3csub\u3e8+y\u3c/sub\u3e

The compound LaCa2Fe3O8+y, also known as the Grenier phase, is known to undergo an order–disorder transformation (ODT) at high temperatures and oxidation has been observed when the compound is cooled in air after the ODT. In this study, we have synthesized the Grenier compound in air using traditional solid-state reactions and investigated the structure and composition before and after the ODT. Thermal analysis showed that the material undergoes an ODT in both oxygen and argon atmospheres with dynamic, temperature dependent, oxidation upon cooling. Results from scanning transmission electron microscopy (STEM) suggest that the Grenier phase has preferential segregation of Ca and La on the two crystallographic A sites before the ODT, but a random distribution above the ODT temperature. Furthermore, STEM images suggest the possibility that oxygen excess may exist in La-rich regions within microdomains rather than at microdomain boundaries