774 research outputs found
Thermal and Arc Resistance of Polyester Resin Glass Reinforced Laminates
The heat resistance of several types of polyester resins are studied by measuring the flexural strength of glass reinforced laminates before and after conditioning at 200°C. Arc resistance readings are also taken. The type of saturated acid, glycol and monomer is varied. The ratio of saturated to unsaturated acid and the ratio of monomer to base resin is also studied. Chlorendic acid improves the heat resistance over phthalic and isophthalic acids but it lowers the arc resistance. Ethylene glycol yields resins with the highest flexural strengths. Styrene monomer content has little effect on heat resistance up to 40%. In the case of phthalic and isophthalic acid, increasing the proportion of unsaturated acid increases the heat resistance. However, the chlorendicmaleic acid combination shows optimum properties at a molar ratio of three to five
A study of the replacement of the aryl amino group by hydrogen using isopropyl nitrite
The use of the amino group as a directing agent in the synthesis of many aryl compounds is a well known and often used process. Therefore a simple and efficient method of removing the amino group after it has served its purpose is to be desired. The purpose of this work has been to investigate the possibilitiy of deaminating using dilute solutions and isopropyl nitrite as a diazotizing agent. The method of reacting as well as the use of different reactants was studied
Evolution of superconductivity by oxygen annealing in FeTe0.8S0.2
Oxygen annealing dramatically improved the superconducting properties of
solid-state-reacted FeTe0.8S0.2, which showed only a broad onset of
superconducting transition just after the synthesis. The zero resistivity
appeared and reached 8.5 K by the oxygen annealing at 200\degree C. The
superconducting volume fraction was also enhanced from 0 to almost 100%. The
lattice constants were compressed by the oxygen annealing, indicating that the
evolution of bulk superconductivity in FeTe0.8S0.2 was correlated to the
shrinkage of lattice.Comment: 13 pages, 6 figure
Long-Lived Electron Capture Dissociation Product Ions Experience Radical Migration via Hydrogen Abstraction
To explore the mechanism of electron capture dissociation (ECD) of linear peptides, a set of 16-mer peptides were synthesized with deuterium labeled on the α-carbon position of four glycines. The ECD spectra of these peptides showed that such peptides exhibit a preference for the radical to migrate to the α-carbon position on glycine via hydrogen (or deuterium) abstraction before the final cleavage and generation of the detected product ions. The data show c-type fragment ions, ions corresponding to the radical cation of the c-type fragments, c·, and they also show c·-1 peaks in the deuterated peptides only. The presence of the c·-1 peaks is best explained by radical-mediated scrambling of the deuterium atoms in the long-lived, metastable, radical intermediate complex formed by initial electron capture, followed by dissociation of the complex. These data suggest the presence of at least two mechanisms, one slow, one fast. The abundance of H· and −CO losses from the precursor ion changed upon deuterium labeling indicating the presence of a kinetic isotope effect, which suggests that the values reported here represent an underestimation of radical migration and H/D scrambling in the observed fragments
Performance of a cryogenic system prototype for the XENON1T Detector
We have developed an efficient cryogenic system with heat exchange and
associated gas purification system, as a prototype for the XENON1T experiment.
The XENON1T detector will use about 3 ton of liquid xenon (LXe) at a
temperature of 175K as target and detection medium for a dark matter search. In
this paper we report results on the cryogenic system performance focusing on
the dynamics of the gas circulation-purification through a heated getter, at
flow rates above 50 Standard Liter per Minute (SLPM). A maximum flow of 114
SLPM has been achieved, and using two heat exchangers in parallel, a heat
exchange efficiency better than 96% has been measured
Asymmetry of Magnetosheath Flows and Magnetopause Shape During Low Alfvén Mach Number Solar Wind
Previous works have emphasized the significant influence of the solar wind Alfvén Mach number (MA) on magnetospheric dynamics. Here we report statistical, observational results that pertain to changes in the magnetosheath flow distribution and magnetopause shape as a function of solar wind MA and interplanetary magnetic field (IMF) clock angle orientation. We use all Cluster 1 data in the magnetosheath during the period 2001–2010, using an appropriate spatial superposition procedure, to produce magnetosheath flow distributions as a function of location in themagnetosheath relative to the IMF and other parameters. The results demonstrate that enhanced flows in the magnetosheath are expected at locations quasi-perpendicular to the IMF direction in the plane perpendicular to the Sun-Earth line; in other words, for the special case of a northward IMF, enhanced flows are observed on the dawn and dusk flanks of the magnetosphere, while much lower flows are observed above the poles. The largest flows are adjacent to themagnetopause. Using appropriate magnetopause crossing lists (for both high and lowMA), we also investigate the changes inmagnetopause shape as a function of solarwindMA and IMF orientation. Comparing observed magnetopause crossings with predicted positions from an axisymmetric semi-empirical model, we statistically show that the magnetopause is generally circular during high MA, while is it elongated (albeit with moderate statistical significance) along the direction of the IMF during low MA. These findings are consistent with enhanced magnetic forces that prevail in the magnetosheath during lowMA. The component of the magnetic forces parallel to the magnetopause produces the enhanced flows along and adjacent to the magnetopause, while the component normal to the magnetopause exerts an asymmetric pressure on the magnetopause that deforms it into an elongated shape
Dynamic fibrils in H-alpha and C IV
Aim: To study the interaction of the solar chromosphere with the transition
region, in particular active-region jets in the transition region and their
relation to chromospheric fibrils. Methods: We carefully align image sequences
taken simultaneously in C IV with the Transition Region and Coronal Explorer
and in H-alpha with the Swedish 1-m Solar Telescope. We examine the temporal
evolution of "dynamic fibrils", i.e., individual short-lived active-region
chromospheric jet-like features in H-alpha. Results: All dynamic fibrils appear
as absorption features in H-alpha that progress from the blue to the red wing
through the line, and often show recurrent behavior. Some of them, but not all,
appear also as bright features in C IV which develop at or just beyond the apex
of the H-alpha darkening. They tend to best resemble the H-alpha fibril at +700
mA half a minute earlier. Conclusions: Dynamic chromospheric fibrils observed
in H-alpha regularly correspond to transition-region jets observed in the
ultraviolet. This correspondence suggests that some plasma associated with
dynamic fibrils is heated to transition-region temperatures.Comment: 8 pages, 8 figure
Influence of Preparative Form on the Target Efficiency and Toxicity of the Solid Insecticide Based on Pyrethroid and Neonicatinoid
Received: 24.11.2021. Revised: 11.01.2022. Accepted: 11.01.2022. Available online: 13.01.2022.The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.The influence of solid preparative form was studied on the «GET Dry» insecticide based on alpha-cypermethrin and imidacloprid. The target efficiency as acute and residual impact was studied when agent was applied against the bedbugs (Cimex hemipterus), German cockroach (Blatella germanica), common house flies (Musca domestica) and larvae of the leather beetles (Attagenus smirnovi). The agent demonstrated strong acute effect (about 100%) when applied against the cockroaches, bugs, and flies. Moreover, the agent demonstrates the residual impact on the cockroaches, flies, fleas for 45 days, and on the bugs for 30 days. The slight insecticidal activity was observed when the agent was applied against the larvae. We studied toxicity of the agent, LD50, when swallowed (moderately hazardous substances, class III) and when applied to the skin (low-hazard substance, class IV) as well as studied its inhalation hazard according to its volatility С 20 °C, irritant action when applied to the skin (slight) and eye irritation (moderate). Sensibilizing action was not observed
Explosive events - swirling transition region jets
In this paper, we extend our earlier work to provide additional evidence for
an alternative scenario to explain the nature of so-called `explosive events'.
The bi-directed, fast Doppler motion of explosive events observed
spectroscopically in the transition region emission is classically interpreted
as a pair of bidirectional jets moving upward and downward from a reconnection
site. We discuss the problems of such a model. In our previous work, we focused
basically on the discrepancy of fast Doppler motion without detectable motion
in the image plane. We now suggest an alternative scenario for the explosive
events, based on our observations of spectral line tilts and bifurcated
structure in some events. Both features are indicative of rotational motion in
narrow structures. We explain the bifurcation as the result of rotation of
hollow cylindrical structures and demonstrate that such a sheath model can also
be applied to explain the nature of the puzzling `explosive events'. We find
that the spectral tilt, the lack of apparent motion, the bifurcation, and a
rapidly growing number of direct observations support an alternative scenario
of linear, spicular-sized jets with a strong spinning motion.Comment: 9 pages, 3 figures, accepted for publication in Solar Physic
The Structure and Dynamics of the Upper Chromosphere and Lower Transition Region as Revealed by the Subarcsecond VAULT Observations
The Very high Angular resolution ULtraviolet Telescope (VAULT) is a sounding
rocket payload built to study the crucial interface between the solar
chromosphere and the corona by observing the strongest line in the solar
spectrum, the Ly-a line at 1216 {\AA}. In two flights, VAULT succeeded in
obtaining the first ever sub-arcsecond (0.5") images of this region with high
sensitivity and cadence. Detailed analyses of those observations have
contributed significantly to new ideas about the nature of the transition
region. Here, we present a broad overview of the Ly-a atmosphere as revealed by
the VAULT observations, and bring together past results and new analyses from
the second VAULT flight to create a synthesis of our current knowledge of the
high-resolution Ly-a Sun. We hope that this work will serve as a good reference
for the design of upcoming Ly-a telescopes and observing plans.Comment: 28 pages, 11 figure
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