Potential for Abrupt Changes in Atmospheric Methane

Methane (CH4) is the second most important greenhouse gas that humans directly influence, carbon dioxide (CO2) being first. Concerns about methane’s role in abrupt climate change stem primarily from (1) the large quantities of methane stored as solid methane hydrate on the sea floor and to a lesser degree in terrestrial sediments, and the possibility that these reservoirs could become unstable in the face of future global warming, and (2) the possibility of large-scale conversion of frozen soil in the high- latitude Northern Hemisphere to methane producing wetland, due to accelerated warming at high latitudes. This chapter summarizes the current state of knowledge about these reservoirs and their potential for forcing abrupt climate change

Surface exposure geochronology using cosmogenic nuclides : applications in Antarctic glacial geology

Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences, and the Woods Hole Oceanographic Institution, 1994.Vita.Includes bibliographical references (leaves 224-227).by Edward Jeremy Brook.Ph.D

The Guitarist-Composer Pedagogue: An Exploration of Technical and Artistic Relationships Between Didactic and Concert Works. A portfolio of two 60-minute recitals and exegesis

Vol. 1 Audio recordings (currently unavailable) -- Vol. 2 ExegesisThis exegesis explores the ways in which composers Leo Brouwer, Abel Carlevaro, Mauro Giuliani, Fernando Sor and Heitor Villa-Lobos negotiate the relationship between technical decisions and artistic outcomes in their didactic and concert works for guitar. It is comprised of two chapters and three appendices. Chapter one outlines the conceptual framework, details the repertoire and composers selected for the study, key terms and concepts and includes a literature review. Chapter two contains five case-studies, each focused on one composer and is rounded out by a conclusion and three appendices containing programme notes from both recitals and an Étude Catalogue.Thesis (MPhil) -- University of Adelaide, Elder Conservatorium of Music, 202

CO(2) Diffusion in Polar Ice: Observations from Naturally Formed CO(2) Spikes in the Siple Dome (Antarctica) Ice Core

One common assumption in interpreting ice-core CO(2) records is that diffusion in the ice does not affect the concentration profile. However, this assumption remains untested because the extremely small CO(2) diffusion coefficient in ice has not been accurately determined in the laboratory. In this study we take advantage of high levels of CO(2) associated with refrozen layers in an ice core from Siple Dome, Antarctica, to study CO(2) diffusion rates. We use noble gases (Xe/Ar and Kr/Ar), electrical conductivity and Ca(2+) ion concentrations to show that substantial CO(2) diffusion may occur in ice on timescales of thousands of years. We estimate the permeation coefficient for CO(2) in ice is similar to 4 x 10(-21) mol m(-1) s(-1) Pa(-1) at -23 degrees C in the top 287 m (corresponding to 2.74 kyr). Smoothing of the CO(2) record by diffusion at this depth/age is one or two orders of magnitude smaller than the smoothing in the firn. However, simulations for depths of similar to 930-950m (similar to 60-70 kyr) indicate that smoothing of the CO(2) record by diffusion in deep ice is comparable to smoothing in the firn. Other types of diffusion (e.g. via liquid in ice grain boundaries or veins) may also be important but their influence has not been quantified

Controls on Millennial‐Scale Atmospheric CO2 Variability During the Last Glacial Period

Changes in atmospheric CO2 on millennial‐to‐centennial timescales are key components of past climate variability during the last glacial and deglacial periods (70‐10ka) yet the sources and mechanisms responsible for the CO2 fluctuations remain largely obscure. Here we report the 13C/12C ratio of atmospheric CO2 during a key interval of the last glacial period at sub‐millennial resolution, with coeval histories of atmospheric CO2, CH4 and N2O concentrations. The carbon isotope data suggest that the millennial‐scale CO2 variability in MIS3 is driven largely by changes in the organic carbon cycle, most likely by sequestration of respired carbon in the deep ocean. Centennial‐scale CO2 variations, distinguished by carbon isotope signatures, are associated with both abrupt hydrological change in the tropics (e.g. Heinrich Events) and rapid increases in northern hemisphere temperature (DO events). These events can be linked to modes of variability during the last deglaciation, thus suggesting that drivers of millennial and centennial CO2 variability during both periods are intimately linked to abrupt climate variability.National Science Foundatio