368 research outputs found
Competing charge density waves and temperature-dependent nesting in 2H-TaSe2
Multiple charge density wave (CDW) phases in 2H-TaSe2 are investigated by
high-resolution synchrotron x-ray diffraction. In a narrow temperature range
immediately above the commensurate CDW transition, we observe a multi-q
superstructure with coexisting commensurate and incommensurate order
parameters, clearly distinct from the fully incommensurate state at higher
temperatures. This multi-q ordered phase, characterized by a temperature
hysteresis, is found both during warming and cooling, in contrast to previous
reports. In the normal state, the incommensurate superstructure reflection
gives way to a broad diffuse peak that persists nearly up to room temperature.
Its position provides a direct and accurate estimate of the Fermi surface
nesting vector, which evolves non-monotonically and approaches the commensurate
position as the temperature is increased. This behavior agrees with our recent
observations of the temperature-dependent Fermi surface in the same compound
[Phys. Rev. B 79, 125112 (2009)]
Inelastic X-ray scattering studies of phonon dispersions in superconductors at high pressures
Electron-phonon interaction is of central importance for the electrical and
heat transport properties of metals, and is directly responsible for
charge-density-waves or (conventional) superconducting instabilities. The
direct observation of phonon dispersion anomalies across electronic phase
transitions can provide insightful information regarding the mechanisms
underlying their formation. Here, we review the current status of phonon
dispersion studies in superconductors under hydrostatic and uniaxial pressure.
Advances in the instrumentation of high resolution inelastic X-ray scattering
beamlines and pressure generating devices allow these measurements to be
performed routinely at synchrotron beamlines worldwide.Comment: 8 pages, 6 figures. Invited review submitted to Superconductor
Science and Technology, Focus issue on Hydride & High-Pressure
Superconductors. References in figure caption fixed. Hyperlinks adde
Phonon surface mapping of graphite: disentangling quasi--degenerate phonon dispersions
The two-dimensional mapping of the phonon dispersions around the point of
graphite by inelastic x-ray scattering is provided. The present work resolves
the longstanding issue related to the correct assignment of transverse and
longitudinal phonon branches at . We observe an almost degeneracy of the
three TO, LA and LO derived phonon branches and a strong phonon trigonal
warping. Correlation effects renormalize the Kohn anomaly of the TO mode, which
exhibits a trigonal warping effect opposite to that of the electronic band
structure. We determined the electron--phonon coupling constant to be
166 in excellent agreement to calculations. These results
are fundamental for understanding angle-resolved photoemission,
double--resonance Raman and transport measurements of graphene based systems
The phonon dispersion of graphite by inelastic x-ray scattering
We present the full in-plane phonon dispersion of graphite obtained from
inelastic x-ray scattering, including the optical and acoustic branches, as
well as the mid-frequency range between the and points in the Brillouin
zone, where experimental data have been unavailable so far. The existence of a
Kohn anomaly at the point is further supported. We fit a fifth-nearest
neighbour force-constants model to the experimental data, making improved
force-constants calculations of the phonon dispersion in both graphite and
carbon nanotubes available.Comment: 7 pages; submitted to Phys. Rev.
Framework for integrated dynamic thermal simulation of future civil transport aircraft
The development of increasingly more electric systems and ultra high bypass ratio turbofan engines for civil transport aircraft is projected to bring forth critical challenges regarding thermal management. To address these, it is required that the thermal behavior of the complete propulsion-airframe unit is studied in an integrated manner. To this purpose, a simulation framework for performing integrated thermal and performance analyses of the engines, airframe, and airframe systems, is presented. The framework was specifically devised to test novel integrated thermal management solutions for future civil aircraft. In this paper, the discussion focuses mainly on the thermal modeling of the wing and fuel. A highly flexible approach for creating wing thermal models by means of assembling generic thermal compartments is introduced. To demonstrate some of the capabilities, a case study is provided that involves thermal analysis of a single-aisle airplane with ultra high bypass ratio engines. Results are provided for fuel temperatures across flights in standard, hot, and cold days and for different airframe materials. Engine heat sink temperatures and input power to the engine gearboxes, both important parameters needed to design thermal management systems, are also presented
Evidence for anisotropic polar nanoregions in relaxor PMN: A neutron study of the elastic constants and anomalous TA phonon damping
We use neutron scattering to characterize the acoustic phonons in the relaxor
PMN and demonstrate the presence of an anisotropic damping mechanism directly
related to short-range, polar correlations. For a large range of temperatures
above Tc ~ 210, K, where dynamic polar correlations exist, acoustic phonons
propagating along [1\bar{1}0] and polarized along [110] (TA2 phonons) are
overdamped and softened across most of the Brillouin zone. By contrast,
acoustic phonons propagating along [100] and polarized along [001] (TA1
phonons) are overdamped and softened for only a limited range of wavevectors.
The anisotropy and temperature dependence of the acoustic phonon energy
linewidth are directly correlated with the elastic diffuse scattering,
indicating that polar nanoregions are the cause of the anomalous behavior. The
damping and softening vanish for q -> 0, i.e. for long-wavelength acoustic
phonons, which supports the notion that the anomalous damping is a result of
the coupling between the relaxational component of the diffuse scattering and
the harmonic TA phonons. Therefore, these effects are not due to large changes
in the elastic constants with temperature because the elastic constants
correspond to the long-wavelength limit. We compare the elastic constants we
measure to those from Brillouin scattering and to values reported for pure PT.
We show that while the values of C44 are quite similar, those for C11 and C12
are significantly less in PMN and result in a softening of (C11-C12) over PT.
There is also an increased elastic anisotropy (2C44/(C11-C12)) versus that in
PT. These results suggest an instability to TA2 acoustic fluctuations in
relaxors. We discuss our results in the context of the debate over the
"waterfall" effect and show that they are inconsistent with TA-TO phonon
coupling or other models that invoke the presence of a second optic mode.Comment: (21 pages, 16 figures, to be published in Physical Review B
The creation of modulated monoclinic aperiodic composites in n-alkane/urea compounds
Citation: Mariette, C., Guerin, L., Rabiller, P., Chen, Y. S., Bosak, A., Popov, A., . . . Toudic, B. (2015). The creation of modulated monoclinic aperiodic composites in n-alkane/urea compounds. Zeitschrift Fur Kristallographie, 230(1), 5-11. doi:10.1515/zkri-2014-1773n-Dodecane/urea is a member of the prototype series of n-alkane/urea inclusion compounds. At room temperature, it presents a quasi-one dimensional liquid-like state for the confined guest molecules within the rigid, hexagonal framework of the urea host. At lower temperatures, we report the existence of two other phases. Below T-c=248 K there appears a phase with rank four superspace group P6(1)22(00 gamma), the one typically observed at room temperature in n-alkane/urea compounds with longer guest molecules. A misfit parameter, defined by the ratio gamma=C-h/C-g (C-host/C-guest), is found to be 0.632 +/- 0.005. Below T-c1=123 K, a monoclinic modulated phase is created with a constant shift along c of the guest molecules in adjacent channels. The maximal monoclinic space group for this structure is P12(1)1(alpha 0 gamma). Analogies and differences with n-heptane/urea, which also presents a monoclinic, modulated low-temperature phase, are discussed
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