730 research outputs found

    Coupling of the lattice and superlattice deformations and hysteresis in thermal expansion for the quasi one-dimensional conductor TaS3_3

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    An original interferometer-based setup for measurements of length of needle-like samples is developed, and thermal expansion of o-TaS3_3 crystals is studied. Below the Peierls transition the temperature hysteresis of length LL is observed, the width of the hysteresis loop δL/L\delta L/L being up to 51055 \cdot 10^{-5}. The behavior of the loop is anomalous: the length changes so that it is in front of its equilibrium value. The hysteresis loop couples with that of conductivity. The sign and the value of the length hysteresis are consistent with the strain dependence of the charge-density waves (CDW) wave vector. With lowering temperature down to 100 K the CDW elastic modulus grows achieving a value comparable with the lattice Young modulus. Our results could be helpful in consideration of different systems with intrinsic superstructures.Comment: 4 pages, 3 figures. Phys. Rev. Lett., accepted for publicatio

    Contributions of spontaneous phase slippage to linear and non-linear conduction near the Peierls transition in thin samples of o-TaS_3

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    In the Peierls state very thin samples of TaS_3 (cross-section area \sim 10^{-3} mkm^2) are found to demonstrate smearing of the I-V curves near the threshold field. With approaching the Peierls transition temperature, T_P, the smearing evolves into smooth growth of conductance from zero voltage interpreted by us as the contribution of fluctuations to the non--linear conductance. We identify independently the fluctuation contribution to the linear conductance near T_P. Both linear and non-linear contributions depend on temperature with close activation energies \sim (2 - 4) x 10^3 K and apparently reveal the same process. We reject creep of the {\it continuous} charge-density waves (CDWs) as the origin of this effect and show that it is spontaneous phase slippage that results in creep of the CDW. A model is proposed accounting for both the linear and non-linear parts of the fluctuation conduction up to T_P.Comment: 6 pages, 5 Postscript figure, RevTeX, accepted for publication in PR

    Classical Density Functional Study on Interfacial Structure and Differential Capacitance of Ionic Liquids near Charged Surfaces

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    We have implemented a generic coarse-grained model for the aromatic ionic liquid [CnMIM+][Tf2N-]. Various lengths for the alkyl chain on the cation define a homologous series, whose electric properties are expected to vary in a systematic way. Within the framework of a classical density functional theory, the interfacial structures of members of this series are compared over a range of surface charge densities, alkyl chain lengths, and surface geometries. The differential capacitance of the electric double layer, formed by ionic liquids against a charged electrode, is calculated as a function of the surface electric potential. A comparison of planar, cylindrical, and spherical surfaces confirms that the differential capacitance increases and varies less with surface potential as the surface curvature increases. Our results are in qualitative agreement with recent atomistic simulations

    Meromorphic tensor equivalence for Yangians and quantum loop algebras

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    Let g{\mathfrak g} be a complex semisimple Lie algebra, and Yh(g)Y_h({\mathfrak g}), Uq(Lg)U_q(L{\mathfrak g}) the corresponding Yangian and quantum loop algebra, with deformation parameters related by q=exp(πih)q=\exp(\pi i h). When hh is not a rational number, we constructed in arXiv:1310.7318 a faithful functor Γ\Gamma from the category of finite-dimensional representations of Yh(g)Y_h ({\mathfrak g}) to those of Uq(Lg)U_q(L{\mathfrak g}). The functor Γ\Gamma is governed by the additive difference equations defined by the commuting fields of the Yangian, and restricts to an equivalence on a subcategory of Yh(g)Y_h({\mathfrak g}) defined by choosing a branch of the logarithm. In this paper, we construct a tensor structure on Γ\Gamma and show that, if q1|q|\neq 1, it yields an equivalence of meromorphic braided tensor categories, when Yh(g)Y_h({\mathfrak g}) and Uq(Lg)U_q(L{\mathfrak g}) are endowed with the deformed Drinfeld coproducts and the commutative part of the universal RR-matrix. This proves in particular the Kohno-Drinfeld theorem for the abelian qqKZ equations defined by Yh(g)Y_h({\mathfrak g}). The tensor structure arises from the abelian qqKZ equations defined by a appropriate regularisation of the commutative RR-matrix of Yh(g)Y_h({\mathfrak g}).Comment: Title changed, details added. 67 pages, 1 figure. Final version, to appear in Publ. Math IHE

    Quasiparticle interfacial level alignment of highly hybridized frontier levels: H2_2O on TiO2_2(110)

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    Knowledge of the frontier levels' alignment prior to photo-irradiation is necessary to achieve a complete quantitative description of H2_2O photocatalysis on TiO2_2(110). Although H2_2O on rutile TiO2_2(110) has been thoroughly studied both experimentally and theoretically, a quantitative value for the energy of the highest H2_2O occupied levels is still lacking. For experiment, this is due to the H2_2O levels being obscured by hybridization with TiO2_2(110) levels in the difference spectra obtained via ultraviolet photoemission spectroscopy (UPS). For theory, this is due to inherent difficulties in properly describing many-body effects at the H2_2O-TiO2_2(110) interface. Using the projected density of states (DOS) from state-of-the-art quasiparticle (QP) G0W0G_0W_0, we disentangle the adsorbate and surface contributions to the complex UPS spectra of H2_2O on TiO2_2(110). We perform this separation as a function of H2_2O coverage and dissociation on stoichiometric and reduced surfaces. Due to hybridization with the TiO2_2(110) surface, the H2_2O 3a1_1 and 1b1_1 levels are broadened into several peaks between 5 and 1 eV below the TiO2_2(110) valence band maximum (VBM). These peaks have both intermolecular and interfacial bonding and antibonding character. We find the highest occupied levels of H2_2O adsorbed intact and dissociated on stoichiometric TiO2_2(110) are 1.1 and 0.9 eV below the VBM. We also find a similar energy of 1.1 eV for the highest occupied levels of H2_2O when adsorbed dissociatively on a bridging O vacancy of the reduced surface. In both cases, these energies are significantly higher (by 0.6 to 2.6 eV) than those estimated from UPS difference spectra, which are inconclusive in this energy region. Finally, we apply self-consistent QPGWGW (scQPGWGW1) to obtain the ionization potential of the H2_2O-TiO2_2(110) interface.Comment: 12 pages, 12 figures, 1 tabl

    Stochastic averaging using elliptic functions to study nonlinear stochastic systems

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    In this paper, a new scheme of stochastic averaging using elliptic functions is presented that approximates nonlinear dynamical systems with strong cubic nonlinearities in the presence of noise by a set of Itô differential equations. This is an extension of some recent results presented in deterministic dynamical systems. The second order nonlinear differential equation that is examined in this work can be expressed as % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaWexLMBb50ujb% qeguuDJXwAKbacfiGaf8hEaGNbamaacqGHRaWkcaWGJbadcaaIXaGc% cqWF4baEcqGHRaWkcaWGJbadcaaIZaGccqWF4baEdaahaaWcbeqaai% aaiodaaaGccqGHRaWkcqaH1oqzcaWGMbGaaiikaiab-Hha4jaacYca% cqWFGaaicuWF4baEgaGaaiaacMcacqGHRaWkcqaH1oqzdaahaaWcbe% qaaiaaigdacaGGVaGaaGOmaaaaruWrL9MCNLwyaGGbcOGaa43zaiaa% cIcacqWF4baEcaGGSaGae8hiaaIaf8hEaGNbaiaacaGGSaGae8hiaa% IaeqOVdGNaaeikaiaadshacaqGPaGaaiykaiabg2da9iaaicdaaaa!645D![ddot x + c1x + c3x^3 + varepsilon f(x, dot x) + varepsilon ^{1/2} g(x, dot x, xi {text{(}}t{text{)}}) = 0] where c 1 and c 3 are given constants, ξ( t ) is stationary stochastic process with zero mean and ε≪1 is a small parameter. This method involves the laborious manipulation of Jacobian elliptic functions such as cn, dn and sn rather than the usual trigonometric functions. The use of a symbolic language such as Mathematica reduces the computational effort and allows us to express the results in a convenient form. The resulting equations are Markov approximations of amplitude and phase involving integrals of elliptic functions. Finally, this method was applied to study some standard second order systems.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/43328/1/11071_2004_Article_BF00120672.pd

    Спектр изменений внутрисуставных структур при гемофилической артропатии по данным магнитно-резонансной томографии

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    The results of joints's magnetic resonance imaging of 10 patients with severe form of hemophilic artropathy are discussing in this article. The purpose of research was to study the state of soft tissue and bone intraarticulare's structures in present group of patients. The form of bones, condition of an articulate cartilage, the joint’s tendons and ligaments, synovium, presence of an intraarticulate exudate, presence and extent of adjournment haemosiderin, and also signal characteristics of a marrow were estimated.В статье обсуждаются результаты магнитно-резонансной томографии суставов у 10 больных гемофилической артропатией с тяжелой формой заболевания. Исследование проводилось с целью детального изучения состояния мягкотканных и костных внутрисуставных структур у данной группы пациентов. Оценивались форма костей, состояние суставного хряща, сухожильно-связочного аппарата, синовия, определялось наличие внутрисуставного выпота, наличие и протяженность отложения гемосидерина, а также сигнальные характеристики костного мозга

    Separating Semantic and Circular Security for Symmetric-Key Bit Encryption from the Learning with Errors Assumption

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    In this work we separate private-key semantic security from circular security using the Learning with Error assumption. Prior works used the less standard assumptions of multilinear maps or indistinguishability obfuscation. To achieve our results we develop new techniques for obliviously evaluating branching programs

    Magnetic shielding accelerates the proliferation of human neuroblastoma cell by promoting G1-phase progression

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    Organisms have been exposed to the geomagnetic field (GMF) throughout evolutionary history. Exposure to the hypomagnetic field (HMF) by deep magnetic shielding has recently been suggested to have a negative effect on the structure and function of the central nervous system, particularly during early development. Although changes in cell growth and differentiation have been observed in the HMF, the effects of the HMF on cell cycle progression still remain unclear. Here we show that continuous HMF exposure significantly increases the proliferation of human neuroblastoma (SH-SY5Y) cells. The acceleration of proliferation results from a forward shift of the cell cycle in G1-phase. The G2/M-phase progression is not affected in the HMF. Our data is the first to demonstrate that the HMF can stimulate the proliferation of SH-SY5Y cells by promoting cell cycle progression in the G1-phase. This provides a novel way to study the mechanism of cells in response to changes of environmental magnetic field including the GMF
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