Two-color polarization control on angularly resolved attosecond time delays

Measured photoionization time delays may exhibit large variations as a function of the emission angles, even for spherically symmetric targets, as shown in recent RABBITT (reconstruction of attosecond beating by interference of two-photon transitions) experiments. The contributions from different pathways to the two-photon quantum channels can already explain the observed phase jumps that shape those angular distributions. Here, we propose a simple analytical model to describe angularly-resolved RABBITT spectra as a function of the relative polarization angle between the ionizing attosecond pulse train and the assisting IR field. We demonstrate that the angular dependencies of the measured delays can be analytically predicted and the position of the phase jumps reduced to the analysis of a few relevant parameters.Comment: 10 pages, 4 figure

Time-Resolved Measurement of Interatomic Coulombic Decay in Ne_2

The lifetime of interatomic Coulombic decay (ICD) [L. S. Cederbaum et al., Phys. Rev. Lett. 79, 4778 (1997)] in Ne_2 is determined via an extreme ultraviolet pump-probe experiment at the Free-Electron Laser in Hamburg. The pump pulse creates a 2s inner-shell vacancy in one of the two Ne atoms, whereupon the ionized dimer undergoes ICD resulting in a repulsive Ne^{+}(2p^{-1}) - Ne^{+}(2p^{-1}) state, which is probed with a second pulse, removing a further electron. The yield of coincident Ne^{+} - Ne^{2+} pairs is recorded as a function of the pump-probe delay, allowing us to deduce the ICD lifetime of the Ne_{2}^{+}(2s^{-1}) state to be (150 +/- 50) fs in agreement with quantum calculations.Comment: 5 pages, 3 figures, accepted by PRL on July 11th, 201

Risk Assessment of Erosion from Concentrated Flow on Rangelands Using Overland Flow Distribution and Shear Stress Partitioning

Erosion rates of overland flow on rangelands tend to be relatively low, but under certain conditions where flow is concentrated, soil loss can be significant. Therefore, a rangeland site can be highly vulnerable to soil erosion where overland flow is likely to concentrate and exert high shear stress on soil grains. This concept is commonly applied in cropland and wildland soil erosion modeling using predictions of flow effective shear stress (shear stress applied on soil grains). However, historical approaches to partition shear stress in erosion models are computationally complex and require extensive parameterization. Furthermore, most models are not capable of predicting the conditions in which concentrated flow occurs on rangelands. In this study, we investigated the rangelands conditions at which overland flow is more likely to become concentrated and developed equations for partitioning the shear stress of concentrated flow on rangelands. A logistic equation was developed to estimate the probability of overland flow to become concentrated. Total shear stress of rangeland overland flow was partitioned into components exerted on soil, vegetation, and rock cover using field experimental data. In addition, we investigated the vegetation cover limit at which the effective shear stress component is substantially reduced, limiting the erosion rate. The results from the partitioning equations show that shear stress exerted on soil grains was relatively small in sheet flow. Shear stress exerted on soil grains in concentrated flow was significantly higher when bare soil exceeded 60% of the total surface area but decreased significantly when the bare soil area was less than 25% or when the plant base cover exceeded 20%. These percentages could be used as relative measures of hydrologic recovery for disturbed rangelands or as triggers that indicate a site is crossing a threshold beyond which soil erosion might accelerate due to the high effective shear stress

Concentrated Flow Erodibility for Physically Based Erosion Models: Temporal Variability in Disturbed and Undisturbed Rangelands

Current physically based overland flow erosion models for rangeland application do not separate disturbed and undisturbed conditions in modeling concentrated flow erosion. In this study, concentrated flow simulations on disturbed and undisturbed rangelands were used to estimate the erodibility and to evaluate the performance of linear and power law equations that describe the relationship between erosion rate and several hydraulic parameters. None of the hydraulic parameters consistently predicted the detachment capacity well for all sites, however, stream power performed better than most of other hydraulic parameters. Using power law functions did not improve the detachment relation with respect to that of the linear function. Concentrated flow erodibility increased significantly when a site was exposed to a disturbance such as fire or tree encroachment into sagebrush steppe. This study showed that burning increases erosion by amplifying the erosive power of overland flow through removing obstacles and by changing the soil properties affecting erodibility itself. However, the magnitude of fire impact varied among sites due to inherent differences in site characteristics and variability in burn severity. In most cases we observed concentrated flow erodibility had a high value at overland flow initiation and then started to decline with time due to reduction of sediment availability. Thus we developed an empirical function to predict erodibility variation within a runoff event as a function of cumulative unit discharge. Empirical equations were also developed to predict erodibility variation with time postdisturbance as a function of readily available vegetation cover and surface soil texture data

Coupled motion of Xe clusters and quantum vortices in He nanodroplets

Citation: Jones, C. F., Bernando, C., Tanyag, R. M. P., Bacellar, C., Ferguson, K. R., Gomez, L. F., . . . Vilesov, A. F. (2016). Coupled motion of Xe clusters and quantum vortices in He nanodroplets. Physical Review B - Condensed Matter and Materials Physics, 93(18). doi:10.1103/PhysRevB.93.180510Additional Authors: Erk, B.;Foucar, L.;Hartmann, R.;Neumark, D. M.;Epp, S. W.;Englert, L.;Siefermann, K. R.;Weise, F.;Rudek, B.;Sturm, F. P.;Ullrich, J.;Bostedt, C.;Gessner, O.;Vilesov, A. F.Single He nanodroplets doped with Xe atoms are studied via ultrafast coherent x-ray diffraction imaging. The diffraction images show that rotating He nanodroplets about 200 nm in diameter contain a small number of symmetrically arranged quantum vortices decorated with Xe clusters. Unexpected large distances of the vortices from the droplet center (?0.7-0.8 droplet radii) are explained by a significant contribution of the Xe dopants to the total angular momentum of the droplets and a stabilization of widely spaced vortex configurations by the trapped Xe clusters. © 2016 American Physical Society

Оценка эффективности управления деятельностью предприятия

Целью исследования является оценка эффективности управления деятельностью предприятия как интегрального показателя, то есть управления совокупностью деятельностей, таких как производственная, инвестиционная, инновационная, маркетинговая и финансовая

Tracking the ultraviolet-induced photochemistry of thiophenone during and after ultrafast ring opening

Photoinduced isomerization reactions lie at the heart of many chemical processes in nature. The mechanisms of such reactions are determined by a delicate interplay of coupled electronic and nuclear dynamics occurring on the femtosecond scale, followed by the slower redistribution of energy into different vibrational degrees of freedom. Here we apply time-resolved photoelectron spectroscopy with a seeded extreme ultraviolet free-electron laser to trace the ultrafast ring opening of gas-phase thiophenone molecules following ultraviolet photoexcitation. When combined with ab initio electronic structure and molecular dynamics calculations of the excited- and ground-state molecules, the results provide insights into both the electronic and nuclear dynamics of this fundamental class of reactions. The initial ring opening and non-adiabatic coupling to the electronic ground state are shown to be driven by ballistic S–C bond extension and to be complete within 350 fs. Theory and experiment also enable visualization of the rich ground-state dynamics that involve the formation of, and interconversion between, ring-opened isomers and the cyclic structure, as well as fragmentation over much longer timescales