Magnetocaloric effect in Gd/W thin film heterostructures

In an effort to understand the impact of nanostructuring on the magnetocaloric effect, we have grown and studied gadolinium in MgO/W(50 $\textrm{\AA}$)/[Gd(400 $\textrm{\AA}$)/W(50 $\textrm{\AA}$)]$_8$ heterostructures. The entropy change associated with the second order magnetic phase transition was determined from the isothermal magnetization for numerous temperatures and the appropriate Maxwell relation. The entropy change peaks at a temperature of 284 K with a value of approximately 3.4 J/kg-K for a 0-30 kOe field change; the full width at half max of the entropy change peak is about 70 K, which is significantly wider than that of bulk Gd under similar conditions. The relative cooling power of this nanoscale system is about 240 J/kg, somewhat lower than that of bulk Gd (410 J/kg). An iterative Kovel-Fisher method was used to determine the critical exponents governing the phase transition to be $\beta=0.51$, and $\gamma=1.75$. Along with a suppressed Curie temperature relative to the bulk, the fact that the convergent value of $\gamma$ is that predicted by the 2-D Ising model may suggest that finite size effects play an important role in this system. Together, these observations suggest that nanostructuring may be a promising route to tailoring the magnetocaloric response of materials

Photovoice and photodocumentary for enhancing community partner engagement and student learning in a public health field school in Cape Town

Background: Field school research, which begins by considering community partners as pedagogues and thus exploring their perspectives on student learning, is uncommon. Photovoice is a method for self-expression of such marginalized voices. Purpose: Describe the photovoice to photodocumentary process and present results of its evaluation. Methodology/Approach: We employed photovoice with the local guides who accompany community health research field school students in Cape Town. Guides were prompted to take photographs of what students may not see or understand about their community. These were discussed at three workshops and developed into a photodocumentary for inclusion in the curriculum. Twenty-one students completed an open-ended questionnaire. These, and student/staff discussions, were thematically analyzed. Findings/Conclusion: Students reported learning about cultural practices which otherwise would not be visible to them. They felt greater connection to their guides who they saw in a new light, and became aware of how topic-specificity drew attention away from overarching characteristics of community life. Questions raised might be better explored through facilitated discussion rather than question-and-answer sessions alone. Implications: Field schools depend on academic–community partnerships. Photovoice can create space for community partner reflection on student learning and the co-creation of effective pedagogical tools valued by students

The origin of the red luminescence in Mg-doped GaN

Optically-detected magnetic resonance (ODMR) and positron annihilation spectroscopy (PAS) experiments have been employed to study magnesium-doped GaN layers grown by metal-organic vapor phase epitaxy. As the Mg doping level is changed, the combined experiments reveal a strong correlation between the vacancy concentrations and the intensity of the red photoluminescence band at 1.8 eV. The analysis provides strong evidence that the emission is due to recombination in which electrons both from effective mass donors and from deeper donors recombine with deep centers, the deep centers being vacancy-related defects.Comment: 4 pages, 3 figure

Distributed Order Derivatives and Relaxation Patterns

We consider equations of the form $(D_{(\rho)}u)(t)=-\lambda u(t)$, $t>0$, where $\lambda >0$, $D_{(\rho)}$ is a distributed order derivative, that is the Caputo-Dzhrbashyan fractional derivative of order $\alpha$, integrated in $\alpha\in (0,1)$ with respect to a positive measure $\rho$. Such equations are used for modeling anomalous, non-exponential relaxation processes. In this work we study asymptotic behavior of solutions of the above equation, depending on properties of the measure $\rho$

Ba(OH)(2) - blast furnace slag composite binders for encapsulation of sulphate bearing nuclear waste

The present study investigated the feasibility of the immobilisation of sulphate bearing radioactive wastes in blast furnace slag (BFS) based binders. BaSO4–BFS composites were produced via two methods using Na2SO4 as a waste simulant, along with Ba(OH)2 to promote precipitation of BaSO4 in an insoluble sulphate form and the consequent activation of the BFS. BaSO4 was effectively formed by both methods, and solid wasteforms were successfully produced. Although both methods produced BaSO4 embedded in the cement-like composites, different reaction products including ettringite and witherite were produced, depending on the order Ba(OH)2 was mixed with the system. These results show that the immobilisation of soluble sulphate-bearing aqueous wastes is achievable in Na2SO4–Ba(OH)2–BFS composites

Communication: Non-monotonic supersaturation dependence of the nucleus size of crystals with anisotropically interacting molecules.

We study the nucleation of model two-dimensional crystals formed from anisotropically interacting molecules using kinetic Monte Carlo simulations and the forward flux sampling algorithm. The growth probability P(n) of a cluster of n molecules is measured while the supersaturation s and interaction anisotropy of the molecules are varied, in order to gain insight into the nucleation mechanism. It is found that with increasing degree of interaction anisotropy the nucleus size (defined as the cluster size at which P(n) = 0.5) can increase with increasing s, with sharp jumps at certain s values. Analysis of the cluster shape reveals that nucleation in the system studied is of a non-standard form, in that it embodies elements of both the classical nucleation theory and the density functional theory frameworks

Brownian Motion in wedges, last passage time and the second arc-sine law

We consider a planar Brownian motion starting from $O$ at time $t=0$ and stopped at $t=1$ and a set $F= \{OI_i ; i=1,2,..., n\}$ of $n$ semi-infinite straight lines emanating from $O$. Denoting by $g$ the last time when $F$ is reached by the Brownian motion, we compute the probability law of $g$. In particular, we show that, for a symmetric $F$ and even $n$ values, this law can be expressed as a sum of $\arcsin$ or $(\arcsin)^2$ functions. The original result of Levy is recovered as the special case $n=2$. A relation with the problem of reaction-diffusion of a set of three particles in one dimension is discussed

The magnetic properties of 177^{\rm 177}Hf and 180^{\rm 180}Hf in the strong coupling deformed model

This paper reports NMR measurements of the magnetic dipole moments of two high-K isomers, the 37/2$^-$, 51.4 m, 2740 keV state in $^{\rm 177}$Hf and the 8$^-$, 5.5 h, 1142 keV state in $^{\rm 180}$Hf by the method of on-line nuclear orientation. Also included are results on the angular distributions of gamma transitions in the decay of the $^{\rm 177}$Hf isotope. These yield high precision E2/M1 multipole mixing ratios for transitions in bands built on the 23/2$^+$, 1.1 s, isomer at 1315 keV and on the 9/2$^+$, 0.663 ns, isomer at 321 keV. The new results are discussed in the light of the recently reported finding of systematic dependence of the behavior of the g$_{\rm R}$ parameter upon the quasi-proton and quasi-neutron make up of high-K isomeric states in this region.Comment: 9 pages, 9 figures, accepted for publication in Physical Review