Mechanical and microstructural characterization of MCrAlY coatings produced by laser cladding: The influence of the Ni, Co and Al content

[EN] Laser metal deposition (LMD) and laser cladding (LC) are alternative methods to thermal spraying processes to produce dense, high-quality coatings. In this work, two MCrAlY coatings (M=Ni+Co) have been prepared onto stainless steel substrate using a coaxial LC technique under two different Ni/Co and Al proportions. The mechanical properties were then evaluated with microhardness, nanoindentation, and three-point bending tests. The microstructure and composition of coatings were characterized by X-ray Diffraction (XRD) analysis and Field Emission Electron Microscopy (FESEM) coupled to an Energy Dispersive Spectroscopy (EDS) detector. The study revealed that the ¿/ß phases formed in the MCrAlY coating microstructure result in a lower elastic modulus than the austenitic stainless steel substrate, while an inverse behavior for hardness was observed due the presence of the aluminum-rich ß-phase. Under flexural loads, the failure of coatings showed plasticity and anisotropy characteristics depending on the two laser tracks orientations evaluated.The authors would like to acknowledge the financial support of the Ministry of Science and Innovation of the Government of Spain through research project MAT2011-28492-C03, and the support of the Generalitat Valenciana through ACOMP/2013/114Pereira, JC.; Zambrano, JC.; Rayón, E.; Yañez, A.; Amigó, V. (2018). Mechanical and microstructural characterization of MCrAlY coatings produced by laser cladding: The influence of the Ni, Co and Al content. Surface and Coatings Technology. 338:22-31. https://doi.org/10.1016/j.surfcoat.2018.01.073S223133

Towards a Framework for Understanding Fairtrade Purchase Intention in the Mainstream Environment of Supermarkets

© 2014, Springer Science+Business Media Dordrecht. Despite growing interest in ethical consumer behaviour research, ambiguity remains regarding what motivates consumers to purchase ethical products. While researchers largely attribute the growth of ethical consumerism to an increase in ethical consumer concerns and motivations, widened distribution (mainstreaming) of ethical products, such as fairtrade, questions these assumptions. A model that integrates both individual and societal values into the theory of planned behaviour is presented and empirically tested to challenge the assumption that ethical consumption is driven by ethical considerations alone. Using data sourced from fairtrade shoppers across the UK, structural equation modelling suggests that fairtrade purchase intention is driven by both societal and self-interest values. This dual value pathway helps address conceptual limitations inherent in the underlying assumptions of existing ethical purchasing behaviour m odels and helps advance understanding of consumers’ motivation to purchase ethical products

Anticoagulation régionale au citrate pour l’épuration extrarénale continue [Regional citrate anticoagulation for continuous renal replacement therapy]

Regional citrate anticoagulation (RCA) is currently the recommended anticoagulation modality for continuous renal replacement therapy. Indeed, compared with systemic heparinization, RCA is associated with a lower risk of bleeding, a longer circuit lifespan and a decrease nursing workload. However, RCA requires a strict protocol to be followed, as it might be associated with potentially severe complications, such as citrate accumulation. Citrate accumulation is rare and usually associated with specific situations : severe circulatory shock, liver failure and mitochondrial dysfunction. According to centers' expertise, these situations might represent contra-indications to RCA. This review presents RCA, its mode of action, associated risks and proposes an algorithm for patients' selection

Starving the Newsfeed for Social Media Detox: Effects of Strict and Self-regulated Facebook Newsfeed Diets

Article 19

Ethical consumption and new business models in the food industry. Evidence from the Eataly case

Individual and collective ethical stances regarding ethical consumption and related outcomes are usually seen as both a form of concern about extant market offerings and as opportunities to develop new offerings. In this sense, demand and supply are traditionally portrayed as interacting dialectically on the basis of extant business models. In general, this perspective implicitly assumes the juxtaposition of demand side ethical stances and supply side corporate initiatives. The Eataly story describes, however, a different approach to market transformation; in this case a company and a social movement (Slow Food) have negotiated and collaborated prior to initiating a new business model. This collaboration process and its outcomes are described, focusing specifically on ordinary Eataly customers\u2019 and Slow Food members\u2019 reactions. Given that Eataly can be regarded as a case of mainstreaming, ordinary customers seem satisfied with the new offering and the Slow Food support for the initiative; the more purist members of the Slow Food movement had critical concerns, however, as happened in similar conditions, according to literature, with regard to Fair Trade. The Slow Food endorsement of the new venture has also been observed from the attitude\u2013behaviour gap perspective, as it contributed to addressing the factors affecting the gap between attitudes and actual behaviours. Extensive qualitative data were collected and analysed over a 3-year period. The main study implications refer to the ways in which companies and social movements could interact to co-design new business models, as well as outlining consumers\u2019attitudes and behaviours towards such new offerings

Willingness to reduce food choice in favour of sustainable alternatives: the role of government and consumer behaviour

Despite greater emphasis being placed on research into ethical consumer behaviour, there is still no clear view of the magnitude of willingness to reduce food choices in favour of sustainable alternatives (WTRFCIFOSA), while the role of government is also under the microscope, more specifically how willing it is to take the initiative in keeping only organic food on the shelves. This study advances a new concept by theorising “willingness to reduce food choices for sustainable alternatives”. The concept emerged from assessing consumer behaviour, ethical attributes, health attributes, and the roles played by both government and food producers in relation to naturalness. It is theorised that WTRFCIFOSA would lead to the consumption of natural and organic food. At present, consumers themselves have no willingness to switch to organic consumption. Moreover, ethical and health attributes, government, and food producers have no significant impact on convincing consumers to opt for organic/natural food. It is therefore suggested that governments should introduce the concept of mandatory consumption of sustainable alternatives by reducing the range of unnatural and less ethical food choices for consumers, because naturalness is a significant moderator in the process