Late Cenozoic metamorphic evolution and exhumation of Taiwan

The Taiwan mountain belt is composed of a Cenozoic slate belt (Hsuehshan Range units, HR, and Backbone Slates, BS) and of accreted polymetamorphic basement rocks (Tananao Complex, TC). Ongoing crustal shortening has resulted from the collision between the Chinese continental margin and the Luzon volcanic arc, which initiated ~6.5 Ma ago. The grade and age of metamorphism and exhumation are a key record of the development of the orogenic wedge. Because the Taiwan mountain belt is mostly composed by accreted sediments lacking metamorphic index minerals, quantitative constraints on metamorphism are sparse. By contrast, these rocks are rich in carbonaceaous material (CM) and are therefore particularly appropriate for RSCM (Raman Spectroscopy of CM) thermometry. We apply this technique in addition to (U-Th)/He thermochronology on detrital zircons to assess peak metamorphic temperatures (T) and the late exhumational history respectively, along different transects in central and southern Taiwan. In the case of the HR units, we find evidence for high metamorphic T of at least 340°–350°C and locally up to 475°C, and for relative rapid exhumation with zircon (U-Th)/He ages in the range of 1.5–2 Ma. Farther east, the BS were only slightly metamorphosed (T < 330 °C), and zircons are not reset for (U-Th)/He. From the eastern BS to the inner TC schists, T gradually increases from ~350°C up to ~500°C following an inverted metamorphic gradient. Available geochronological constraints and the continuous thermal gradient from the BS to the basement rocks of the TC suggest that the high RSCM T of the TC were most probably acquired during the last orogeny, and were not inherited from a previous thermal event. Zircons yield (U-Th)/He ages of ~0.5–1.2 Ma. Peak metamorphic T and the timing of exhumation do not show along-strike variations over the TC in the studied area. In contrast, exhumation is laterally diachronous and decreases southward in the case of the HR units. In particular, our data imply that the HR units have been exhumed by a minimum of 15 km over the last few Ma. In the case of the BS, they show far less cumulated exhumation and much slower cooling rates. We propose that most of the deformation and exhumation of the Taiwan mountain belt is sustained through two underplating windows located beneath the Hsuehshan Range and the TC. Our data show significant departures from the predictions of the prevailing model in Taiwan, which assumes a homogeneous critical wedge with dominant frontal accretion. Our study sheds new light on how the mountain belt has grown as a possible result of underplating mostly

Can shed snakeskin be considered to be a model membrane for human stratum corneum?

Recently there has been some interest in the use of shed snake skin as a "model" membrane for in vitro diffusion studies. Many different species of snake have been utilised as well as different skin sites (dorsal and ventral). The species is usually named and sometimes the skin site is indicated butsometimes neither species nor skin site is reported. Insome countries it is particularly difficult to obtain human skin for in vitro experimentation and it is therefore important to have alternate biological or synthetic membranes which mimic human skin membranes for diffusion experiments. In South Africa. shed snake skin is easily obtainable from the many snake parks present in the country. Since snakes moult periodically, a single animal can provide repeated sheds, thus reducing interindividual variability. Skins can be obtained without injury to the animal and do not have to be subjected to chemical or heat stress prior to use. The epidermis is shed as a large intact sheet, thus a single snake skin can provide multiple samples. Shed snake skin is not a living tissue, can be stored for long periods at room temperature and is easily transported. Stored and fresh snake skins appear to show no differences in permeability. Since snake skin lacks hair follicles,the problems associated with the transfollicular route of penetration, which may be significant in mammalian skins, can be avoided

Thermal structure and exhumation history of the Lesser Himalaya in central Nepal

The Lesser Himalaya (LH) consists of metasedimentary rocks that have been scrapped off from the underthrusting Indian crust and accreted to the mountain range over the last ~20 Myr. It now forms a significant fraction of the Himalayan collisional orogen. We document the kinematics and thermal metamorphism associated with the deformation and exhumation of the LH, combining thermometric and thermochronological methods with structural geology. Peak metamorphic temperatures estimated from Raman spectroscopy of carbonaceous material decrease gradually from 520°–550°C below the Main Central Thrust zone down to less than 330°C. These temperatures describe structurally a 20°–50°C/km inverted apparent gradient. The Ar muscovite ages from LH samples and from the overlying crystalline thrust sheets all indicate the same regular trend; i.e., an increase from about 3–4 Ma near the front of the high range to about 20 Ma near the leading edge of the thrust sheets, about 80 km to the south. This suggests that the LH has been exhumed jointly with the overlying nappes as a result of overthrusting by about 5 mm/yr. For a convergence rate of about 20 mm/yr, this implies underthrusting of the Indian basement below the Himalaya by about 15 mm/yr. The structure, metamorphic grade and exhumation history of the LH supports the view that, since the mid-Miocene, the Himalayan orogen has essentially grown by underplating, rather than by frontal accretion. This process has resulted from duplexing at a depth close to the brittle-ductile transition zone, by southward migration of a midcrustal ramp along the Main Himalayan Thrust fault, and is estimated to have resulted in a net flux of up to 150 m^2/yr of LH rocks into the Himalayan orogenic wedge. The steep inverse thermal gradient across the LH is interpreted to have resulted from a combination of underplating and post metamorphic shearing of the underplated units

In vitro permeation of progesterone from a gel through the shed skin of three different snake species

The in vitro diffusion of progesterone from a gel formulation using the European Pharmacopoeia method for transdermal dosage forms is described. The membranes used were the dorsal and ventral portions of the shed skin of three different species of snake. Considerable differences are apparent between the dorsal and ventral sites and between the different species of snake. The dorsal area shows better permeability for progesterone and the permeability order for the different species is python>cobra>viper. These differences may be due to the thickness of the skin and the hinge:scale ratio. The results indicate that shed snake skin is not a model membrane for human skin

Evolution of the macromolecular structure of sporopollenin during thermal degradation

AbstractReconstructing the original biogeochemistry of organic microfossils requires quantifying the extent of the chemical transformations they experienced during burial and maturation processes. In the present study, fossilization experiments have been performed using modern sporopollenin chosen as an analogue for the resistant biocompounds possibly constituting the wall of many organic microfossils. Sporopollenin powder has been processed thermally under argon atmosphere at different temperatures (up to 1000 °C) for varying durations (up to 900 min). Solid residues of each experiment have been characterized using infrared, Raman and synchrotron-based XANES spectroscopies. Results indicate that significant defunctionalisation and aromatization affect the molecular structure of sporopollenin with increasing temperature. Two distinct stages of evolution with temperature are observed: in a first stage, sporopollenin experiences dehydrogenation and deoxygenation simultaneously (below 500 °C); in a second stage (above 500 °C) an increasing concentration in aromatic groups and a lateral growth of aromatic layers are observed. With increasing heating duration (up to 900 min) at a constant temperature (360 °C), oxygen is progressively lost and conjugated carbon–carbon chains or domains grow progressively, following a log-linear kinetic behavior. Based on the comparison with natural spores fossilized within metasediments which experienced intense metamorphism, we show that the present experimental simulations may not perfectly mimic natural diagenesis and metamorphism. Yet, performing such laboratory experiments provides key insights on the processes transforming biogenic molecules into molecular fossils

L'UNASUR : modèle de démocratisation et d'intégration en Amérique du Sud

À une époque où l'internationalisation des échanges est primordiale, l'Union sud-américaine de Nations (UNASUR) semble déployer une certaine capacité de négociation collective et peser davantage sur les processus de décision au sein des institutions internationales. À travers les dynamiques d'intégration régionale, l'UNASUR développe une nouvelle forme « d'interdépendance » à un niveau sud-américain. Les gouvernements s'engagent à faire face aux conflits associés aux intérêts de chacun des pays. L'intégration continentale de l'UNASUR ne peut se maintenir que si les gouvernements assument leurs divergences et se dirigent vers une coalition « post nationale » et démocratique. Ces acteurs sont témoins de la crise de la représentation politique et évoquent une nouvelle dynamique démocratique encadrant les mouvements sociaux et les gouvernements dans un rapport coopératifs. L'UNASUR s'inscrit dans un contexte particulier, dans la construction inédite d'une nouvelle Amérique du Sud, à un moment où la plupart des pays prennent un tournant démocratique, un virage à gauche. Alors que la communauté internationale assiste à l'impulsion et l'intégration politique, économique et infrastructurelle d'une grande partie sud-américaine, comment expliquer ce tournant « démocratique »? Quels sont les espoirs que ces différents pays suscitent? Le sous-continent est aux prises avec de multiples défis. La construction d'une démocratie capable de palier aux inégalités criantes, aux violences, aux frustrations sociales, culturelles et identitaires dans un milieu aussi vulnérable est de mise. Le virage à gauche de la plupart des pays est certes un basculement politique important dans l'histoire sud-américaine; cependant, il reflète le poids de la précarité sociale, politique et institutionnelle du sous-continent. Nous étudierons tout au long de ce mémoire les gouvernements sud-américains qui tendent à réunir la puissance productive des différents peuples et réinventent les institutions au-delà de l'État. L'UNASUR exige des gouvernements le maintien des relations ouvertes et démocratiques. Les institutions naissantes matérialisent les relations diplomatiques entre les gouvernements, mais aussi des relations sociales et culturelles avec les peuples. La démocratisation en Amérique latine et la création de l'UNASUR sont l'affirmation d'une nouvelle politique. Les acteurs politiques sont témoins de la crise de la représentation politique et évoquent une nouvelle dynamique démocratique encadrant les mouvements sociaux et les gouvernements dans un rapport capital. La réussite de cette union laisserait penser que le rêve d'une alternative démocratique est possible dans la reconstruction politique, sociale et économique de l'Amérique du Sud. \ud ______________________________________________________________________________ \ud MOTS-CLÉS DE L’AUTEUR : intégration sud-américaine, mondialisation, impérialisme, néolibéralisme, socialisme, mouvements sociaux, reconnaissance des identités, populisme

Diachronous evolution of the alpine continental subduction wedge: evidence from P-T estimates in the Briançonnais Zone houillère (France - Western Alps).

International audienceThe study of continental subduction processes requires detailed Pressure Temperature (P-T) paths to understand the kinematic of burial and exhumation of continental units. In the French Western Alps, the Briançonnais zone is a remnant of the continental subduction wedge. P-T conditions have been estimated in its most internal parts, but there is a lack of data in the western part, known as the "Zone houillère". This Briançonnais Zone houillère is classically divided into two sub-units: the upper and lower Houiller units. This study focuses on both of these in the Clarée valley, north of Briançon. In this low-grade metamorphic terrain, estimation of P-T history is complicated because there are few adapted methods and these rocks have a poor metamorphic mineralogical content, including detrital metamorphic minerals inherited from their hercynian history. Therefore, to acquire accurate P-T estimates a multi-method approach is required, involving qualitative and quantitative Raman study of Carbonaceous Material (RSCM), chemical analysis from quantified X-ray maps and thermodynamic modelling of chlorites and K-white micas. Such multi-approach P-T estimates on a sandstone sample allow distinguishing hercynian peak metamorphic conditions of 371 ± 26°C and 3.5 ± 1.4 kbar and alpine peak metamorphic conditions of 275 ± 23°C and 5.9 ± 1.7 kbar. These results are consistent with our RSCM and Tmax estimates. Raman study conducted on organic-rich schist samples shows an eastward increase of the alpine Tmax in the upper Houiller unit, from 280 to 300°C across the Briançonnais Zone houillère. In contrast, carbonaceous material included in detrital grains of muscovite in the sandstone exhibits higher temperatures. This hercynian Tmax is estimated using thermodynamic modelling at 376 ± 50°C. According to these results and previous work in more internal parts of the Briançonnais zone, a geodynamic reconstruction is proposed, which is characterized by a diachronous evolution of the Briançonnais zone involved in alpine continental subduction at different times. The geothermal gradient in the Briançonnais zone changes from 8°C/km during early continental subduction, to 40°C/km during the collisional event at about 35-30 Ma. The intermediate gradient of 15°C/km estimated in the Briançonnais Zone houillère suggests that this unit was buried later, than the more internal Briançonnais units, after 40 Ma