329 research outputs found
Wall slip and flow of concentrated hard-sphere colloidal suspensions
We present a comprehensive study of the slip and flow of concentrated
colloidal suspensions using cone-plate rheometry and simultaneous confocal
imaging. In the colloidal glass regime, for smooth, non-stick walls, the solid
nature of the suspension causes a transition in the rheology from
Herschel-Bulkley (HB) bulk flow behavior at large stress to a Bingham-like slip
behavior at low stress, which is suppressed for sufficient colloid-wall
attraction or colloid-scale wall roughness. Visualization shows how the
slip-shear transition depends on gap size and the boundary conditions at both
walls and that partial slip persist well above the yield stress. A
phenomenological model, incorporating the Bingham slip law and HB bulk flow,
fully accounts for the behavior. Microscopically, the Bingham law is related to
a thin (sub-colloidal) lubrication layer at the wall, giving rise to a
characteristic dependence of slip parameters on particle size and
concentration. We relate this to the suspension's osmotic pressure and yield
stress and also analyze the influence of van der Waals interaction. For the
largest concentrations, we observe non-uniform flow around the yield stress, in
line with recent work on bulk shear-banding of concentrated pastes. We also
describe residual slip in concentrated liquid suspensions, where the vanishing
yield stress causes coexistence of (weak) slip and bulk shear flow for all
measured rates
Geen hoofdrol nutriënten in de afname van witvis in de Nederlandse binnenwateren
Dit artikel geeft een overzicht van de verandering van witvisbestanden in een aantal Nederlandse binnenwateren en bespreekt de mogelijke oorzaken van deze veranderingen. Deze analyse geeft aan dat de vispopulaties van vier grote Nederlandse binnenwateren onder druk staan van met name de visserij. De invloed van andere factoren, voornamelijk actief biologisch beheer en een toename van het aantal aalscholvers, lijkt kleiner en verschilt per meer. Vermindering van de nutriëntenconcentraties in het water vormt niet de hoofdoorzaak van de afname van witvis
Mode locking of vortex matter driven through mesoscopic channels
We investigated the driven dynamics of vortices confined to mesoscopic flow
channels by means of a dc-rf interference technique. The observed mode-locking
steps in the -curves provide detailed information on how the number of rows
and lattice structure in the channel change with magnetic field. Minima in flow
stress occur when an integer number of rows is moving coherently, while maxima
appear when incoherent motion of mixed and row configurations is
predominant. Simulations show that the enhanced pinning at mismatch originates
from quasi-static fault zones with misoriented edge dislocations induced by
disorder in the channel edges.Comment: some minor changes were made, 4 pages, 4 figures, accepted for
publication in Phys. Rev. Let
Quasi-chemical Theories of Associated Liquids
It is shown how traditional development of theories of fluids based upon the
concept of physical clustering can be adapted to an alternative local
clustering definition. The alternative definition can preserve a detailed
valence description of the interactions between a solution species and its
near-neighbors, i.e., cooperativity and saturation of coordination for strong
association. These clusters remain finite even for condensed phases. The
simplest theory to which these developments lead is analogous to quasi-chemical
theories of cooperative phenomena. The present quasi-chemical theories require
additional consideration of packing issues because they don't impose lattice
discretizations on the continuous problem. These quasi-chemical theories do not
require pair decomposable interaction potential energy models. Since
calculations may be required only for moderately sized clusters, we suggest
that these quasi-chemical theories could be implemented with computational
tools of current electronic structure theory. This can avoid an intermediate
step of approximate force field generation.Comment: 20 pages, no figures replacement: minor typographical corrections,
four references added, in press Molec. Physics 199
Successful policy formulation processes: Lessons from fifteen case experiences in five Dutch departments
Dynamic ordering and frustration of confined vortex rows studied by mode-locking experiments
The flow properties of confined vortex matter driven through disordered
mesoscopic channels are investigated by mode locking (ML) experiments. The
observed ML effects allow to trace the evolution of both the structure and the
number of confined rows and their match to the channel width as function of
magnetic field. From a detailed analysis of the ML behavior for the case of
3-rows we obtain ({\it i}) the pinning frequency , ({\it ii}) the onset
frequency for ML ( ordering velocity) and ({\it iii}) the
fraction of coherently moving 3-row regions in the channel. The
field dependence of these quantities shows that, at matching, where is
maximum, the pinning strength is small and the ordering velocity is low, while
at mismatch, where is small, both the pinning force and the ordering
velocity are enhanced. Further, we find that , consistent
with the dynamic ordering theory of Koshelev and Vinokur. The microscopic
nature of the flow and the ordering phenomena will also be discussed.Comment: 10 pages, 7 figure, submitted to PRB. Discussion has been improved
and a figure has been adde
Glass Rheology: From mode-coupling theory to a dynamical yield criterion
The mode coupling theory (MCT) of glasses, while offering an incomplete
description of glass transition physics, represents the only established route
to first-principles prediction of rheological behavior in nonergodic materials
such as colloidal glasses. However, the constitutive equations derivable from
MCT are somewhat intractable, hindering their practical use and also their
interpretation. Here, we present a schematic (single-mode) MCT model which
incorporates the tensorial structure of the full theory. Using it, we calculate
the dynamic yield surface for a large class of flows
Flux flow of Abrikosov-Josephson vortices along grain boundaries in high-temperature superconductors
We show that low-angle grain boundaries (GB) in high-temperature
superconductors exhibit intermediate Abrikosov vortices with Josephson cores,
whose length along GB is smaller that the London penetration depth, but
larger than the coherence length. We found an exact solution for a periodic
vortex structure moving along GB in a magnetic field and calculated the
flux flow resistivity , and the nonlinear voltage-current
characteristics. The predicted dependence describes well our
experimental data on unirradiated and irradiated
bicrystals, from which the core size , and the intrinsic depairing
density on nanoscales of few GB dislocations were measured for the
first time. The observed temperature dependence of
indicates a significant order parameter suppression in current channels between
GB dislocation cores.Comment: 5 pages 5 figures. Phys. Rev. Lett. (accepted
- …