Orientation effects in reactions of allenyl cations with styrene

Allenyl cations, generated from allenyl or alkynyl halides and Ag+, attack styrene at the side chain or at the aromatic nucleus. The allenyl/alkynyl product ratio is dependent on the structure of the precursor halide except for highly substituted systems

Protonolysis of a Ruthenium–Carbene Bond and Applications in Olefin Metathesis

The synthesis of a ruthenium complex containing an N-heterocylic carbene (NHC) and a mesoionic carbene (MIC) is described wherein addition of a Brønsted acid results in protonolysis of the Ru–MIC bond to generate an extremely active metathesis catalyst. Mechanistic studies implicated a rate-determining protonation step in the generation of the metathesis-active species. The activity of the NHC/MIC catalyst was found to exceed those of current commercial ruthenium catalysts

Ring-apodized vortex coronagraphs for obscured telescopes. I. Transmissive ring apodizers

The vortex coronagraph (VC) is a new generation small inner working angle (IWA) coronagraph currently offered on various 8-meter class ground-based telescopes. On these observing platforms, the current level of performance is not limited by the intrinsic properties of actual vortex devices, but by wavefront control residuals and incoherent background (e.g. thermal emission of the sky) or the light diffracted by the imprint of the secondary mirror and support structures on the telescope pupil. In the particular case of unfriendly apertures (mainly large central obscuration) when very high contrast is needed (e.g. direct imaging of older exoplanets with extremely large telescopes or space- based coronagraphs), a simple VC, as most coronagraphs, can not deliver its nominal performance because of the contamination due to the diffraction from the obscured part of the pupil. Here we propose a novel yet simple concept that circumvents this problem. We combine a vortex phase mask in the image plane of a high-contrast instrument with a single pupil-based amplitude ring apodizer, tailor designed to exploit the unique convolution properties of the VC at the Lyot-stop plane. We show that such a ring-apodized vortex coronagraph (RAVC) restores the perfect attenuation property of the VC regardless of the size of the central obscuration, and for any (even) topological charge of the vortex. More importantly the RAVC maintains the IWA and conserves a fairly high throughput, which are signature properties of the VC.Comment: 10 pages, 6 figure

Imaging and manipulating electrons in a 1D quantum dot with Coulomb blockade microscopy

Motivated by the recent experiments by the Westervelt group using a mobile tip to probe the electronic state of quantum dots formed on a segmented nanowire, we study the shifts in Coulomb blockade peak positions as a function of the spatial variation of the tip potential, which can be termed "Coulomb blockade microscopy". We show that if the tip can be brought sufficiently close to the nanowire, one can distinguish a high density electronic liquid state from a Wigner crystal state by microscopy with a weak tip potential. In the opposite limit of a strongly negative tip potential, the potential depletes the electronic density under it and divides the quantum wire into two partitions. There the tip can push individual electrons from one partition to the other, and the Coulomb blockade micrograph can clearly track such transitions. We show that this phenomenon can be used to qualitatively estimate the relative importance of the electron interaction compared to one particle potential and kinetic energies. Finally, we propose that a weak tip Coulomb blockade micrograph focusing on the transition between electron number N=0 and N=1 states may be used to experimentally map the one-particle potential landscape produced by impurities and inhomogeneities.Comment: 4 pages 7 figure

Hybridization gap and anisotropic far-infrared optical conductivity of URu2Si2

We performed far-infrared optical spectroscopy measurements on the heavy fermion compound URu 2 Si 2 as a function of temperature. The light's electric-field was applied along the a-axis or the c-axis of the tetragonal structure. We show that in addition to a pronounced anisotropy, the optical conductivity exhibits for both axis a partial suppression of spectral weight around 12 meV and below 30 K. We attribute these observations to a change in the bandstructure below 30 K. However, since these changes have no noticeable impact on the entropy nor on the DC transport properties, we suggest that this is a crossover phenomenon rather than a thermodynamic phase transition.Comment: To be published in Physical Review