Annual report 2009 // Institute of Radiochemistry

[no abstract available

Annual report 2008 // Institute of Radiochemistry

[no abstract available

A nation-wide laboratory: Examining trust and trustworthiness by integrating behavioral experiments into representative surveys

Typically, laboratory experiments suffer from homogeneous subject pools and selfselection biases. The usefulness of survey data is limited by measurement error and by the questionability of their behavioral relevance. Here we present a method integrating interactive experiments and representative surveys thereby overcoming crucial weaknesses of both approaches. One of the major advantages of our approach is that it allows for the integration of experiments, which require interaction among the participants, with a survey of non-interacting respondents in a smooth and inexpensive way. We illustrate the power of our approach with the analysis of trust and trustworthiness in Germany by combining representative survey data with representative behavioral data from a social dilemma experiment. We identify which survey questions intended to elicit peoples trust correlate well with behaviorally exhibited trust in the experiment. People above the age of 65, highly skilled workers and people living in bigger households exhibit less trusting behavior. Foreign citizens, Catholics and people favoring the Social Democratic Party or the Christian Democratic Party exhibit more trust. People above the age of 65 and those in good health behave more trustworthy or more altruistically, respectively. People below the age of 35, the unemployed and people who say they are in favor of none of the political parties behave less trustworthy or less altruistically, respectively. -- Die experimentelle Ökonomie führt typischerweise Labor-Untersuchungen durch, die mit homogenen und selektiven Versuchspersonen arbeiten. Repräsentative Surveys leiden hingegen unter Meßfehlern und der Frage, ob hypothetisches Verhalten, das erhoben wird, mit tatsächlichem Verhalten korrespondiert. Deswegen präsentieren wir eine Methode, mit der man die Schwächen beider Ansätze überwindet, indem man Survey-Daten mit Experimenten kombiniert. Die von uns entwickelte Methode hat den Vorzug, dass sie es auf preiswerte Art und Weise erlaubt, Experimente, die die Interaktion zweier Personen erfordern, mit Standard-Surveys zu kombinieren, die auf der Unabhängigkeit der befragten Personen beruhen. Wir illustrieren die Möglichkeiten unserer Methodik mit einer Untersuchung über Vertrauen und Vertrauenswürdigkeit in Deutschland, bei der eine repräsentative Umfrage mit einem Experiment über eine Dilemma-Situation verbunden wurde. Unsere Resultate zeigen zum einen, dass nicht alle Survey-Fragen über Vertrauen mit den Ergebnissen des Experiments korrelieren. Zum zweiten zeigen unsere Ergebnisse, dass ältere Menschen (65 Jahre und älter), Hochqualifizierte und Personen, die in grösseren Haushalten leben, im Experiment unterdurchschnittlich Vertrauen offenbaren. Für Ausländer, Katholiken und die Anhänger der großen Volksparteien finden wir überdurchschnittliches Vertrauen. Vertrauenswürdigkeit bzw. Altruismus zeigen im Experiment Ältere und Befragte mit gutem Gesundheitszustand. Unterdurchschnittliche Vertrauenswüdigkeit bzw. Altruismus zeigen jüngere Befragte (bis zu 35 Jahren), arbeitslos Gemeldete und Befragte ohne eine Parteineigung.Experiment,Survey,Trust,Trustworthiness,Altruism

Annual Report 2010 - Institute of Radiochemistry

At the beginning of 2011, the former Forschungszentrum Dresden-Rossendorf (FZD) was fully integrated into the Helmholtz Association, as Helmholtz-Zentrum Dresden-Rossendorf (HZDR). Therefore, the present Annual Report 2010 of the Institute of Radiochemistry (IRC) is published as the first HZDR-Report. The Institute of Radiochemistry is one of the six Research Institutes of this centre. IRC contributes to the research program “Nuclear Safety Research” in the “Research Field of Energy” and performs basic and applied research in radiochemistry and radioecology. Motivation and background of our research are environmental processes relevant for the installation of nuclear waste repositories, for remediation of uranium mining and milling sites, and for radioactive contaminations caused by nuclear accidents and fallout. Because of their high radiotoxicity and long half-life the actinides are of special interest

Joint Project: Interaction and transport of actinides in natural clay rock with consideration of humic substances and clay organics - Characterization and quantification of the influence of clay organics on the interaction and diffusion of uranium and americium in the clay

The objective of this project was the study of basic interaction processes in the systems actinide - clay organics - aquifer and actinide - natural clay - clay organics - aquifer. Thus, complexation, redox, sorption and diffusion studies were performed. To evaluate the influence of nitrogen, phosphorus and sulfur containing functional groups of humic acid (HA) on the complexation of actinides in comparison to carboxylic groups, the Am(III) and U(VI) complexation by model ligands was studied by UV-Vis spectroscopy and TRLFS. The results show that Am(III) is mainly coordinated via carboxylic groups, however, probably stabilized by nitrogen groups. The U(VI) complexation is dominated by carboxylic groups, whereas nitrogen and sulfur containing groups play a minor role. Phosphorus containing groups may contribute to the U(VI) complexation by HA, however, due to their low concentration in HA they play only a subordinate role compared to carboxylic groups. Applying synthetic HA with varying sulfur contents (0 to 6.9 wt.%), the role of sulfur functionalities of HA for the U(VI) complexation and Np(V) reduction was studied. The results have shown that sulfur functionalities can be involved in U(VI) humate complexation and act as redox-active sites in HA for the Np(V) reduction. However, due to the low content of sulfur in natural HA, its influence is less pronounced. In the presence of carbonate, the U(VI) complexation by HA was studied in the alkaline pH range by means of cryo-TRLFS (-120°C) and ATR FT-IR spectroscopy. The formation of the ternary UO2(CO3)2HA(II)4− complex was detected. The complex formation constant was determined with log β0.1 M = 24.57 ± 0.17. For aqueous U(VI) citrate and oxalate species, luminescence emission properties were determined by cryo-TRLFS and used to determine stability constants. The existing data base could be validated. The U(VI) complexation by lactate, studied in the temperature range 7 to 65°C, was found to be endothermic and entropy-driven. In contrast, the complex stability constants determined for U(VI) humate complexation at 20 and 40°C are comparable, however, decrease at 60°C. For aqueous U(IV) citrate, succinate, mandelate and glycolate species stability constants were determined. These ligands, especially citrate, increase solubility and mobility of U(IV) in solution due to complexation. The U(VI) sorption onto crushed Opalinus Clay (OPA, Mont Terri, Switzerland) was studied in the absence and presence of HA or low molecular weight organic acids, in dependence on temperature and CO2 presence using OPA pore water as background electrolyte. Distribution coefficients (Kd) were determined for the sorption of U(VI) and HA onto OPA with (0.0222 ± 0.0004) m3/kg and (0.129 ± 0.006) m3/kg, respectively. The U(VI) sorption is not influenced by HA (50 mg/L), however, decreased by low molecular weight organic acids (> 1×10-5 M), especially by citrate and tartrate. With increasing temperature, the U(VI) sorption increases both in the absence and in the presence of clay organics. The U(VI) diffusion in compacted OPA is not influenced by HA at 25 and 60°C. Predictions of the U(VI) diffusion show that an increase of the temperature to 60°C does not accelerate the migration of U(VI). With regard to uranium-containing waste, it is concluded that OPA is suitable as host rock for a future nuclear waste repository since OPA has a good retardation potential for U(VI)

Abtrennung von Uran aus wässriger Lösung durch Calix[6]arene mittels Flüssig-Flüssig-Extraktion sowie Festphasen-Extraktion

Die Uranspeziation in ausgewählten Sicker- und Grubenwässern des ehemaligen Uranbergbaus wurde mittels spektroskopischer Methoden (TRLFS, LIPAS) untersucht. Deren Kenntnis in Abhängigkeit vom pH-Wert ermöglicht die Optimierung der Uranabtrennung mittels uranophiler Calixarene. Mittels Flüssig-Flüssig-Extraktion wurde gezeigt, dass COOH-derivatisierte Calix[6]arene als effektive Extraktionsmittel für die selektive Uranylabtrennung aus umweltrelevanten Wässern bei pH-Werten größer 4 geeignet sind und für Praxisanwendungen eingesetzt werden können. Extraktionskonstanten wurden bestimmt. Die durch Fixierung dieser Calixarenderivate auf Polyester dargestellten calixarenmodifizierten Vliese sind in der Lage Uranylionen aus synthetischen Grubenwässern in Anwesenheit von Konkurrenzionen abzutrennen. Die Untersuchungen zur Reversibilität der Uranbindung an calixarenausgerüsteten Polyestervliesen haben gezeigt, dass eine fast vollständige Regenerierung der calixarenmodifizierten Vliese mittels verdünnter Mineralsäuren möglich ist. Die regenerierten textilen Filtermaterialien können für weitere Uranabtrennungszyklen eingesetzt werden. Nach Auswahl geeigneter Calixarenderivate ist eine Übertragung des entwickelten Abtrennungsprinzipes auf weitere Actinide (z.B. Np, Pu) bzw. Schwermetall-Kontaminanten (z.B. As, Cd, Pb) möglich