Isotopic signature of burial diagenesis and primary lithological contrasts in periplatform carbonates (Miocene, Great Bahama Bank)

The stable isotope geochemistry of Miocene sediments from the leeward margin of the Great Bahama Bank was examined to investigate burial diagenetic processes in periplatform carbonates. Data indicate that, in addition to differences in bulk proportions of neritic and pelagic carbonate along the slope, rhythmic variation in primary carbonate content has controlled patterns of burial diagenesis and associated geochemical signatures throughout much of the succession examined. The present study focuses on Ocean Drilling Program Sites 1006 and 1007, the most distal of five sites drilled from marginal to deep basin environments during Leg 166. These Miocene sections are characterized by their cyclic appearance, manifest as decimeter- to meter-scale alternations between light-colored ooze/chalk/limestone and dark-colored marl/marlstone. The section at Site 1006 contains a high proportion of pelagic carbonate and is unlithified to a subbottom depth of ~675 m. Fluctuations in δ18O and δ13C values at this site are independent of lithological variation and reflect primary conditions. At Site 1007, located at the toe-of-slope and composed of a mixture of bank-derived and pelagic carbonate, limestones are densely cemented, show little evidence of compaction and have δ18O values up to 2‰ higher than coeval sediments at Site 1006. Marlstones at Site 1007 are poorly cemented, exhibit an increase in compaction-related features with depth and have lower and more variable δ18O values that are similar to those of coeval sediments at Site 1006. Isotopic and petrographic characteristics of limestone interbeds result from cement precipitation from cold sea water during the first ~100 m of burial. Higher proportions of insoluble materials and pelagic carbonate seem to have inhibited diagenetic alteration in adjacent marlstones; in spite of significant compaction and pressure solution during burial, original isotopic compositions appear to be best preserved in these intervals at Site 1007. The documented contrasts in petrographic and isotopic patterns illustrate the role of primary sediment composition in controlling lithification processes in periplatform carbonates and stress the importance of considering such factors when interpreting geochemical data from ancient shelf and slope limestones

Microwave pretreatment of lignocellulosic biomass to release maximum phenolic acids

[EN] The objectives fixed by world’s governments concerning energy transition have aroused interest on lignocellulosic biomass utilization for bioenergy and green chemistry applications. However, due to their resistant structure, deconstructive pretreatments are necessary to render possible biological conversions of these lignocellulosic residues. Microwave (MW) treatment has been reported as efficient in many biotechnology fields; biomass pretreatment for biorefinery purposes is another possible application. This work presents the effects of MW pretreatment on underexploited natural agri-food biomass of economic interest: wheat bran, miscanthus stalks and corn stalks. Various parameters were studied including solvent, power density, treatment duration, pressure. Effects were evaluated by a complete biomass characterization before and after treatment, with main focus on phenolic acids release. In the tested conditions and when compared to the high NaOH consumption reference extraction method for phenolic acids, the atmospheric pressure (open vessel) microwave treatment did not allow attaining high acid yields (Fig.1). The most important parameters for improving treatment efficiency were power density and solvent. In order to increase yields, microwave treatments under pressure were carried out to reach higher temperatures while taking care as to not exceed the acid denaturation temperature (150°C) and to avoid the formation of inhibitors. Phenolic acids yields and biomass composition are currently being processed and will be discussed.Authors would like to thank Nicolas Holfeltz, NH Verre France for his help in designing the microwave reactor. The authors also thank Yannick Sire from INRA Pech Rouge for phenolic acids analysis.Bichot, A.; Radoiu, M.; Bernet, N.; Mechin, V.; Delgenès, J.; García Bernet, D. (2019). Microwave pretreatment of lignocellulosic biomass to release maximum phenolic acids. En AMPERE 2019. 17th International Conference on Microwave and High Frequency Heating. Editorial Universitat Politècnica de València. 182-188. https://doi.org/10.4995/AMPERE2019.2019.9629OCS18218

A Hybrid Medium Voltage Multilevel Converter with Parallel Voltage-Source Active Filter

In consequence of high semiconductor losses, grid-connected medium voltage power converters are typically operated at switching frequencies of several hundred Hertz per switch position. Therefore, conventional converter systems require bulky and expensive LCL-filters in order to meet the harmonic limits given by the grid code. It is only possible to reduce the LCL-filter costs by semiconductor current derating and operation at increased switching frequencies, leading to a reduced utilization and efficiency of the converter system. To overcome these disadvantages of conventional converter systems, the presented hybrid converter uses a parallel voltage-source active output filter and thus allows a significant reduction of the passive component demand. An excellent harmonic performance is achieved for the operation with small passive filter components, revealing the potential for increasing the power density and efficiency of high power medium voltage converters. As a result, significant reductions of the filter losses and passive components as well as an increased utilization are achieved compared to a reference LCL-filter based converter system

Increase of metallothionein-immunopositive chloride cells in the gills of brown trout and rainbow trout after exposure to sewage treatment plant effluents

Metallothionein, a biomarker of exposure and toxicity of heavy metals, has been detected in the gills of brown trout (Salmo trutta fario L.) and rainbow trout (Oncorhynchus mykiss Richardson) by means of immunohistochemistry. A very prominent labelling of chloride cells was found after exposure to diluted sewage plant effluents. No significant increase was observed in either the number of labelled cells or their labelling intensity after exposure to water of a polluted river compared to fish kept in tap water. These results do not correlate with findings of a histopathological study, suggesting that the metal levels at the sewage treatment plant were too low to produce gross histopathology. A comparison between the species indicated that the rainbow trout showed a generally higher metallothionein expression than the brown trout

Surface water floods in Switzerland: what insurance claim records tell us about the damage in space and time

Surface water floods (SWFs) have received increasing attention in the recent years. Nevertheless, we still know relatively little about where, when and why such floods occur and cause damage, largely due to a lack of data but to some degree also because of terminological ambiguities. Therefore, in a preparatory step, we summarize related terms and identify the need for unequivocal terminology across disciplines and international boundaries in order to bring the science together. Thereafter, we introduce a large (n = 63 117), long (10–33 years) and representative (48 % of all Swiss buildings covered) data set of spatially explicit Swiss insurance flood claims. Based on registered flood damage to buildings, the main aims of this study are twofold: First, we introduce a method to differentiate damage caused by SWFs and fluvial floods based on the geographical location of each damaged object in relation to flood hazard maps and the hydrological network. Second, we analyze the data with respect to their spatial and temporal distributions aimed at quantitatively answering the fundamental questions of how relevant SWF damage really is, as well as where and when it occurs in space and time. This study reveals that SWFs are responsible for at least 45 % of the flood damage to buildings and 23 % of the associated direct tangible losses, whereas lower losses per claim are responsible for the lower loss share. The Swiss lowlands are affected more heavily by SWFs than the alpine regions. At the same time, the results show that the damage claims and associated losses are not evenly distributed within each region either. Damage caused by SWFs occurs by far most frequently in summer in almost all regions. The normalized SWF damage of all regions shows no significant upward trend between 1993 and 2013. We conclude that SWFs are in fact a highly relevant process in Switzerland that should receive similar attention like fluvial flood hazards. Moreover, as SWF damage almost always coincides with fluvial flood damage, we suggest considering SWFs, like fluvial floods, as integrated processes of our catchments

Sum Rules and Moments of the Nucleon Spin Structure Functions

The nucleon has been used as a laboratory to investigate its own spin structure and Quantum Chromodynamics. New experimental data on nucleon spin structure at low to intermediate momentum transfers combined with existing high momentum transfer data offer a comprehensive picture of the transition region from the {\it confinement} regime of the theory to its {\it asymptotic freedom} regime. Insight for some aspects of the theory is gained by exploring lower moments of spin structure functions and their corresponding sum rules (i.e. the Gerasimov-Drell-Hearn, Bjorken and Burkhardt-Cottingham). These moments are expressed in terms of an operator product expansion using quark and gluon degrees of freedom at moderately large momentum transfers. The sum rules are verified to a good accuracy assuming that no singular behavior of the structure functions is present at very high excitation energies. The higher twist contributions have been examined through the moments evolution as the moments evolution as the momentum transfer varies from higher to lower values. Furthermore, QCD-inspired low-energy effective theories, which explicitly include chiral symmetry breaking, are tested at low momentum transfers. The validity of these theories is further examined as the momentum transfer increases to moderate values. It is found that chiral perturbation calculations agree reasonably well with the first moment of the spin structure function $g_1$ at momentum transfer of 0.1 GeV$^2$ but fail to reproduce the neutron data in the case of the generalized polarizability $\delta_{LT}$.Comment: 21 pages, 4 figures, review for Modern Physics Letters A. Minor modifications in text and improved quality for one figure. Corrected mistakes in section

A novel high dynamic six phase 120 kW Power Hardware in the Loop Emulation Test Bench for emulating AC/DC Grids and Electrical Machines

This paper presents a highly customizable 120kVA Power-Hardware-in-the-Loop test bench. The output stage consist of two identical Parallel Hybrid Converters each with a 17-level output voltage and an effective switching frequency of 1MHz. The Parallel Hybrid Converters can provide 3-phase AC or bipolar DC as output voltage. Thus, one 6-AC, 3-AC or DC system or two systems with 2x3-AC, 1x3-AC and 1xDC or 2xDC can be emulated

A novel high dynamic six phase 120 kW Power Hardware in the Loop Emulation Test Bench for emulating AC/DC Grids and Electrical Machines

This paper presents a highly customizable 120kVA Power-Hardware-in-the-Loop test bench. The output stage consist of two identical Parallel Hybrid Converters each with a 17-level output voltage and an effective switching frequency of 1MHz. The Parallel Hybrid Converters can provide 3-phase AC or bipolar DC as output voltage. Thus, one 6-AC, 3-AC or DC system or two systems with 2x3-AC, 1x3-AC and 1xDC or 2xDC can be emulated

Study of timing characteristics of a 3 m long plastic scintillator counter using waveform digitizers

A plastic scintillator bar with dimensions 300 cm x 2.5 cm x 11 cm was exposed to a focused muon beam to study its light yield and timing characteristics as a function of position and angle of incidence. The scintillating light was read out at both ends by photomultiplier tubes whose pulse shapes were recorded by waveform digitizers. Results obtained with the WAVECATCHER and SAMPIC digitizers are analyzed and compared. A discussion of the various factors affecting the timing resolution is presented. Prospects for applications of plastic scintillator technology in large-scale particle physics detectors with timing resolution around 100 ps are provided in light of the results