Anisotropic valence-->core x-ray fluorescence from a [Rh(en)3][Mn(N)(CN)5]·H2O single crystal: Experimental results and density functional calculations

High resolution x-ray fluorescence spectra have been recorded for emission in different directions from a single crystal of the compound [Rh(en)3][Mn(N)(CN)5]·H2O. The spectra are interpreted by comparison with density functional theory (DFT) electronic structure calculations. The Kbeta[double-prime] line, which is strongly polarized along the Mn–N axis, can be viewed as an N(2s)-->Mn(1s) transition, and the angular dependence is understood within the dipole approximation. The so-called Kbeta2,5 region has numerous contributions but is dominated by Mn(4p) and C(2s)-->Mn(1s) transitions. Transition energy splittings are found in agreement with those of calculated occupied molecular orbitals to within 1 eV. Computed relative transition probabilities reproduce experimentally observed trends

Precipitation dynamics and chemical properties in tropical mountain forests of Ecuador

International audienceTerrestrial ecosystems in southern Ecuador are strongly affected by interannual climate variations. This holds especially true for the episodic El Niño events, which cause above-normal precipitation in the coastal region of Ecuador and below normal values in the eastern provinces of the Amazon basin (Bendix, 1999). For the transitional zone between these two extremes, which consists mainly of the andean slopes and larger interandean basins the effect on interannual climate variability is not well known. The PREDICT project monitors regional climate in the provinces of Loja and Zamora-Chinchipe (4° S/79° W), where a strong gradients of precipitation are observed. Between the eastern slopes of the Cordillera Real and the dry valley of Catamayo, which are only 70km apart, rain totals drop from over 4000 mm to only 300 mm per year. These two extremes represent the both sides of the Andean mountain chain and are completely covered by the study area, which is 120 km in diameter. Methods used are a combination of point measurements (climate stations) and remote sensing devices (weather radar, satellite imagery), which enable a high-resolution real-time observation of rain distribution and underlying processes. By this, ideal conditions are given to monitor a potential shift of the transition zone between below-average and above-average rainfall situated in this region, if another ENSO-anomaly occurs. Furthermore variability of atmospheric nutrient inputs is analysed within the scope of the project, to assess further impacts on this ecosystem

First results on a process-oriented rain area classification technique using Meteosat Second Generation SEVIRI nighttime data

A new technique for process-oriented rain area classification using Meteosat Second Generation SEVIRI nighttime data is introduced. It is based on a combination of the Advective Convective Technique (ACT) which focuses on precipitation areas connected to convective processes and the Rain Area Delineation Scheme during Nighttime (RADS-N) a new technique for the improved detection of stratiform precipitation areas (e.g. in connection with mid-latitude frontal systems). The ACT which uses positive brightness temperature differences between the water vapour (WV) and the infrared (IR) channels (ΔT<sub>WV-IR</sub>) for the detection of convective clouds and connected precipitating clouds has been transferred from Meteosat First Generation (MFG) Metesoat Visible and Infra-Red Imager radiometer (MVIRI) to Meteosat Second Generation (MSG) Spinning Enhanced Visible and InfraRed Imager (SEVIRI). RADS-N is based on the new conceptual model that precipitating cloud areas are characterised by a large cloud water path (<i>cwp</i>) and the presence of ice particles in the upper part of the cloud. The technique considers information about both parameters inherent in the channel differences ΔT<sub>3.9-10.8</sub>, ΔT<sub>3.9-7.3</sub>, ΔT<sub>8.7-10.8</sub>, and ΔT<sub>10.8-12.1</sub>, to detect potentially precipitating cloud areas. All four channel differences are used to gain implicit knowledge about the <i>cwp</i>. ΔT<sub>8.7-10.8</sub> and ΔT<sub>10.8-12.1</sub> are additionally considered to gain information about the cloud phase. First results of a comparison study between the classified rain areas and corresponding ground based radar data for precipitation events in connection with a cold front occlusion show encouraging performance of the new proposed process-oriented rain area classification scheme

Discriminating raining from non-raining clouds at mid-latitudes using Meteosat Second Generation daytime data

International audienceA new method for the delineation of precipitation during daytime using multispectral satellite data is proposed. The approach is not only applicable to the detection of mainly convective precipitation by means of the commonly used relation between infrared cloud top temperature and rainfall probability but enables also the detection of stratiform precipitation (e.g. in connection with mid-latitude frontal systems). The presented scheme is based on the conceptual model that precipitating clouds are characterized by a combination of particles large enough to fall, an adequate vertical extension (both represented by the cloud water path (cwp)), and the existence of ice particles in the upper part of the cloud. The technique considers the VIS0.6 and the NIR1.6 channel to gain information about the cloud water path. Additionally, the channel differences ?T8.7-10.8 and ?T10.8-12.1 are considered to supply information about the cloud phase. Rain area delineation is realized by using a minimum threshold of the rainfall confidence. To obtain a statistical transfer function between the rainfall confidence and the channel differences, the value combination of the four variables is compared to ground based radar data. The retrieval is validated against independent radar data not used for deriving the transfer function and shows an encouraging performance as well as clear improvements compared to existing optical retrieval techniques using only IR thresholds for cloud top temperature

Skin microbiota analysis in patients with anorexia nervosa and healthy-weight controls reveals microbial indicators of healthy weight and associations with the antimicrobial peptide psoriasin

Anorexia nervosa (AN), a psychiatric condition defined by low body weight for age and height, is associated with numerous dermatological conditions. Yet, clinical observations report that patients with AN do not suffer from infectious skin diseases like those associated with primary malnutrition. Cell-mediated immunity appears to be amplified in AN; however, this proinflammatory state does not sufficiently explain the lower incidence of infections. Antimicrobial peptides (AMPs) are important components of the innate immune system protecting from pathogens and shaping the microbiota. In Drosophila melanogaster starvation precedes increased AMP gene expression. Here, we analyzed skin microbiota in patients with AN and age-matched, healthy-weight controls and investigated the influence of weight gain on microbial community structure. We then correlated features of the skin microbial community with psoriasin and RNase 7, two highly abundant AMPs in human skin, to clarify whether an association between AMPs and skin microbiota exists and whether such a relationship might contribute to the resistance to cutaneous infections observed in AN. We find significant statistical correlations between Shannon diversity and the highly abundant skin AMP psoriasin and bacterial load, respectively. Moreover, we reveal psoriasin significantly associates with Abiotrophia, an indicator for the healthy-weight control group. Additionally, we observe a significant correlation between an individual’s body mass index and Lactobacillus, a microbial indicator of health. Future investigation may help clarify physiological mechanisms that link nutritional intake with skin physiology

Radical cation salts of TTF donors with XF6 (X = Re,Ta) anions

Electrocrystallization of the dianionic Re(IV)F6 species with different organic π electron donors was carried out. Depending on the first oxidation potential of the TTF derivatives this crystallization technique gave rise to various radical cations salts involving Re(IV) or Re(V) anions. With tetramethyltetrathiafulvalene (TMTTF) the (TMTTF)2Re(IV)F6  salt was obtained. However, with tetramethyltetraselenafulvalene (TMTSF) we obtained very small needles of the (TMTSeF)2Re(V)F6 system, analogue to the so called “Bechgaard salts” [1]. We present some characteristics of this new metallic phase. We compare to the diamagnetic (TMTSeF)2Ta(V)F6 obtained by the same strategy using TBATaF6 prepared according to the Browstein’s method [2] and explore electrocrystallization of the tantalum based anions [3], [4]. References: [1] K. Bechgaard, C.S. Jacobsen, K. Mortensen, H.J. Pedersen, N. Thorup, Solid State Commun. 1980, 33, 1119-1125. [2] S. Brownstein, Inorg. Chem. 1973, 12, N°3, 584-589. [3] C. Lenoir, K. Boubekeur, P. Batail, E. Canadell, P. Auban, O. Traetteberg, D. Jérome, Synth. Met. 1991, 42, 1939-1942. [4] F. Iwase, K. Sugiura, K. Furukawa, T. Nakamura, J. Phys. Soc. Jpn. 2009, 78, N°10, 104717:1-104717:7