Nanoparticles in explosives detection – the state-of-the-art and future directions

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Recent Developments in the Field of Explosive Trace Detection

Explosive trace detection (ETD) technologies play a vital role in maintaining national security. ETD remains an active research area with many analytical techniques in operational use. This review details the latest advances in animal olfactory, ion mobility spectrometry (IMS), and Raman and colorimetric detection methods. Developments in optical, biological, electrochemical, mass, and thermal sensors are also covered in addition to the use of nanomaterials technology. Commercially available systems are presented as examples of current detection capabilities and as benchmarks for improvement. Attention is also drawn to recent collaborative projects involving government, academia, and industry to highlight the emergence of multimodal screening approaches and applications. The objective of the review is to provide a comprehensive overview of ETD by highlighting challenges in ETD and providing an understanding of the principles, advantages, and limitations of each technology and relating this to current systems

Pathways of the Modified Atlantic Water across the Strait of Sicily

The purpose of this study is to study the medium-scale dynamics, as well as the dynamics of the sub-basin scale in the Central Mediterranean, and to elucidate the routes of the Atlantic waters in this region using a high-resolution numerical model of the eddy-resolving simplest equation. The seasonal variability of the two streams of modified Atlantic waters crossing the Sicilian Strait varies considerably. The main stream along the coast of Tunisia, giving rise to the Atlantic Tunisian current, is stronger than the Atlantic Ionian stream (AIP) from autumn to spring. The Atlantic Tunisian current, which, apparently, is present throughout the year, is characterized by high spatial and temporal variability from the simulation results. The high-resolution model is capable of well reproducing the flow and variability of AIP, including such associating characteristic structures as the Advent Benk Vortex, Moltis Channel Cross, Ionian Benc Vortex and the outflow to the northern Ionian Sea

Sensitive and specific detection of explosives in solution and vapour by surface-enhanced Raman spectroscopy on silver nanocubes

Surface-enhanced Raman spectroscopy (SERS) has been widely utilised as a sensitive analytical technique for the detection of trace levels of organic molecules. The detection of organic compounds in the gas phase is particularly challenging due to the low concentration of adsorbed molecules on the surface of the SERS substrate. This is particularly the case for explosive materials, which typically have very low vapour pressures, limiting the use of SERS for their identification. In this work, silver nanocubes (AgNCs) were developed as a highly sensitive SERS substrate with very low limit-of-detection (LOD) for explosive materials down to the femtomolar (10−15 M) range. Unlike typical gold-based nanostructures, the AgNCs were found suitable for the detection of both aromatic and aliphatic explosives, enabling detection with high specificity at low concentration. SERS studies were first carried out using a model analyte, Rhodamine-6G (Rh-6G), as a probe molecule. The SERS enhancement factor was estimated as 8.71 × 1010 in this case. Further studies involved femtomolar concentrations of 2,4-dinitrotoluene (DNT) and nanomolar concentrations of 1,3,5-trinitroperhydro-1,3,5-triazine (RDX), as well as vapour phase detection of DNT

Biofiltration of high concentration of H2S in waste air under extreme acidic conditions

International audienceRemoval of high concentrations of hydrogen sulfide using a biofilter packed with expanded schist under extreme acidic conditions was performed. The impact of various parameters such as H2S concentration, pH changes and sulfate accumulation on the performances of the process was evaluated. Elimination efficiency decreased when the pH was lower than 1 and the sulfate accumulation was more than 12 mg S-SO42-/g dry media, due to a continuous overloading by high H2S concentrations. The influence of these parameters on the degradation of H2S was clearly underlined, showing the need for their control, performed through an increase of watering flow rate. A maximum elimination capacity (ECmax) of 24.7 g m−3 h−1 was recorded. As a result, expanded schist represents an interesting packing material to remove high H2S concentration up to 360 ppmv with low pressure drops. In addition, experimental data were fitted using both Michaelis–Menten and Haldane models, showing that the Haldane model described more accurately experimental data since the inhibitory effect of H2S was taken into accoun

Impact of nutrients supply and pH changes on the elimination of hydrogen sulfide, dimethyl disulfide and ethanethiol by biofiltration.

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Photo-induced enhanced Raman spectroscopy as a probe for photocatalytic surfaces

Photo-induced enhanced Raman spectroscopy (PIERS) has emerged as a highly sensitive surface-enhanced Raman spectroscopy (SERS) technique for the detection of ultra-low concentrations of organic molecules. The PIERS mechanism has been largely attributed to UV-induced formation of surface oxygen vacancies (Vo) in semiconductor materials, although alternative interpretations have been suggested. Very recently, PIERS has been proposed as a surface probe for photocatalytic materials, following Vo formation and healing kinetics. This work establishes comparison between PIERS and Vo-induced SERS approaches in defected noble-metal-free titanium dioxide (TiO2-x) films to further confirm the role of Vo in PIERS. Upon application of three post-treatment methods (namely UV-induction, vacuum annealing and argon etching), correlation of Vo kinetics and distribution could be established. A proposed mechanism and further discussion on PIERS as a probe to explore photocatalytic materials are also presented. This article is part of the theme issue 'Exploring the length scales, timescales and chemistry of challenging materials (Part 2)'

Photo-induced enhanced Raman spectroscopy for universal ultra-trace detection of explosives, pollutants and biomolecules

Surface-enhanced Raman spectroscopy is one of the most sensitive spectroscopic techniques available, with single-molecule detection possible on a range of noble-metal substrates. It is widely used to detect molecules that have a strong Raman response at very low concentrations. Here we present photo-induced-enhanced Raman spectroscopy, where the combination of plasmonic nanoparticles with a photo-activated substrate gives rise to large signal enhancement (an order of magnitude) for a wide range of small molecules, even those with a typically low Raman cross-section. We show that the induced chemical enhancement is due to increased electron density at the noble-metal nanoparticles, and demonstrate the universality of this system with explosives, biomolecules and organic dyes, at trace levels. Our substrates are also easy to fabricate, self-cleaning and reusable