Stratigraphic hierarchy and three‐dimensional evolution of an exhumed submarine slope channel system

Submarine slope channel systems have complicated three‐dimensional geometries and facies distributions, which are challenging to resolve using subsurface data. Outcrop analogues can provide sub‐seismic‐scale detail, although most exhumed systems only afford two‐dimensional constraints on the depositional architecture. A rare example of an accessible fine‐grained slope channel complex set situated in a tectonically quiescent basin that offers seismic‐scale, down‐dip and across‐strike exposures is the Klein Hangklip area, Tanqua‐Karoo Basin, South Africa. This study investigates the three‐dimensional architecture of this channel complex set to characterise the stratigraphic evolution of a submarine channel‐fill and the implications this has for both sediment transport to the deep‐oceans and reservoir quality distribution. Correlated sedimentary logs and mapping of key surfaces across a 3 km2 area reveal that: (i) the oldest channel elements in channel complexes infill relatively deep channel cuts and have low aspect‐ratios. Later channel elements are bound by comparatively flat erosion surfaces and have high aspect‐ratios; (ii) facies changes across depositional strike are consistent and predictable; conversely, facies change in successive down depositional dip positions indicating longitudinal variability in depositional processes; (iii) stratigraphic architecture is consistent and predictable at seismic‐scale both down‐dip and across‐strike in three‐dimensions; (iv) channel‐base‐deposits exhibit spatial heterogeneity on one to hundreds of metres length‐scales, which can inhibit accurate recognition and interpretations drawn from one‐dimensional or limited two‐dimensional datasets; and (v) channel‐base‐deposit character is linked to sediment bypass magnitude and longevity, which suggests that time‐partitioning is biased towards conduit excavation and maintenance rather than the fill‐phase. The data provide insights into the stratigraphic evolution and architecture of slope channel‐fills on fine‐grained continental margins and can be utilised to improve predictions derived from lower resolution and one‐dimensional well data

Differential responses of emergent intertidal coral reef fauna to a large-scale El-Niño southern oscillation event: sponge and coral resilience.

There is a paucity of information on the impacts of the 1997-8 El Niño event and subsequent climatic episodes on emergent intertidal coral reef assemblages. Given the environmental variability intertidal reefs experience, such reefs may potentially be more resilient to climatic events and provide important insights into the adaptation of reef fauna to future ocean warming. Here we report the results of a 17-year (1995-2011) biodiversity survey of four emergent coral reef ecosystems in Bahia, Brazil, to assess the impact of a major El Niño event on the reef fauna, and determine any subsequent recovery. The densities of two species of coral, Favia gravida and Siderastrea stellata, did not vary significantly across the survey period, indicating a high degree of tolerance to the El Niño associated stress. However, there were marked decreases in the diversity of other taxa. Molluscs, bryozoans and ascidians suffered severe declines in diversity and abundance and had not recovered to pre-El Niño levels by the end of the study. Echinoderms were reduced to a single species in 1999, Echinometra lucunter, although diversity levels had recovered by 2002. Sponge assemblages were not impacted by the 1997-8 event and their densities had increased by the study end. Multivariate analysis indicated that a stable invertebrate community had re-established on the reefs after the El Niño event, but it has a different overall composition to the pre-El Niño community. It is unclear if community recovery will continue given more time, but our study highlights that any increase in the frequency of large-scale climatic events to more than one a decade is likely to result in a persistent lower-diversity state. Our results also suggest some coral and sponge species are particularly resilient to the El Niño-associated stress and therefore represent suitable models to investigate temperature adaptation in reef organisms

New insights into the stratigraphic evolution of southwest Britain: Implications for Triassic salt and hydrocarbon prospectivity

The discovery of Wytch Farm field in the Wessex Basin, and Kinsale Head field in the North Celtic Sea Basin in the early 1970s, led to exploration interest offshore in the Western Approaches Trough. Despite this activity, little evidence for prospective hydrocarbon resources has been found. To better understand the failures and analyse remaining hydrocarbon potential in this region, we make use of a large collection of new seismic reflection and well data to map Carboniferous to Neogene stratigraphy. The improved seismic imaging has allowed a better interpretation of the hitherto poorly understood, salt-related structures in the South Melville and the Plymouth Bay basins. The implications of the new interpretations for Carnian (Late Triassic), and Carboniferous stratigraphic and geodynamic evolution are assessed and contextualised with regional salt deposition in the Wessex, Bristol, and South Celtic Sea basins. From a petroleum system perspective, the Lias and Carboniferous source rocks are evaluated and modelled to analyse the maturity and evolution of the petroleum systems. We conclude that the Lias is an ineffective petroleum system due to timing and source maturation risk. However, the Triassic salt and associated subcropping faults have produced several possible pre-salt hydrocarbon traps. The traps may be charged from sporadic Mid-Late Carboniferous coal-bearing post-orogenic basins, a petroleum system previously overlooked

Electric Field Effects on Graphene Materials

Understanding the effect of electric fields on the physical and chemical properties of two-dimensional (2D) nanostructures is instrumental in the design of novel electronic and optoelectronic devices. Several of those properties are characterized in terms of the dielectric constant which play an important role on capacitance, conductivity, screening, dielectric losses and refractive index. Here we review our recent theoretical studies using density functional calculations including van der Waals interactions on two types of layered materials of similar two-dimensional molecular geometry but remarkably different electronic structures, that is, graphene and molybdenum disulphide (MoS$_2$). We focus on such two-dimensional crystals because of they complementary physical and chemical properties, and the appealing interest to incorporate them in the next generation of electronic and optoelectronic devices. We predict that the effective dielectric constant ($\varepsilon$) of few-layer graphene and MoS$_2$ is tunable by external electric fields ($E_{\rm ext}$). We show that at low fields ($E_{\rm ext}^{}<0.01$ V/\AA) $\varepsilon$ assumes a nearly constant value $\sim$4 for both materials, but increases at higher fields to values that depend on the layer thickness. The thicker the structure the stronger is the modulation of $\varepsilon$ with the electric field. Increasing of the external field perpendicular to the layer surface above a critical value can drive the systems to an unstable state where the layers are weakly coupled and can be easily separated. The observed dependence of $\varepsilon$ on the external field is due to charge polarization driven by the bias, which show several similar characteristics despite of the layer considered.Comment: Invited book chapter on Exotic Properties of Carbon Nanomatter: Advances in Physics and Chemistry, Springer Series on Carbon Materials. Editors: Mihai V. Putz and Ottorino Ori (11 pages, 4 figures, 30 references

Spatial variability in depositional reservoir quality of deep-water channel-fill and lobe deposits

Initial porosity and permeability in deep-water systems are controlled by primary sedimentary texture and mineralogy. Therefore, understanding the sedimentary processes that control changes in primary texture is critical for improved reservoir quality predictions. A well-constrained, exhumed submarine lobe in the Jaca Basin, and a submarine channel-fill element in the Aínsa Basin, northern Spain, were studied to characterize the depositional reservoir quality in axial to marginal/fringe positions. Construction of architectural panels and strategic sampling enabled analysis of the spatial changes in textural properties, and their relationship to reservoir quality distribution. Samples were analyzed in thin-section to establish how depositional processes inferred from outcrop observations affect textural properties. Results show that high-density turbidites are concentrated in lobe- and channel-axis positions and exhibit good depositional reservoir quality. Lobe off-axis deposits contain high- and low-density turbidites and have moderate depositional reservoir quality. Conversely, low-density turbidites dominate lobe fringe and channel-margin positions and have relatively poor depositional reservoir quality. There is a sharp decrease in depositional reservoir quality between the lobe off-axis and lobe fringe due to: 1) an abrupt increase in matrix content; 2) an abrupt decrease in sandstone amalgamation; and 3) a decrease in grain-size. There is an abrupt increase in depositional reservoir quality from channel margin to channel axis corresponding to: 1) an increase in total sandstone thickness and amalgamation; 2) an increase in grain-size, 3) a decrease in matrix content. Rates of change of key properties are up to two orders of magnitude greater between channel-fill sub-environments compared to lobe sub-environments. Spatial variability in properties of discrete architectural elements, and rates of changes, provides input to reservoir models during exploration, appraisal, and development phases of hydrocarbon fields

Anomalies and the chiral magnetic effect in the Sakai-Sugimoto model

In the chiral magnetic effect an imbalance in the number of left- and right-handed quarks gives rise to an electromagnetic current parallel to the magnetic field produced in noncentral heavy-ion collisions. The chiral imbalance may be induced by topologically nontrivial gluon configurations via the QCD axial anomaly, while the resulting electromagnetic current itself is a consequence of the QED anomaly. In the Sakai-Sugimoto model, which in a certain limit is dual to large-N_c QCD, we discuss the proper implementation of the QED axial anomaly, the (ambiguous) definition of chiral currents, and the calculation of the chiral magnetic effect. We show that this model correctly contains the so-called consistent anomaly, but requires the introduction of a (holographic) finite counterterm to yield the correct covariant anomaly. Introducing net chirality through an axial chemical potential, we find a nonvanishing vector current only before including this counterterm. This seems to imply the absence of the chiral magnetic effect in this model. On the other hand, for a conventional quark chemical potential and large magnetic field, which is of interest in the physics of compact stars, we obtain a nontrivial result for the axial current that is in agreement with previous calculations and known exact results for QCD.Comment: 35 pages, 4 figures, v2: added comments about frequency-dependent conductivity at the end of section 4; references added; version to appear in JHE

Chiral drag force

We provide a holographic evaluation of novel contributions to the drag force acting on a heavy quark moving through strongly interacting plasma. The new contributions are chiral in that they act in opposite directions in plasmas containing an excess of left- or right-handed quarks and in that they are proportional to the coefficient of the axial anomaly. These new contributions to the drag force act either parallel to or antiparallel to an external magnetic field or to the vorticity of the fluid plasma. In all these respects, these contributions to the drag force felt by a heavy quark are analogous to the chiral magnetic effect on light quarks. However, the new contribution to the drag force is independent of the electric charge of the heavy quark and is the same for heavy quarks and antiquarks. We show that although the chiral drag force can be non-vanishing for heavy quarks that are at rest in the local fluid rest frame, it does vanish for heavy quarks that are at rest in a suitably chosen frame. In this frame, the heavy quark at rest sees counterpropagating momentum and charge currents, both proportional to the axial anomaly coefficient, but feels no drag force. This provides strong concrete evidence for the absence of dissipation in chiral transport, something that has been predicted previously via consideration of symmetries. Along the way to our principal results, we provide a general calculation of the corrections to the drag force due to the presence of gradients in the flowing fluid in the presence of a nonzero chemical potential. We close with a consequence of our result that is at least in principle observable in heavy ion collisions, namely an anticorrelation between the direction of the CME current for light quarks in a given event and the direction of the kick given to the momentum of all the heavy quarks and antiquarks in that event.Comment: 28 pages, small improvement to the discussion of gravitational anomaly, references adde

On the Generation of the Hubble Sequence through an Internal Secular Dynamical Process

The secular evolution process, which slowly transforms the morphology of a galaxy over its lifetime, could naturally account for observed properties of the great majority of physical galaxies if both stellar and gaseous accretion processes are taken into account. As an emerging paradigm for galaxy evolution, its dynamical foundation had been established in the past few years, and its observational consequences are yet to be fully explored. The secular evolution picture provides a coherent framework for understanding the extraordinary regularity and the systematic variation of galaxy properties along the Hubble sequence.Comment: 10 pages, 1 figure, invited talk presented at the international conference on "Penetrating Bars through the Masks of Cosmic Dust: The Hubble Tuning Fork Strikes a New Note", June 2004, South Afric

Study of Peri-Articular Anaesthetic for Replacement of the Knee (SPAARK): study protocol for a patient-blinded, randomised controlled superiority trial of liposomal bupivacaine

Background: Optimising the management of peri-operative pain and recovery following knee replacement has been identified as a patient priority. Current pain relief strategies use opiate-based analgesia; however, up to 50% of patients experience significant side effects. Local anaesthetic incisional infiltration is one alternative. The length of the duration of action is a major limiting factor of current local anaesthetic techniques. Liposomal bupivacaine has been reported to be effective for up to 72 h. This randomised controlled trial will evaluate the clinical and cost effectiveness of liposomal bupivacaine. Methods: SPAARK is a patient-blinded, multi-centre, active comparator, superiority, two-arm, parallel-group randomised controlled trial. Five hundred patients undergoing knee replacement will be recruited and randomised to liposomal bupivacaine plus bupivacaine hydrochloride or bupivacaine hydrochloride alone. The co-primary outcomes are the Quality of Recovery 40 measured at 72 h post-surgery and also cumulative pain measured daily using a 0–10 visual analogue scale for the first 3 days following surgery. Secondary outcomes include cumulative opioid consumption, fitness for discharge, functional outcomes assessed using the Oxford Knee Score and American Knee Society Score, the EuroQol five dimensions instrument and complications. A cost utility analysis is also planned. Discussion: The clinical effectiveness and cost effectiveness of liposomal bupivacaine have yet to be evaluated in the National Health Service, making this trial appropriate and timely. Trial registration: ISRCTN registry, ISRCTN54191675. Registered on 14 November 2017