An Empirical Model For Refrigerant Flammability Based On Molecular Structure and Thermodynamics

Screening methods for refrigerant blend flammability using metrics that can be easily calculated are of great interest to the refrigerant industry. Existing flammability metrics such as heat of combustion are not adequate for hydrofluorocarbon blends. Alternative metrics are needed that can be used to assess the flammability of refrigerant blends without requiring time-consuming experimental measurements. In this work we study the combination of the maximum adiabatic flame temperature and the fluorine-substitution ratio as metrics for characterizing the flammability of refrigerant blends. The combination of these metrics yields an estimate of the flammability class of refrigerants (both blends and pure fluids) containing hydrofluorocarbon and hydrocarbon components. The calculations of adiabatic flame temperature are carried out with the open-source chemical kinetics software package Cantera using a mechanism available in the literature

A Survey of Eclipsing Binary Stars in the Eastern Spiral Arm of M31

Results of an archival survey are presented using B-band imaging of the eastern spiral arm of M31. Focusing on the eclipsing binary star population, a matched-filter technique has been used to identify 280 binary systems. Of these, 127 systems (98 of which are newly discovered) have sufficient phase coverage to allow accurate orbital periods to be determined. At least nine of these binaries are detached systems which could, in principle, be used for distance determination. The light curves of the detached and other selected systems are presented along with a discussion of some of the more interesting binaries. The impact of unresolved stellar blends on these lightcurves is considered.Comment: 10 pages, accepted for publication in MNRA

Evaluation of binary and ternary refrigerant blends as replacements for R134a in an air-conditioning system

We investigated refrigerant blends as possible low-GWP (global warming potential) alternatives for R134a in an air-conditioning application. We carried out an extensive screening of the binary and ternary blends possible among a list of 10 pure refrigerants comprising three hydrofluoroolefins (HFOs), six hydrofluorocarbons (HFCs), and carbon dioxide. The screening was based on a simplified cycle model, but with the inclusion of pressure drops in the evaporator and condenser. The metrics for the evaluation were nonflammability, low-GWP, high COP (coefficient of performance), and a volumetric capacity similar to the R134a baseline system. While no mixture was ideal in all regards, we identified 12 best blends that were nonflammable (based on a new estimation method by Linteris, et al., presented in a companion paper at this conference) and with COP and capacity similar to the R134a baseline; the tradeoff, however, was a reduction in GWP of, at most, 56% compared to R134a. An additional seven blends that were estimated to be marginally flammable (ASHRAE Standard 34 classification of A2L) were identified with GWP reductions of as much as 90%. These 19 best blends were then simulated in a more detailed cycle model

Quantum Entropic Effects in the Liquid Viscosities of Hydrogen, Deuterium, and Neon

The extremely low temperatures have limited the availability and accuracy of experimental thermophysical property measurements for cryogens, particularly transport properties. Traditional scaling techniques such as corresponding states theory have long been known to be inaccurate for fluids with strong quantum effects. To address this need, this paper investigates how quantum effects impact thermodynamics and momentum transfer (shear viscosity) in the fluid phases of hydrogen, deuterium, and neon. We utilize experimental viscosity measurements and reference empirical equations of state to show that conventional entropy scaling is inadequate for quantum-dominated systems. We then provide a simple empirical correction to entropy scaling based on the ratio of quantum to packing length scale that accounts for the deviations

Distribution of thermophilic endospores in a temperate estuary indicate that dispersal history structures sediment microbial communities

Endospores of thermophilic bacteria are found in cold and temperate sediments where they persist in a dormant state. As inactive endospores that cannot grow at the low ambient temperatures, they are akin to tracer particles in cold sediments, unaffected by factors normally governing microbial biogeography (e.g., selection, drift, mutation). This makes thermophilic endospores ideal model organisms for studying microbial biogeography since their spatial distribution can be directly related to their dispersal history. To assess dispersal histories of estuarine bacteria, thermophilic endospores were enriched from sediments along a freshwater‐to‐marine transect of the River Tyne in high temperature incubations (50°C). Dispersal histories for 75 different taxa indicated that the majority of estuarine endospores were of terrestrial origin; most closely related to bacteria from warm habitats associated with industrial activity. A subset of the taxa detected were marine derived, with close relatives from hot deep marine biosphere habitats. These patterns are consistent with the sources of sediment in the River Tyne being predominantly terrestrial in origin. The results point to microbial communities in estuarine and marine sediments being structured by bi‐directional currents, terrestrial run‐off and industrial effluent as vectors of passive dispersal and immigration

Prevalence of true vein graft aneurysms: Implications for aneurysm pathogenesis

AbstractBackground: Circumstantial evidence suggests that arterial aneurysms have a different cause than atherosclerosis and may form part of a generalized dilating diathesis. The aim of this study was to compare the rates of spontaneous aneurysm formation in vein grafts performed either for popliteal aneurysms or for occlusive disease. The hypothesis was that if arterial aneurysms form a part of a systemic process, then the rates of vein graft aneurysms should be higher for patients with popliteal aneurysms than for patients with lower limb ischemia caused by atherosclerosis. Methods: Infrainguinal vein grafting procedures performed from 1990 to 1995 were entered into a prospective audit and graft surveillance program. Aneurysmal change was defined as a focal increase in the graft diameter of 1.5 cm or greater, excluding false aneurysms and dilatations after graft angioplasty. Results: During the study period, 221 grafting procedures were performed in 200 patients with occlusive disease and 24 grafting procedures were performed in 21 patients with popliteal aneurysms. Graft surveillance revealed spontaneous aneurysm formation in 10 of the 24 bypass grafts (42%) for popliteal aneurysms but in only 4 of the 221 grafting procedures (2%) that were performed for chronic lower limb ischemia. Conclusion:This study provides further evidence that aneurysmal disease is a systemic process, and this finding has clinical implications for the treatment of popliteal aneurysms. (J Vasc Surg 1999;29:403-8.

A general computer program for the Bell detection loophole

The difference between ideal experiments to test Bell's weak nonlocality and the real experiments leads to loopholes. Ideal experiments involve either inequalities (Bell) or equalities (Greenberger, Horne, Zeilinger). Every real experiment has its own critical inequalities, which are almost all more complicated than the corresponding ideal inequalities and equalities. If one of these critical inequalities is violated, then the detection loophole is closed, with no further assumptions. If all the critical inequalities are satisfied, then it remains open, unless further assumptions are made. The computer program described here and published on the website http://www.strings.ph.qmw.ac.uk/QI/main.htm obtains the critical inequalities for any real experiment, given the number of allowed settings of the angles and the corresponding possible output signals for a single run. Given all the necessary conditional probabilities or rates, it tests whether all these inequalities are satisfied.Comment: 10 pages, no figures. Revised version with additional reference to Pitowski and Svozi

Is graphene on copper doped?

Angle-resolved photoemission spectroscopy (ARPES) and X-ray photoemission spectroscopy have been used to characterise epitaxially ordered graphene grown on copper foil by low-pressure chemical vapour deposition. A short vacuum anneal to 200 °C allows observation of ordered low energy electron diffraction patterns. High quality Dirac cones are measured in ARPES with the Dirac point at the Fermi level (undoped graphene). Annealing above 300 °C produces n-type doping in the graphene with up to 350 meV shift in Fermi level, and opens a band gap of around 100 meV. Dirac cone dispersion for graphene on Cu foil after vacuum anneals (left: 200 °C, undoped; right: 500 °C, n-doped). Centre: low energy electron diffraction from graphene on Cu foil after 200 °C anneal. Data from Antares (SOLEIL)