Enantioselective Ring-Opening Polymerization of <i>rac</i>-Lactide Dictated by Densely Substituted Amino Acids

Organocatalysis is becoming an important tool in polymer science because of its versatility and specificity. To date a limited number of organic catalysts have demonstrated the ability to promote stereocontrolled polymerizations. In this work we report one of the first examples of chirality transfer from a catalyst to a polymer in the organocatalyzed ring-opening polymerization (ROP) of <i>rac</i>-lactide (<i>rac</i>-LA). We have polymerized <i>rac</i>-LA using the diastereomeric densely substituted amino acids (2<i>S</i>,3<i>R</i>,4<i>S</i>,5<i>S</i>)-1-methyl-4-nitro-3,5-diphenylpyrrolidine-2-carboxylic acid (<i>endo</i>-<b>6</b>) and (2<i>S</i>,3<i>S</i>,4<i>R</i>,5<i>S</i>)-1-methyl-4-nitro-3,5-diphenylpyrrolidine-2-carboxylic acid (<i>exo</i>-<b>6</b>), combined with 1,8-diazabicyclo[5.4.0]­undec-7-ene (DBU) as a cocatalyst. Both diastereoisomers not only showed the ability to synthesize enriched isotactic polylactide with a <i>P</i>_m higher than 0.90 at room temperature but also were able to preferentially promote the polymerization of one of the isomers (l or d) with respect to the other. Thus, <i>exo</i>-<b>6</b> preferentially polymerized l-lactide, whereas <i>endo</i>-<b>6</b> preferred d-lactide as the substrate. Density functional theory calculations were conducted to investigate the origins of this unique stereocontrol in the polymerization, providing mechanistic insight and explaining why the chirality of the catalyst is able to define the stereochemistry of the monomer insertion

Solid-state Li metal battery with hybrid electrolyte: An overview of the Horizon Europe SEATBELT project.

International audienceWithin the next decade, new generations of lithium (Li) batteries based on silicon/carbon and Li metal anodes where the conventional flammable liquid electrolyte of the currently commercialized Li-ion device is replaced by a non- flammable solid-one are expected to take over the battery market. Among those, all- solid-state batteries comprising a Li metal anode and a solid-state electrolyte is a target of choice as their properties should overcome all previous battery technologies. Indeed, only all-solid-state Li batteries are expected to fulfil the needed cell gravimetric energy density, cyclability, sustainability and recycling specifications demanded by electromobility and stationary applications. In this context, the EU- funded (Horizon Europe) SEATBELT project will help to pave the road towards a cost-effective, robust all-solid-state Li battery comprising sustainable materials by 2026. SEATBELT intends to achieve the first technological milestone of developingan all-solid-state battery cell meeting the needs of Electric Vehicle (EV) and stationary industry. The low-cost SEATBELT cell is safe-by-design with sustainable and recyclable materials, with the goal to reach high energy densities (>380 Wh/kg) and long cyclability (> 500 cycles) by 2026 in line with the 2030 European targets. Herein, we will present the project and technological strategies that will be developed during the project and the consortium partners. SEATBELT consortium is composed of 14 beneficiary partners and one associated partner spread all over Europe (8 countries). Typically, the battery cells will be produced by low-cost solvent-free extrusion process comprising a combination of innovative materials: thin Li metal, solid hybrid electrolyte, a safe cathode active material without critical materials and thin Al current collector. The cell design being optimized by interface (operando and atomistic modelling) and process (machine learning) methodologies. In addition, in situ imaging instrumentation will be performed to investigate safety properties and mechanical deformation to assess the cell safety in real conditions. An innovative recycling cycle from materials to cell level will be also established

Solid-state Li metal battery with hybrid electrolyte: An overview of the Horizon Europe SEATBELT project.

International audienceWithin the next decade, new generations of lithium (Li) batteries based on silicon/carbon and Li metal anodes where the conventional flammable liquid electrolyte of the currently commercialized Li-ion device is replaced by a non- flammable solid-one are expected to take over the battery market. Among those, all- solid-state batteries comprising a Li metal anode and a solid-state electrolyte is a target of choice as their properties should overcome all previous battery technologies. Indeed, only all-solid-state Li batteries are expected to fulfil the needed cell gravimetric energy density, cyclability, sustainability and recycling specifications demanded by electromobility and stationary applications. In this context, the EU- funded (Horizon Europe) SEATBELT project will help to pave the road towards a cost-effective, robust all-solid-state Li battery comprising sustainable materials by 2026. SEATBELT intends to achieve the first technological milestone of developingan all-solid-state battery cell meeting the needs of Electric Vehicle (EV) and stationary industry. The low-cost SEATBELT cell is safe-by-design with sustainable and recyclable materials, with the goal to reach high energy densities (>380 Wh/kg) and long cyclability (> 500 cycles) by 2026 in line with the 2030 European targets. Herein, we will present the project and technological strategies that will be developed during the project and the consortium partners. SEATBELT consortium is composed of 14 beneficiary partners and one associated partner spread all over Europe (8 countries). Typically, the battery cells will be produced by low-cost solvent-free extrusion process comprising a combination of innovative materials: thin Li metal, solid hybrid electrolyte, a safe cathode active material without critical materials and thin Al current collector. The cell design being optimized by interface (operando and atomistic modelling) and process (machine learning) methodologies. In addition, in situ imaging instrumentation will be performed to investigate safety properties and mechanical deformation to assess the cell safety in real conditions. An innovative recycling cycle from materials to cell level will be also established