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Application of Poly(hydroxyalkanoate) In Food Packaging: Improvements by Nanotechnology

The environmental impact of plastic usage is of critical concern and too great to repair. A shift toward biodegradable food packaging is one option. The aim of this review paper is the study of the potential of biodegradable materials for food packaging. The main characteristics in relation to food usage can be narrowed down to mass transfer (gas and water vapor), thermal and mechanical properties. Among several kinds of biodegradable polymers, poly(hydroxyalkanoate) is one of the favorable candidates for food packaging due to its physical and mechanical properties, biodegradability, with low permeability for O2, H2O and CO2 without residues of catalysts and water solubility. The main focus of this article is to address poly(hydroxyalkanoate) as a potential candidate for food packaging. The need of applying biobased polymers in food packaging is presented in the introduction of this study. We also describe the most common biopolymers providing a brief overview of classification and application. This is followed by an outline of biopolymer production and a main section in which the properties of poly(hydroxybutyrate)-based nanocomposites of greatest relevance to food packaging are discussed. Furthermore, several approaches for improvement of poly(hydroxybutyrate) properties are described and the role of nanotechnology to improve its mechanical properties is presented. Finally, the article concludes with a summary as well as some possible future trends

A study of environmental characterization of conventional and advanced aluminum alloys for selection and design. Phase 2: The breaking load test method

A technique is demonstrated for accelerated stress corrosion testing of high strength aluminum alloys. The method offers better precision and shorter exposure times than traditional pass fail procedures. The approach uses data from tension tests performed on replicate groups of smooth specimens after various lengths of exposure to static stress. The breaking strength measures degradation in the test specimen load carrying ability due to the environmental attack. Analysis of breaking load data by extreme value statistics enables the calculation of survival probabilities and a statistically defined threshold stress applicable to the specific test conditions. A fracture mechanics model is given which quantifies depth of attack in the stress corroded specimen by an effective flaw size calculated from the breaking stress and the material strength and fracture toughness properties. Comparisons are made with experimental results from three tempers of 7075 alloy plate tested by the breaking load method and by traditional tests of statistically loaded smooth tension bars and conventional precracked specimens

Middle Pleistocene to Holocene activity of the Gondola Fault Zone (Southern Adriatic Foreland): deformation of a regional shear zone and seismotectonic implications

Recent seismicity in and around the Gargano Promontory, an uplifted portion of the southern Adriatic Foreland domain, indicates active E-W strike-slip faulting in a region that has also been struck by large historical earthquakes, particularly along the Mattinata Fault. Seismic profiles published in the past two decades show that the pattern of tectonic deformation along the E-W–trending segment of the Gondola Fault Zone, the offshore counterpart of the Mattinata Fault, is strikingly similar to that observed onshore during the Eocene-Pliocene interval. Based on the lack of instrumental seismicity in the south Adriatic offshore, however, and on standard seismic reflection data showing an undisturbed Quaternary succession above the Gondola Fault Zone, this fault zone has been interpreted as essentially inactive since the Pliocene. Nevertheless, many investigators emphasised the genetic relationships and physical continuity between the Mattinata Fault, a positively active tectonic feature, and the Gondola Fault Zone. The seismotectonic potential of the system formed by these two faults has never been investigated in detail. Recent investigations of Quaternary sedimentary successions on the Adriatic shelf, by means of very high-resolution seismic-stratigraphic data, have led to the identification of fold growth and fault propagation in Middle-Upper Pleistocene and Holocene units. The inferred pattern of gentle folding and shallow faulting indicates that sediments deposited during the past ca. 450 ka were recurrently deformed along the E-W branch of the Gondola Fault Zone. We performed a detailed reconstruction and kinematic interpretation of the most recent deformation observed along the Gondola Fault Zone and interpret it in the broader context of the seismotectonic setting of the southern Apennines-foreland region. We hypothesise that the entire 180 km-long Molise-Gondola Shear Zone is presently active and speculate that also its offshore portion, the Gondola Fault Zone, has a seismogenic behaviour

Palindromic Length of Words with Many Periodic Palindromes

The palindromic length $\text{PL}(v)$ of a finite word $v$ is the minimal number of palindromes whose concatenation is equal to $v$. In 2013, Frid, Puzynina, and Zamboni conjectured that: If $w$ is an infinite word and $k$ is an integer such that $\text{PL}(u)\leq k$ for every factor $u$ of $w$ then $w$ is ultimately periodic. Suppose that $w$ is an infinite word and $k$ is an integer such $\text{PL}(u)\leq k$ for every factor $u$ of $w$. Let $\Omega(w,k)$ be the set of all factors $u$ of $w$ that have more than $\sqrt[k]{k^{-1}\vert u\vert}$ palindromic prefixes. We show that $\Omega(w,k)$ is an infinite set and we show that for each positive integer $j$ there are palindromes $a,b$ and a word $u\in \Omega(w,k)$ such that $(ab)^j$ is a factor of $u$ and $b$ is nonempty. Note that $(ab)^j$ is a periodic word and $(ab)^ia$ is a palindrome for each $i\leq j$. These results justify the following question: What is the palindromic length of a concatenation of a suffix of $b$ and a periodic word $(ab)^j$ with "many" periodic palindromes? It is known that $\lvert\text{PL}(uv)-\text{PL}(u)\rvert\leq \text{PL}(v)$, where $u$ and $v$ are nonempty words. The main result of our article shows that if $a,b$ are palindromes, $b$ is nonempty, $u$ is a nonempty suffix of $b$, $\vert ab\vert$ is the minimal period of $aba$, and $j$ is a positive integer with $j\geq3\text{PL}(u)$ then $\text{PL}(u(ab)^j)-\text{PL}(u)\geq 0$

Different approaches for assessing sperm function

Different approaches can be used to assess sperm function in different conditions, i.e. sperm storage, freezing-thawing or activation by induction of capacitation and acrosome reaction. In this review we will focus on the assays routinely performed in our laboratories, giving a literature support to critically analyse different approaches. In fact, researchers usually tend to look for the \u201cone shot\u201c parameter that could explain itself a specific process; it is our conviction that a multiparametric approach is still more valid, as some changes in sperm function are very complex and could be explained only by operating in different ways. Sperm motility, the most evident sperm characteristic, should be assessed by computer-aided sperm analysers that permit an objective evaluation of the motility and its kinematic parameters. Commercial and open source instruments are available and could be profitably used together with specific statistical approaches. The use of microscopy, and particularly fluorescent microscopy, could be a very useful tool to assess different parameters in sperm cells both by fluorophores that give indication of a determined function, and by immunolocalization of proteins, that permits the discover of new features or to explain particular sperm functions. The same substrates could be used also in flow cytometry: the difference is that it permits to study wider sperm populations (and their sub-population distribution). Flow cytometry is undergoing a very wide use in spermatology and technical and experimental rigor is needed to obtain reliable results. Metabolic assessment of sperm features, particularly energetic supply, ATP formation and other enzyme activities, could represent a very important challenge to acquire new information and complete/integrate those derived from other techniques. Finally, functional assays such as oocyte binding and in vitro fertilization, represent a very strong tool to assess sperm function in vitro, as they could evidence the functional intactness of some pathways

Middle Pleistocene to Holocene activity of the Gondola Fault Zone (Southern Adriatic Foreland): deformation of a regional shear zone and seismotectonic implications

Recent seismicity in and around the Gargano Promontory, an uplifted portion of the Southern Adriatic Foreland domain, indicates active E–W strike-slip faulting in a region that has also been struck by large historical earthquakes, particularly along the Mattinata Fault. Seismic profiles published in the past two decades show that the pattern of tectonic deformation along the E–W-trending segment of the Gondola Fault Zone, the offshore counterpart of the Mattinata Fault, is strikingly similar to that observed onshore during the Eocene–Pliocene interval. Based on the lack of instrumental seismicity in the south Adriatic offshore, however, and on standard seismic reflection data showing an undisturbed Quaternary succession above the Gondola Fault Zone, this fault zone has been interpreted as essentially inactive since the Pliocene. Nevertheless, many investigators emphasised the genetic relationships and physical continuity between the Mattinata Fault, a positively active tectonic feature, and the Gondola Fault Zone. The seismotectonic potential of the system formed by these two faults has never been investigated in detail. Recent investigations of Quaternary sedimentary successions on the Adriatic shelf, by means of very high-resolution seismic–stratigraphic data, have led to the identification of fold growth and fault propagation in Middle–Upper Pleistocene and Holocene units. The inferred pattern of gentle folding and shallow faulting indicates that sediments deposited during the past ca. 450 ka were recurrently deformed along the E–W branch of the Gondola Fault Zone. We performed a detailed reconstruction and kinematic interpretation of the most recent deformation observed along the Gondola Fault Zone and interpret it in the broader context of the seismotectonic setting of the Southern Apennines-foreland region. We hypothesise that the entire 180 km-long Molise–Gondola Shear Zone is presently active and speculate that also its offshore portion, the Gondola Fault Zone, has a seismogenic behaviour

Long-term prediction of adherence to continuous positive air pressure therapy for the treatment of moderate/severe obstructive sleep apnea syndrome

BACKGROUND: Continuous positive airway pressure (CPAP) therapy is a highly effective treatment for obstructive sleep apnea syndrome (OSAS). However, poor adherence is a limiting factor, and a significant proportion of patients are unable to tolerate CPAP. The aim of this study was to determine predictors of long-term non-compliance with CPAP. METHODS: CPAP treatment was prescribed to all consecutive patients with moderate or severe OSAS (AHI ≥15 events/h) (n = 295) who underwent a full-night CPAP titration study at home between February 1, 2002 and December 1, 2016. Adherence was defined as CPAP use for at least 4 h per night and five days per week. Subjects had periodical follow-up visits including clinical and biochemical evaluation and assessment of adherence to CPAP. RESULTS: Median follow-up observation was 74.8 (24.2/110.9) months. The percentage of OSAS patients adhering to CPAP was 41.4% (42.3% in males and 37.0% in females), and prevalence was significantly higher in severe OSAS than in moderate (51.8% vs. 22.1%; p < 0.001; respectively). At multivariate analysis, lower severity of OSAS (HR = 0.66; CI 95 0.46-0.94) p < 0.023), cigarette smoking (HR = 1.72; CI 95 1.13-2.61); p = 0.011), and previous cardiovascular events (HR = 1.95; CI 95 1.03-3.70; p = 0.04) were the only independent predictors of long-term non-adherence to CPAP after controlling for age, gender, and metabolic syndrome. CONCLUSIONS: In our cohort of patients with moderate/severe OSAS who were prescribed CPAP therapy, long-term compliance to treatment was present in less than half of the patients. Adherence was positively associated with OSAS severity and negatively associated with cigarette smoking and previous cardiovascular events at baseline