Preparation of hybrid organic-inorganic materials based on a di-ureasil matrix doped with lithium bis(trifluoromethanesulfonyl)imide

In this presentation we describe the preparation of solvent-free solid polymer electrolytes (SPEs) by the sol-gel route with the incorporation of controlled quantities of lithium bis(trifluoromethanesulfonyl) imide (LiTFSI) into the host matrix. The host framework of these xerogels, designated as di-ureasils and represented by d-U(900), contains oxyethylene oligomers with about 15 repeat units bonded at each end to a siliceous backbone through urea bridging links. Electrolytes were characterized by ionic conductivity measurements, cyclic voltammetry at a gold microelectrode and thermal analysis. The results obtained reveal that these hybrid materials are completely amorphous and exhibit appropriate electrochemical characteristics for a variety of applications.Fundação para a Ciência e a Tecnologia - POCI/QUI/59856/2004; POCTI/3/686; SFRH/BD/22707/2005

Resistencia a penetraçao de um latossolo vermelho amarelo do cerrado sob diferentes sistemas de manejo

The intensification of agricultural production systems has caused soil compaction even when soil conservation technologies are adopted. Soil compaction is one of the main problems for farmers, both in no-tillage and in conventional-tillage systems, as well as in pasture. This study was conducted in Rio Verde, (State of Goias), on Red-Yellow Latosol under the following systems: no-tillage for 14 years (SD14); no-tillage for 8 years (SD8); no-tillage for 2 years (SD2); conventional tillage (CT); pasture (P) and forest (F). The soil resistance to penetration was measured by the impact penetrometer Model IAA/Planalsucar - Stolf, from soil surface to the soil depth of 0.40 m. Soil bulk density and granulometry were also determined. Conventional tillage had lower resistance to penetration at the 0-0.10 m depth, whereas SD2 had more resistance up to 0.40 m in depth. There were no significant differences below 0.15 m in depth among treatments CT, SD8, and SD14. The first two years under the no-tillage system are critical, with regard to the resistance to penetration in to the soil surface layers. (Résumé d'auteur

Tellurite Glass Optical Fiber Doped With Pbte Quantum Dots

We produced a PbTe quantum dot core doped optical fiber with tellurite glasses intended to be used in highly nonlinear ultrafast optical devices capable to operate at the optical communication window at 1300 and 1500 nm wavelength region. Attenuation peaks of the optical fiber depends on the heat treatment time as expected for dots growth and covered the whole mid infrared region near 1500 nm. The optical fiber preform was made with the rod-in-tube method and the fiber was produced with a 4 m high Heatway drawing tower. The optical fiber core can be heavily doped because tellurite glasses solubility for PbTe quantum dots is order of magnitude higher than borosilicate and phosphate glasses, for example. In order to match all the requirements for core-clad optical fibers we studied undoped and doped tellurite glasses optical and thermophysical properties as a function of the glass composition. We also followed the growth kinetics of the quantum dots by High Resolution Transmission Electron Microscopy in the bulk glass matrix and the optical fiber.5734124129Borrelli, N.F., Aitken, B.G., Newhouse, M.A., (1995) J. Non-cryst.Sol., p. 185Wise, F.W., (2000) Acc. Chem. Res., 33, p. 773Borrelli, N.F., Smith, D.W., (1994) J. Non-cryst. Sol., 180, p. 25Lipovskii, A., Kolobkova, E.A., Petrikov, V., Kang, I., Olkhovets, A., Krauus, T., Thomas, M., Kycia, S., (1997) Appl. Phys. Lett., 71, p. 3406Reynoso, V.C.S., De Paula, A.M., Cuevas, R.F., Neto, J.A.M., Alves, O.L., Cesar, C.L., Barbosa, L.C., (1995) Elect. Lett., 31 (12), pp. 1013-1014Rodriguez, E., Jimenez, E., Jacob, G.J., Neves, A., Cesar, C.L., Barbosa, L.C., Photonics West 2005, , poster 5734-22Jacob, G.J., Cesar, C.L., Barbosa, L.C., (2002) Physics and Chemistry of Glass, 43 C, pp. 250-253Tudury, G.E., Marquezini, M.V., Ferreira, L.G., Barbosa, L.C., Cesar, C.L., (2000) Phys. Rev. B, 62 (11), p. 7357Cho, S.J., Paek, U.C., Han, W.T., Heo, J., (2001) OFC2001, , ThC4-1 paperJu, S., Kim, Y.H., Han, W.T., (2004) ECOC2004, , Stockholm, Sweden, September 5-9, Th2.3.3 pape

One-dimensional Photonic Crystal For The 1.3-1.5 μm Region

Multilayer of PbTe quantum dots embedded in SiO2 were fabricated by alternatively use of Plasma Enhanced Chemical Vapor Deposition and Laser Ablation techniques. The optimal growing parameters for both the SiO2 films and the PbTe quantum dots were obtained. The refractive index and optical absorption of the sample were studied. Multilayer X-ray diffraction patterns were used to estimate the nanoparticles diameter. Morphological properties of the nanostructured material were studied using Transmission Electron Microscopy. Both absorption spectra and X-ray diffraction patterns reveled the nanoparticles are 6-8 nm in diameter, consequently appropriate for developing optical devices in the infra red region. Finally the multilayer was grown inside a Fabry Perot cavity. The transmittance of the one-dimensional photonic crystal was measured.6129Tsunetomo, K., Shunsuke, S., Koyama, T., Tanaka, S., Sasaki, F., Kobayashi, S., Ultrafast nonlinear optical response of CdTe microcrystallite-doped glasses fabricated by laser evaporation (1995) Molecular Crystals and Liquid Crystals Science and Technology Section B, Nonlinear Optics, 13 (1-3), pp. 109-126Gleiter, H., (1989) Prog. Mater. Sci., 33, p. 223Tudury, G.E., Marquezini, M.V., Ferreira, L.G., Barbosa, L.C., Cesar, C.L., Effect of band anisotropy on electronic structure of PbS, PbSe, and PbTe quantum dots (2000) Phys. Rev. B, 62 (11), pp. 7357-7364Rodriguez, E., Jimenez, E., Padilha, L.A., Neves, A.A.R., Jacob, G.J., Cesar, C.L., Barbosa, L.C., SiO2/PbTe quantum dots multilayer production and characterization (2005) Appl. Phys. Lett., 86, pp. 113117-113120Rodriguez, E., Jimenez, E., Cesar, C.L., Barbosa, L.C., 1D photonic band gap silica doped PbTe quantum dot optical device (2005) Glass Technology, 46 (2), pp. 47-49Rodriguez, E., Jimenez, E., Neves, A.A.R., Jacob, G.J., Cesar, C.L., Barbosa, L.C., Fabrication and characterization of PbTe quantum dot multilayers for Photonic Fabry-Perot Devices (2005) Physica E, 26, pp. 361-36

Soil biochemistry and microbial activity in vineyards under conventional and organic management at Northeast Brazil.

The São Francisco Submedium Valley is located at the Brazilian semiarid region and is an important center for irrigated fruit growing. This region is responsible for 97% of the national exportation of table grapes, including seedless grapes. Based on the fact that orgThe São Francisco Submedium Valley is located at the Brazilian semiarid region and is an important center for irrigated fruit growing. This region is responsible for 97% of the national exportation of table grapes, including seedless grapes. Based on the fact that organic fertilization can improve soil quality, we compared the effects of conventional and organic soil management on microbial activity and mycorrhization of seedless grape crops. We measured glomerospores number, most probable number (MPN) of propagules, richness of arbuscular mycorrhizal fungi (AMF) species, AMF root colonization, EE-BRSP production, carbon microbial biomass (C-MB), microbial respiration, fluorescein diacetate hydrolytic activity (FDA) and metabolic coefficient (qCO2). The organic management led to an increase in all variables with the exception of EE-BRSP and qCO2. Mycorrhizal colonization increased from 4.7% in conventional crops to 15.9% in organic crops. Spore number ranged from 4.1 to 12.4 per 50 g-1 soil in both management systems. The most probable number of AMF propagules increased from 79 cm-3 soil in the conventional system to 110 cm-3 soil in the organic system. Microbial carbon, CO2 emission, and FDA activity were increased by 100 to 200% in the organic crop. Thirteen species of AMF were identified, the majority in the organic cultivation system. Acaulospora excavata, Entrophospora infrequens, Glomus sp.3 and Scutellospora sp. were found only in the organically managed crop. S. gregaria was found only in the conventional crop. Organically managed vineyards increased mycorrhization and general soil microbial activity

Ultra Large Amplification Bandwidth Of Er3+ And Tm3+ At S And L Band From Teo2-wo3-na2o-nb 2o5 Glass Doped Optical Fibers

Tellurite glasses optical fibers became promising for optical amplifiers due to its high rare earth ions solubility and very large amplification bandwidth. Among several tellurite glasses the TeO2-WO 3-Na2O-Nb2O5 system show one of the largest bandwidth. Our previous characterization of lifetime using the Ω2, Ω4, Ω6, Judd-Ofelt parameters indicate a quantum efficiency maximum for 7500ppm Er3+ concentration. Therefore we decided to produce jointed Er3+ and Tm3+ single mode optical fibers with this glass system keeping the 7500ppm Er3+ concentration and varying the Tm3+ concentration from 2500ppm to 15000ppm. This single mode fiber was pumped by 120mW of the semiconductor laser at 790nm and we observed a flat ASE bandwidth from 1400 to 1570nm for the 5000ppm Tm3+ concentration.5723243247Jeong, H., Oh, K., Han, S.R., Morse, T.F., Broadband amplified spontaneous emission from an Er3+-Tm 3+ - Codoped silica fibar (2003) Opt. Lett., 28, pp. 161-163Reisfeld, R., Jorgensen, C.K., (1987) Handbook on the Physics and Chemistry of Rare Earths, 9, pp. 1-90. , K. A. Gschneidner, Jr. and L. Eyring (Eds.), Elsevier ScienceChen, C.Y., Petrin, R.R., Yeh, D.C., Sibley, W.A., Concentration-dependent energy-transfer processes in Er3+-and Tm3+ -doped heavy-metal fluoride (1989) Opt. Lett., 14, pp. 432-434Miniscalco, W.J., Quimby, R.S., General procedure for the analysis of Er3+ cross sections (1991) Opt. Lett, 16, pp. 258-26

In Situ Synchrotron Radiation Small-angle X-ray Scattering Study Of The Kinetics Of Growth Of Cdte Nanocrystals In Borosilicate Glass

A number of isolator-semiconductor nanocrystal composites exhibit quantum confinement effects and nonlinear optical properties. In this work, the formation and growth of CdTe and CdTe0.9S0.1 nanocrystals immersed in a borosilicate glass host matrix were studied by small-angle x-ray scattering using synchrotron radiation during in situ annealing in the 560-580°C temperature range. The values of the average radii of the CdTe nanocrystals determined by using Guinier plots for different annealing times (20-30 Å) agree with those obtained from optical absorption spectroscopy measurements. The nanocrystal size distribution depends on the thermal history and composition of the samples. The existence of other structural heterogeneities having an average size of several hundred ångstroms was detected. © 1995 American Institute of Physics.6621338134

Pbte Quantum Dots - Sio2 Multilayers For Optical Devices Produced By Laser Ablation

Thin films of glass doped with PbTe quantum dots were successfully fabricated. The semiconducting quantum dots were grown by laser ablation of a PbTe target (99.99%) using the second harmonic of a Q-Switched Quantel Nd:YAG laser under high purity argon atmosphere. The glass matrix was fabricated by a plasma chemical vapor deposition method using vapor of tetramethoxysilane (TMOS) as precursor. The QD's and the glass matrix were alternately deposited onto a Si (100) wafer for 60 cycles. Cross-section TEM image clearly showed QD's layer well separated from each other with glass matrix layers. The influence of the ablation time on the size distribution of the quantum dots is studied. HRTEM revealed anisotropy in the size of the QD's: they were about 9nm in the high and 3-5 in diameter. Furthermore HRTEM studies revealed that the QD's basically growth in the (200) and (220) directions. The thickness of the glass matrix layer was about 20 nm. Absorption, photo luminescence and relaxation time of the multilayer were also measured.5734116123Alivisatos, A.P., (1996) Sci., 271, p. 933Warnock, J., Awschalom, D.D., (1985) Phys. Rev. B, 32, p. 5529Borrelli, N.F., May, D.W., Holland, H.J., Smith, D.W., (1987) J. Appl. Phys., 61, p. 399Potter, B.G., Simmons, J.H., (1988) Phys. Rev. B, 37, p. 10838Gleiter, H., (1989) Prog. Mater. Sci., 33, p. 223Tsunetomo, K., Shunsuke, S., Koyama, T., Tanaka, S., Sasaki, F., Kobayashi, S., (1995) Nonlinear Opt., 13, p. 109Reynoso, V.C.S., De Paula, A.M., Cuevas, R.F., Neto, J.A.M., Alves, O.L., Cesar, C.L., Barbosa, L.C., (1995) Electr. Lett., 31 (12), pp. 1013-1015Jacob, G.J., Cesar, C.L., Barbosa, L.C., (2002) Chem. Phys. Glass, 43 C, pp. 250-252Singh, R.K., Narayan, J., (1990) Phys. Rev. B, 41, p. 8843Barnes, J.P., (2002) Nanotechnology, 13, p. 465Tudury, G.E., Marquezini, M.V., Ferreira, L.G., Barbosa, L.C., Cesar, C.L., (2000) Phys. Rev. B, 62 (11), pp. 7357-7364Cesar, C.L., Jacob, G.J., Tudury, G.E., Marquezini, M.V., Barbosa, L.C., (2004) Atti della Fondazione G. Ronchi Journal, (4), pp. 519-528. , Anno LI

Carbon Nanotube Doped Tellurite Glasses

In the past it was observed that buck ball doped glasses showed enhanced optical nonlinearities. However, carbon nanotubes are much more stable than buck ball and should be a better choice for that purpose. Therefore we decided to investigate the possibility to produce carbon nanotubes doped tellurite glasses and measured their optical nonlinearities. Tellurite glasses already have a larger nonlinearity compared to silica, and other, glasses. We produced TeO 2-ZnO tellurite family glasses doped with multi wall Carbon Nanotube (CNT). The CNTs acquired from Carbolex were vigorously mechanically mixed with the tellurite glass precursors and melted in platinum crucible around 650°C in a controlled atmosphere inside an electrical induction furnace. We used the lowest temperature possible and controlled atmosphere to avoid the CNT oxidation. The glass melt was cast in a stainless steel and thermally treated at 300°C for 5 hours to relieve internal stresses. The samples were than cutted and polished to perform the optical characterization. We measured refractive index and thermo physical properties, such as vitreous transition Tg, crystallization onset Tx and melting Tf temperatures. Raman spectroscopy showed the possible presence of CNTs.6890Iijima, S., (1991) Nature, 354, p. 56http://www.ati.surrey.ac.uk/news/n, onlinearDiMaio, J., Rhyne, S., Yang, Z., Fu, K., Czerw, R., Xu, J., Webster, S., Ballato, J., (2003) Information Sciences, 149, p. 69Aoki, Y., Okubo, S., Kataura, H., Nagasawa, H., Achiba, Y., (2005) Chem. Lett, 34 (4), p. 562Misra, S.K., Watts, P.C.P., Valappil, S.P., Silva, S.R.P., Roy, I., Boccaccini, A.R., (2007) Nanotechnology, 18, p. 07570

Quantum Confinement Effects On The Phonons Of Pbte Quantum Dots In Tellurite Glasses

We present Raman-scattering results for PbTe quantum dots (QDs) in doped telluride glasses which clearly show the confinement effects on the phonon spectra as a function of the quantum-dot size..6892Kraus and F. Wise;Phys. Rev. Lett. 79 (25), 5102-05 (1997)Thoen, E.R., (1998) Appl, Phys. Lett, 73 (15), p. 2149Wise, F., (2000) Ace. Chem. Res, 33, pp. 773-780Tsuda, S., Cruz, C.H.B., (1991) Opt. Lett, 16, p. 1596Nakamura, A., Tokizaki, T., Akiyama, H., Kataoka, T., (1992) J. Lumin, 53, p. 105Ohtsuka, S., Koyama, T., Tsunetomo, K., Nagata, H., Tanaka, S., (1992) Appl. Phys. Lett, 61, p. 2953Tsunetomo, K., Ohtsuka, S., Koyama, T., Tanaka, S., Sasaki, F., Kobayashi, S., (1995) Nonlin. Opt, 13, p. 109Colvin, V.L., Schlamp, M.C., Alivisatos, A.P., (1995) Nature ∼London, 370, p. 354Dabbousi, M., Bawendi, G., Onitsuka, O., Rubner, M.F., (1995) Appl. Phys. Lett, 66, p. 1316Guerreiro, T., Ten, S., Borrelli, N.F., Butty, J., Jabbour, G.E., Peyghambarian, N., (1997) Appl. Phys. Lett, 71, p. 1595Murray, C.B., Kagan, C.R., Bawendi, M.G., (1995) Science, 270, p. 1335Kang, I., Wise, F.W., (1997) J. Opt. Soc. Am. B, 14, p. 1632Reynoso, V.C.S., de Paula, A.M., Cuevas, R.F., Medeiros Neto, J.A., Alves, O.L., Cesar, C.L., Barbosa, L.C., (1995) Electron. Lett, 31, p. 1013G.J.Jacob, C.L.Cesar,L.C.Barbosa, Chem.Phys.Glass 43C (2002)250-252Esch, V., Fluegel, B., Khitrova, G., Gibbs, H.M., Jiajin, X., Kang, K., Koch, S.W., Peyghambarian, N., (1990) Phys. Rev, B42, p. 7450Sercel, P.C., Valhala, K.J., (1990) Phys. Rev, B42, p. 3690Schoenlein, R.W., Mittleman, D.M., Shiang, J.J., Alivisatos, A.P., Shank, C.V., (1993) Phys. Rev. Lett, 70, p. 1014Ekimov, A.I., Hache, F., Schanne-Klein, M.C., Ricard, D., Flytzanis, C., Kudryavtsev, I.A., Yazeva, T.V., Efros, A.L., (1993) J. Opt. Soc. Am, B10, p. 100Norris, D.J., Sacra, A., Bawendi, C.B.M.M.G., (1994) Phys. Rev. Lett, 72, p. 2612de Oliveira, C.R.M., de Paula, A.M., Filho, F.O.P., Neto, J.A.M., Barbosa, L.C., Alves, O.L., Menezes, E.A., Cesar, C.L., (1995) Appl. Phys. Lett, 66, p. 439R. Ruppin and R. Englman, Rep. Prog. Phys. 33, 149 (1970)R. Ruppin, J. Phys. C: 8, 1969 (1975)Thoen, E.R., Steinmeyer, G., Langlois, P., Ippen, E.P., Tudury, G.E., Brito Cruz, C.H., Barbosa, L.C., Cesar, C.L., (1998) Appl. Phys. Lett, 73Krauss, T.D., Wise, F.W., Coherent and Acoustical Phonon in a Semiconductor Quantum DotsPhis (1997) Rev. Lett, 79, pp. 5102-510